Item talk:Q273230
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Geology and genesis of the Shalipayco evaporite-related Mississippi Valley-type Zn\u2013Pb deposit, Central Peru: 3D geological modeling and C\u2013O\u2013S\u2013Sr isotope constraints", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70217190", "url": "https://pubs.usgs.gov/publication/70217190" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70217190 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1007/s00126-020-01029-w", "url": "https://doi.org/10.1007/s00126-020-01029-w" } ], "journal": { "@type": "Periodical", "name": "Mineralium Deposita", "volumeNumber": "56", "issueNumber": null }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Mineralium Deposita" } ], "datePublished": "2021", "dateModified": "2021-10-18", "abstract": "The Shalipayco Zn\u2013Pb deposit, in central Peru, is composed of several stratabound orebodies, the largest of which are the Resurgidora and Intermedios, contained in carbonate rocks of the Upper Triassic Chambar\u00e1 Formation, Pucar\u00e1 group. Petrography suggests that a single ore-forming episode formed sphalerite and galena within vugs, open spaces, and fractures. Three-dimensional (3D) geological modeling has allowed division of the Chambar\u00e1 Formation into four members (Chambar\u00e1 I, II, III, and IV) that better define lithological controls on sulfide formation. Diagenetic replacement of evaporite minerals with the organic matter (OM) presence likely generated secondary porosity and H2S accumulation by bacterial sulfate reduction (BSR), providing ground preparation for the later Zn\u2013Pb mineralizing event. The least-altered host rocks have C\u2013O isotope compositions of 1.8\u2009\u00b1\u20090.1\u2030 (VPDB) and 29.9\u2009\u00b1\u20092.1\u2030 (VSMOW), respectively, within the Triassic marine carbonate ranges. Early dolomite contains lighter C\u2013O composition (1.1\u2009\u00b1\u20090.9 and 23.8\u2009\u00b1\u20092.9\u2030, respectively) consistent with OM decomposition during burial diagenesis. Post-mineralization calcite has still lighter C\u2013O composition (\u2212\u20095.1 and 13.3\u2030, respectively), suggesting meteoric water that had migrated through organic-rich strata. The strontium isotopes of Mitu group basalts (0.709654\u20130.719669) indicate it as a possible, but not the unique source of strontium and probably of other metals. Highly negative sulfide sulfur isotope values (\u2212\u200923.3 to \u2212\u20096.2\u2030 (VCDT)) indicate a major component of the ore sulfur derived ultimately from BSR. However, multiple lines of evidence suggest that preexisting H2S underwent thermochemical redox cycling prior to ore formation. 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