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{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Oxygen isotope fractionation in divalent metal carbonates", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70011501", "url": "https://pubs.usgs.gov/publication/70011501" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70011501 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1063/1.1671982", "url": "https://doi.org/10.1063/1.1671982" }, { "@type": "PropertyValue", "propertyID": "ISSN", "value": "00219606" } ], "journal": { "@type": "Periodical", "name": "Journal of Chemical Physics", "volumeNumber": "51", "issueNumber": "12" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Journal of Chemical Physics" } ], "datePublished": "1969", "dateModified": "2020-11-30", "abstract": "Equilibrium fractionation factors for the distribution of 18O between alkaline\u2010earth carbonates and water have been\u00a0measured\u00a0over the\u00a0temperature\u00a0range 0\u2013500\u00b0C. The fractionation factors\u00a0\u03b1\">\u03b1\u03b1\u00a0can be represented by the equationsCaCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.78(106T\u22122)\u2212\u20093.39,\">CaCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.78(106T\u22122)\u2212\u20093.39,CaCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.78(106T\u22122)\u2212\u20093.39,SrCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.69(106T\u22122)\u2212\u20093.74,\">SrCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.69(106T\u22122)\u2212\u20093.74,SrCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.69(106T\u22122)\u2212\u20093.74,BaCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.57(106T\u22122)\u2212\u20094.73.\">BaCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.57(106T\u22122)\u2212\u20094.73.BaCO3\u2013H2O, 1000ln\u03b1\u2009=\u20092.57(106T\u22122)\u2212\u20094.73.Measurements\u00a0on MnCO3, CdCO3, and PbCO3\u00a0were made at isolated\u00a0temperatures.\u00a0A statistical\u2010mechanical calculation of the isotopic partition function ratios gives reasonably good agreement with experiment. Both cationic size and mass are important in isotopic fractionation, the former predominantly in its\u00a0effect\u00a0on the internal vibrations of the anion, the latter in its\u00a0effect\u00a0on the\u00a0lattice vibrations.", "description": "12 p.", "publisher": { "@type": "Organization", "name": "American Institute of Physics" }, "author": [ { "@type": "Person", "name": "Mayeda, T.K.", "givenName": "T.K.", "familyName": "Mayeda" }, { "@type": "Person", "name": "Clayton, R.N.", "givenName": "R.N.", "familyName": "Clayton" }, { "@type": "Person", "name": "O'Neil, J. R.", "givenName": "J. R.", "familyName": "O'Neil" } ] }, "OpenAlex": { "_id": "https://openalex.org/w1970658925", "abstract_inverted_index": { "Equilibrium": [ 0 ], "fractionation": [ 1, 22 ], "factors": [ 2, 23 ], "for": [ 3 ], "the": [ 4, 17, 29, 63, 84, 91, 95, 97, 103 ], "distribution": [ 5 ], "of": [ 6, 62, 94 ], "18O": [ 7 ], "between": [ 8 ], "alkaline-earth": [ 9 ], "carbonates": [ 10 ], "and": [ 11, 52, 77 ], "water": [ 12 ], "have": [ 13 ], "been": [ 14 ], "measured": [ 15 ], "over": [ 16 ], "temperature": [ 18 ], "range": [ 19 ], "0\u2013500\u00b0C.": [ 20 ], "The": [ 21 ], "\u03b1": [ 24 ], "can": [ 25 ], "be": [ 26 ], "represented": [ 27 ], "by": [ 28 ], "equationsCaCO3\u2013H2O,": [ 30 ], "1000": [ 31, 37, 43 ], "ln\u03b1": [ 32, 38, 44 ], "=": [ 33, 39, 45 ], "2.78(106": [ 34 ], "T\u22122)\u2212": [ 35, 41, 47 ], "3.39,SrCO3\u2013H2O,": [ 36 ], "2.69(106": [ 40 ], "3.74,BaCO3\u2013H2O,": [ 42 ], "2.57(106": [ 46 ], "4.73.Measurements": [ 48 ], "on": [ 49, 90, 102 ], "MnCO3,": [ 50 ], "CdCO3,": [ 51 ], "PbCO3": [ 53 ], "were": [ 54 ], "made": [ 55 ], "at": [ 56 ], "isolated": [ 57 ], "temperatures.": [ 58 ], "A": [ 59 ], "statistical-mechanical": [ 60 ], "calculation": [ 61 ], "isotopic": [ 64, 82 ], "partition": [ 65 ], "function": [ 66 ], "ratios": [ 67 ], "gives": [ 68 ], "reasonably": [ 69 ], "good": [ 70 ], "agreement": [ 71 ], "with": [ 72 ], "experiment.": [ 73 ], "Both": [ 74 ], "cationic": [ 75 ], "size": [ 76 ], "mass": [ 78 ], "are": [ 79 ], "important": [ 80 ], "in": [ 81, 87, 99 ], "fractionation,": [ 83 ], "former": [ 85 ], "predominantly": [ 86 ], "its": [ 88, 100 ], "effect": [ 89, 101 ], "internal": [ 92 ], "vibrations": [ 93 ], "anion,": [ 96 ], "latter": [ 98 ], "lattice": [ 104 ], "vibrations.": [ 105 ] }, "apc_list": { "value": 3500, "currency": "USD", "value_usd": 3500, "provenance": "doaj" }, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5050618858", "display_name": "James R. 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