Item talk:Q308961
From geokb
{
"USGS Publications Warehouse": {
"@context": "https://schema.org",
"@type": "Article",
"additionalType": "Journal Article",
"name": "Solid-solution aqueous-solution equilibria: Thermodynamic theory and representation",
"identifier": [
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse IndexID",
"value": "70016423",
"url": "https://pubs.usgs.gov/publication/70016423"
},
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse Internal ID",
"value": 70016423
},
{
"@type": "PropertyValue",
"propertyID": "DOI",
"value": "10.2475/ajs.290.2.164",
"url": "https://doi.org/10.2475/ajs.290.2.164"
},
{
"@type": "PropertyValue",
"propertyID": "ISSN",
"value": "00029599"
}
],
"journal": {
"@type": "Periodical",
"name": "American Journal of Science",
"volumeNumber": "290",
"issueNumber": "2"
},
"inLanguage": "en",
"isPartOf": [
{
"@type": "CreativeWorkSeries",
"name": "American Journal of Science"
}
],
"datePublished": "1990",
"dateModified": "2019-10-18",
"abstract": "Thorstenson and Plummer's (1977) \"stoichiometric saturation' model is reviewed, and a general relation between stoichiometric saturation Kss constants and excess free energies of mixing is derived for a binary solid-solution B1-xCxA: GE = RT[ln Kss - xln(xKCA) - (l-x)ln((l-x)KBA)]. This equation allows a suitable excess free energy function, such as Guggenheim's (1937) sub-regular function, to be fitted from experimentally determined Kss constants. Solid-phase free energies and component activity-coefficients can then be determined from one or two fitted parameters and from the endmember solubility products KBA and KCA. A general form of Lippmann's (1977,1980) \"solutus equation is derived from an examination of Lippmann's (1977,1980) \"total solubility product' model. Lippmann's II or \"total solubility product' variable is used to represent graphically not only thermodynamic equilibrium states and primary saturation states but also stoichiometric saturation and pure phase saturation states.",
"description": "38 p.",
"publisher": {
"@type": "Organization",
"name": "American Journal of Science"
},
"author": [
{
"@type": "Person",
"name": "Glynn, P. D.",
"givenName": "P. D.",
"familyName": "Glynn"
},
{
"@type": "Person",
"name": "Reardon, E.J.",
"givenName": "E.J.",
"familyName": "Reardon"
}
],
"funder": [
{
"@type": "Organization",
"name": "Toxic Substances Hydrology Program",
"url": null
}
]
},
"OpenAlex": {
"_id": "https://openalex.org/w1981362259",
"abstract_inverted_index": null,
"apc_list": null,
"apc_paid": null,
"authorships": [
{
"author_position": "first",
"author": {
"id": "https://openalex.org/A5048968895",
"display_name": "Pierre D. Glynn",
"orcid": "https://orcid.org/0000-0001-8804-7003"
},
"institutions": [],
"countries": [],
"is_corresponding": false,
"raw_author_name": "P. D. Glynn",
"raw_affiliation_strings": [],
"affiliations": []
},
{
"author_position": "last",
"author": {
"id": "https://openalex.org/A5075006338",
"display_name": "Eric J. Reardon",
"orcid": null
},
"institutions": [],
"countries": [],
"is_corresponding": false,
"raw_author_name": "E. J. Reardon",
"raw_affiliation_strings": [],
"affiliations": []
}
],
"best_oa_location": {
"is_oa": true,
"landing_page_url": "https://doi.org/10.2475/ajs.290.2.164",
"pdf_url": "https://ajsonline.org/article/60519.pdf",
"source": {
"id": "https://openalex.org/S143179485",
"display_name": "American Journal of Science",
"issn_l": "0002-9599",
"issn": [
"0002-9599",
"1945-452X"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310315589",
"host_organization_name": "Yale University",
"host_organization_lineage": [
"https://openalex.org/P4310315589"
],
"host_organization_lineage_names": [
"Yale University"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": "publishedVersion",
"is_accepted": true,
"is_published": true
},
"biblio": {
"volume": "290",
"issue": "2",
"first_page": "164",
"last_page": "201"
},
"citation_normalized_percentile": {
"value": 0.987256,
"is_in_top_1_percent": false,
"is_in_top_10_percent": true
},
"cited_by_api_url": "https://api.openalex.org/works?filter=cites:W1981362259",
"cited_by_count": 198,
"cited_by_percentile_year": {
"min": 98,
"max": 99
},
"concepts": [
{
"id": "https://openalex.org/C184651966",
"wikidata": "https://www.wikidata.org/wiki/Q906356",
"display_name": "Aqueous solution",
"level": 2,
"score": 0.7644099
},
{
"id": "https://openalex.org/C2776359362",
"wikidata": "https://www.wikidata.org/wiki/Q2145286",
"display_name": "Representation (politics)",
"level": 3,
"score": 0.567256
},
{
"id": "https://openalex.org/C97355855",
"wikidata": "https://www.wikidata.org/wiki/Q11473",
"display_name": "Thermodynamics",
"level": 1,
"score": 0.5542992
},
{
"id": "https://openalex.org/C185592680",
"wikidata": "https://www.wikidata.org/wiki/Q2329",
"display_name": "Chemistry",
"level": 0,
"score": 0.36778393
},
{
"id": "https://openalex.org/C147789679",
"wikidata": "https://www.wikidata.org/wiki/Q11372",
"display_name": "Physical chemistry",
"level": 1,
"score": 0.2471514
},
{
"id": "https://openalex.org/C121332964",
"wikidata": "https://www.wikidata.org/wiki/Q413",
"display_name": "Physics",
"level": 0,
"score": 0.21990108
},
{
"id": "https://openalex.org/C94625758",
"wikidata": "https://www.wikidata.org/wiki/Q7163",
"display_name": "Politics",
"level": 2,
"score": 0.0
},
{
"id": "https://openalex.org/C17744445",
"wikidata": "https://www.wikidata.org/wiki/Q36442",
"display_name": "Political science",
"level": 0,
"score": 0.0
},
{
"id": "https://openalex.org/C199539241",
"wikidata": "https://www.wikidata.org/wiki/Q7748",
"display_name": "Law",
"level": 1,
"score": 0.0
}
],
"corresponding_author_ids": [],
"corresponding_institution_ids": [],
"countries_distinct_count": 0,
"counts_by_year": [
{
"year": 2024,
"cited_by_count": 1
},
{
"year": 2023,
"cited_by_count": 3
},
{
"year": 2022,
"cited_by_count": 7
},
{
"year": 2021,
"cited_by_count": 5
},
{
"year": 2020,
"cited_by_count": 6
},
{
"year": 2019,
"cited_by_count": 2
},
{
"year": 2018,
"cited_by_count": 10
},
{
"year": 2017,
"cited_by_count": 14
},
{
"year": 2016,
"cited_by_count": 6
},
{
"year": 2015,
"cited_by_count": 4
},
{
"year": 2014,
"cited_by_count": 8
},
{
"year": 2013,
"cited_by_count": 7
},
{
"year": 2012,
"cited_by_count": 16
}
],
"created_date": "2016-06-24",
"datasets": [],
"display_name": "Solid-solution aqueous-solution equilibria; thermodynamic theory and representation",
"doi": "https://doi.org/10.2475/ajs.290.2.164",
"fwci": 5.883,
"grants": [],
"has_fulltext": false,
"id": "https://openalex.org/W1981362259",
"ids": {
"openalex": "https://openalex.org/W1981362259",
"doi": "https://doi.org/10.2475/ajs.290.2.164",
"mag": "1981362259"
},
"indexed_in": [
"crossref"
],
"institutions_distinct_count": 0,
"is_paratext": false,
"is_retracted": false,
"keywords": [
{
"id": "https://openalex.org/keywords/aqueous-systems",
"display_name": "Aqueous Systems",
"score": 0.568473
},
{
"id": "https://openalex.org/keywords/stochastic-thermodynamics",
"display_name": "Stochastic Thermodynamics",
"score": 0.567761
},
{
"id": "https://openalex.org/keywords/representation",
"display_name": "Representation (politics)",
"score": 0.567256
},
{
"id": "https://openalex.org/keywords/nanoscale-thermodynamics",
"display_name": "Nanoscale Thermodynamics",
"score": 0.560768
},
{
"id": "https://openalex.org/keywords/thermodynamic-efficiency",
"display_name": "Thermodynamic Efficiency",
"score": 0.555197
},
{
"id": "https://openalex.org/keywords/nonequilibrium-systems",
"display_name": "Nonequilibrium Systems",
"score": 0.546473
}
],
"language": "en",
"locations": [
{
"is_oa": true,
"landing_page_url": "https://doi.org/10.2475/ajs.290.2.164",
"pdf_url": "https://ajsonline.org/article/60519.pdf",
"source": {
"id": "https://openalex.org/S143179485",
"display_name": "American Journal of Science",
"issn_l": "0002-9599",
"issn": [
"0002-9599",
"1945-452X"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310315589",
"host_organization_name": "Yale University",
"host_organization_lineage": [
"https://openalex.org/P4310315589"
],
"host_organization_lineage_names": [
"Yale University"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": "publishedVersion",
"is_accepted": true,
"is_published": true
}
],
"locations_count": 1,
"mesh": [],
"ngrams_url": "https://api.openalex.org/works/W1981362259/ngrams",
"open_access": {
"is_oa": true,
"oa_status": "bronze",
"oa_url": "https://ajsonline.org/article/60519.pdf",
"any_repository_has_fulltext": false
},
"primary_location": {
"is_oa": true,
"landing_page_url": "https://doi.org/10.2475/ajs.290.2.164",
"pdf_url": "https://ajsonline.org/article/60519.pdf",
"source": {
"id": "https://openalex.org/S143179485",
"display_name": "American Journal of Science",
"issn_l": "0002-9599",
"issn": [
"0002-9599",
"1945-452X"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310315589",
"host_organization_name": "Yale University",
"host_organization_lineage": [
"https://openalex.org/P4310315589"
],
"host_organization_lineage_names": [
"Yale University"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": "publishedVersion",
"is_accepted": true,
"is_published": true
},
"primary_topic": {
"id": "https://openalex.org/T11520",
"display_name": "Stochastic Thermodynamics and Fluctuation Theorems",
"score": 0.9478,
"subfield": {
"id": "https://openalex.org/subfields/3109",
"display_name": "Statistical and Nonlinear Physics"
},
"field": {
"id": "https://openalex.org/fields/31",
"display_name": "Physics and Astronomy"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
"publication_date": "1990-02-01",
"publication_year": 1990,
"referenced_works": [],
"referenced_works_count": 0,
"related_works": [
"https://openalex.org/W657579294",
"https://openalex.org/W4387497383",
"https://openalex.org/W2948807893",
"https://openalex.org/W2778153218",
"https://openalex.org/W2748952813",
"https://openalex.org/W2527526854",
"https://openalex.org/W2062208111",
"https://openalex.org/W1986764834",
"https://openalex.org/W1976181487",
"https://openalex.org/W1531601525"
],
"sustainable_development_goals": [],
"title": "Solid-solution aqueous-solution equilibria; thermodynamic theory and representation",
"topics": [
{
"id": "https://openalex.org/T11520",
"display_name": "Stochastic Thermodynamics and Fluctuation Theorems",
"score": 0.9478,
"subfield": {
"id": "https://openalex.org/subfields/3109",
"display_name": "Statistical and Nonlinear Physics"
},
"field": {
"id": "https://openalex.org/fields/31",
"display_name": "Physics and Astronomy"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T11177",
"display_name": "Quantum Coherence in Photosynthesis and Aqueous Systems",
"score": 0.9195,
"subfield": {
"id": "https://openalex.org/subfields/3107",
"display_name": "Atomic and Molecular Physics, and Optics"
},
"field": {
"id": "https://openalex.org/fields/31",
"display_name": "Physics and Astronomy"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
}
],
"type": "article",
"type_crossref": "journal-article",
"updated_date": "2024-08-08T17:52:59.585532",
"versions": []
}
}
