Item talk:Q269583
From geokb
{
"USGS Publications Warehouse": {
"@context": "https://schema.org",
"@type": "Article",
"additionalType": "Journal Article",
"name": "Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano, Hawaii",
"identifier": [
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse IndexID",
"value": "70011692",
"url": "https://pubs.usgs.gov/publication/70011692"
},
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse Internal ID",
"value": 70011692
},
{
"@type": "PropertyValue",
"propertyID": "DOI",
"value": "10.1016/0016-7037(82)90024-2",
"url": "https://doi.org/10.1016/0016-7037(82)90024-2"
},
{
"@type": "PropertyValue",
"propertyID": "ISSN",
"value": "00167037"
}
],
"journal": {
"@type": "Periodical",
"name": "Geochimica et Cosmochimica Acta",
"volumeNumber": "46",
"issueNumber": "5"
},
"inLanguage": "en",
"isPartOf": [
{
"@type": "CreativeWorkSeries",
"name": "Geochimica et Cosmochimica Acta"
}
],
"datePublished": "1982",
"dateModified": "2024-03-18",
"abstract": "Eighteen basalts and some volcanic gases from the submarine and subaerial parts of Kilauea volcano were analyzed for the concentration and isotope ratios of sulfur. By means of a newly developed technique, sulfide and sulfate sulfur in the basalts were separately but simultaneously determined. The submarine basalt has 700 \u00b1 100 ppm total sulfur with\u00a0\u03b434S\u03a3s\u00a0of\u00a0\u20300.7 \u00b1 0.1 \u2030. The sulfate/sulfide molar ratio ranges from 0.15 to 0.56 and the fractionation factor between sulfate and sulfide is\u00a0\u2030+7.5 \u00b1 1.5\u2030. On the other hand, the concentration and\u00a0\u03b434S\u03a3s\u00a0values of the total sulfur in the subaerial basalt are reduced to 150 \u00b1 50 ppm and\u00a0\u2030\u22120.8 \u00b1 0.2\u2030, respectively. The sulfate to sulfide ratio and the fractionation factor between them are also smaller, 0.01 to 0.25 and +3.0\u2030, respectively. Chemical and isotopic evidence strongly suggests that sulfate and sulfide in the submarine basalt are in chemical and isotopic equilibria with each other at magmatic conditions. Their relative abundance and the isotope fractionation factors may be used to estimate the \u0192o2\u00a0and temperature of these basalts at the time of their extrusion onto the sea floor. The observed change in sulfur chemistry and isotopic ratios from the submarine to subaerial basalts can be interpreted as degassing of the SO2\u00a0from basalt thereby depleting sulfate and\u00a034S in basalt.The volcanic sulfur gases, predominantly SO2, from the 1971 and 1974 fissures in Kilauea Crater have\u00a0\u03b434S\u00a0values of 0.8 to 0.9%., slightly heavier than the total sulfur in the submarine basalts and definitely heavier than the subaerial basalts, in accord with the above model. However, the\u00a0\u03b434S\u00a0value of sulfur gases (largely SO2) from Sulfur Bank is 8.0%., implying a secondary origin of the sulfur. The\u00a0\u03b434S\u00a0values of native sulfur deposits at various sites of Kilauea and Mauna Loa volcanos, sulfate ions of four deep wells and hydrogen sulfide from a geothermal well along the east rift zone are also reported. The high\u00a0\u03b434S\u00a0values (+5 to +6%.o) found for the hydrogen sulfide might be an indication of hot basalt seawater reaction beneath the east rift zone.",
"description": "10 p.",
"publisher": {
"@type": "Organization",
"name": "Elsevier"
},
"author": [
{
"@type": "Person",
"name": "Moore, J. G.",
"givenName": "J. G.",
"familyName": "Moore"
},
{
"@type": "Person",
"name": "Sakai, H.",
"givenName": "H.",
"familyName": "Sakai"
},
{
"@type": "Person",
"name": "Casadevall, T. J.",
"givenName": "T. J.",
"familyName": "Casadevall"
}
],
"funder": [
{
"@type": "Organization",
"name": "Hawaiian Volcano Observatory",
"url": "https://www.usgs.gov/observatories/hvo"
}
]
},
"OpenAlex": {
"_id": "https://openalex.org/W1990322558",
"abstract_inverted_index": {
"Abstract": [
0
],
"Eighteen": [
3
],
"basalts": [
4,
41,
209,
234,
284
],
"and": [
5,
12,
23,
36,
79,
85,
103,
121,
137,
149,
153,
160,
169,
181,
205,
226,
248,
262,
285,
331,
341
],
"some": [
6
],
"volcanic": [
7,
254
],
"gases": [
8,
304
],
"from": [
9,
75,
229,
243,
259,
307,
344
],
"the": [
10,
21,
40,
80,
98,
101,
107,
111,
138,
163,
182,
191,
211,
217,
230,
241,
260,
278,
282,
289,
295,
299,
317,
349,
365,
377
],
"submarine": [
11,
48,
164,
231,
283
],
"subaerial": [
13,
112,
233,
290
],
"parts": [
14
],
"of": [
15,
26,
30,
59,
106,
207,
213,
240,
271,
302,
316,
322,
329,
337,
372
],
"Kilauea": [
16,
266,
330
],
"volcano": [
17
],
"were": [
18,
42
],
"analyzed": [
19
],
"for": [
20,
364
],
"concentration": [
22,
102
],
"isotope": [
24,
183
],
"ratios": [
25,
228
],
"sulfur.": [
27,
318
],
"By": [
28
],
"means": [
29
],
"a": [
31,
313,
345
],
"newly": [
32
],
"developed": [
33
],
"technique,": [
34
],
"sulfide": [
35,
86,
135,
161,
343,
367
],
"sulfate": [
37,
84,
133,
159,
247,
335
],
"sulfur": [
38,
56,
109,
224,
255,
280,
303,
324
],
"in": [
39,
110,
162,
167,
223,
250,
265,
281,
292
],
"separately": [
43
],
"but": [
44
],
"simultaneously": [
45
],
"determined.": [
46
],
"The": [
47,
70,
132,
220,
253,
319,
356
],
"basalt": [
49,
113,
165,
244
],
"has": [
50
],
"700": [
51
],
"\u00b1": [
52,
64,
92,
118,
126
],
"100": [
53
],
"ppm": [
54,
120
],
"total": [
55,
108,
279
],
"with": [
57,
172,
294
],
"\u03b434S\u03a3s": [
58,
104
],
"0.7": [
63
],
"0.1": [
65
],
"\u2030": [
66
],
".": [
69,
96
],
"sulfate/sulfide": [
71
],
"molar": [
72
],
"ratio": [
73,
136
],
"ranges": [
74
],
"0.15": [
76
],
"to": [
77,
116,
134,
147,
189,
232,
273,
361
],
"0.56": [
78
],
"fractionation": [
81,
139,
184
],
"factor": [
82,
140
],
"between": [
83,
141
],
"is": [
87,
310
],
"+7.5": [
91
],
"1.5\u2030": [
93
],
"On": [
97
],
"other": [
99,
174
],
"hand,": [
100
],
"values": [
105,
270,
321,
359
],
"are": [
114,
143,
166,
353
],
"reduced": [
115
],
"150": [
117
],
"50": [
119
],
"\u22120.8": [
125
],
"0.2\u2030": [
127
],
",": [
130
],
"respectively.": [
131,
151
],
"them": [
142
],
"also": [
144,
354
],
"smaller,": [
145
],
"0.01": [
146
],
"0.25": [
148
],
"+3.0\u2030,": [
150
],
"Chemical": [
152
],
"isotopic": [
154,
170,
227
],
"evidence": [
155
],
"strongly": [
156
],
"suggests": [
157
],
"that": [
158
],
"chemical": [
168
],
"equilibria": [
171
],
"each": [
173
],
"at": [
175,
210,
326
],
"magmatic": [
176
],
"conditions.": [
177
],
"Their": [
178
],
"relative": [
179
],
"abundance": [
180
],
"factors": [
185
],
"may": [
186
],
"be": [
187,
236,
369
],
"used": [
188
],
"estimate": [
190
],
"\u0192o": [
195
],
"2": [
200
],
"temperature": [
206
],
"these": [
208
],
"time": [
212
],
"their": [
214
],
"extrusion": [
215
],
"onto": [
216
],
"sea": [
218
],
"floor.": [
219
],
"observed": [
221
],
"change": [
222
],
"chemistry": [
225
],
"can": [
235
],
"interpreted": [
237
],
"as": [
238
],
"degassing": [
239
],
"SO2": [
242
],
"thereby": [
245
],
"depleting": [
246
],
"34S": [
249
],
"basalt.": [
251
],
"gases,": [
256
],
"predominantly": [
257
],
"SO2,": [
258
],
"1971": [
261
],
"1974": [
263
],
"fissures": [
264
],
"Crater": [
267
],
"have": [
268
],
"\u03b434S": [
269,
300,
320,
358
],
"0.8": [
272
],
"0.9%.,": [
274
],
"slightly": [
275
],
"heavier": [
276,
287
],
"than": [
277,
288
],
"definitely": [
286
],
"basalts,": [
291
],
"accord": [
293
],
"above": [
296
],
"model.": [
297
],
"However,": [
298
],
"value": [
301
],
"(largely": [
305
],
"SO2)": [
306
],
"Sulfur": [
308
],
"Bank": [
309
],
"8.0%.,": [
311
],
"implying": [
312
],
"secondary": [
314
],
"origin": [
315
],
"native": [
323
],
"deposits": [
325
],
"various": [
327
],
"sites": [
328
],
"Mauna": [
332
],
"Loa": [
333
],
"volcanos,": [
334
],
"ions": [
336
],
"four": [
338
],
"deep": [
339
],
"wells": [
340
],
"hydrogen": [
342,
366
],
"geothermal": [
346
],
"well": [
347
],
"along": [
348
],
"east": [
350,
378
],
"rift": [
351,
379
],
"zone": [
352
],
"reported.": [
355
],
"high": [
357
],
"(+5": [
360
],
"+6%.o)": [
362
],
"found": [
363
],
"might": [
368
],
"an": [
370
],
"indication": [
371
],
"hot": [
373
],
"basaltseawater": [
374
],
"reaction": [
375
],
"beneath": [
376
],
"zone.": [
380
]
},
"apc_list": {
"value": 3690,
"currency": "USD",
"value_usd": 3690,
"provenance": "doaj"
},
"apc_paid": null,
"authorships": [
{
"author_position": "first",
"author": {
"id": "https://openalex.org/A5101634056",
"display_name": "Hitoshi Sakai",
"orcid": "https://orcid.org/0009-0005-3326-2511"
},
"institutions": [
{
"id": "https://openalex.org/I163770644",
"display_name": "Okayama University",
"ror": "https://ror.org/02pc6pc55",
"country_code": "JP",
"type": "education",
"lineage": [
"https://openalex.org/I163770644"
]
}
],
"countries": [
"JP"
],
"is_corresponding": false,
"raw_author_name": "Hitoshi Sakai",
"raw_affiliation_strings": [
"Institute for Thermal Spring Research, Okayama University, Misasa, Tottori-ken, Japan 682-02"
],
"affiliations": [
{
"raw_affiliation_string": "Institute for Thermal Spring Research, Okayama University, Misasa, Tottori-ken, Japan 682-02",
"institution_ids": [
"https://openalex.org/I163770644"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5024000862",
"display_name": "Thomas J. Casadevall",
"orcid": "https://orcid.org/0000-0002-9447-6864"
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Thomas J. Casadevall Casadevall",
"raw_affiliation_strings": [
"Hawaii Volcano Observatory, U.S. Geological Survey, Hawaii National Park, Hawaii 96718, U.S.A."
],
"affiliations": [
{
"raw_affiliation_string": "Hawaii Volcano Observatory, U.S. Geological Survey, Hawaii National Park, Hawaii 96718, U.S.A.",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
},
{
"author_position": "last",
"author": {
"id": "https://openalex.org/A5085860098",
"display_name": "James G. Moore",
"orcid": "https://orcid.org/0000-0002-7543-2401"
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "James G. Moore",
"raw_affiliation_strings": [
"U. S. Geological Survey, Menlo Park, California 94025 U.S.A."
],
"affiliations": [
{
"raw_affiliation_string": "U. S. Geological Survey, Menlo Park, California 94025 U.S.A.",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
}
],
"best_oa_location": null,
"biblio": {
"volume": "46",
"issue": "5",
"first_page": "729",
"last_page": "738"
},
"cited_by_api_url": "https://api.openalex.org/works?filter=cites:W1990322558",
"cited_by_count": 160,
"cited_by_percentile_year": {
"min": 98,
"max": 99
},
"concepts": [
{
"id": "https://openalex.org/c120806208",
"wikidata": "https://www.wikidata.org/wiki/Q8072",
"display_name": "Volcano",
"level": 2,
"score": 0.87492317,
"qid": null
},
{
"id": "https://openalex.org/c161509811",
"wikidata": "https://www.wikidata.org/wiki/Q43338",
"display_name": "Basalt",
"level": 2,
"score": 0.75902015,
"qid": "Q41826"
},
{
"id": "https://openalex.org/c2908550418",
"wikidata": "https://www.wikidata.org/wiki/Q552571",
"display_name": "Volcanic Gases",
"level": 3,
"score": 0.714537,
"qid": null
},
{
"id": "https://openalex.org/c17409809",
"wikidata": "https://www.wikidata.org/wiki/Q161764",
"display_name": "Geochemistry",
"level": 1,
"score": 0.634573,
"qid": "Q158980"
},
{
"id": "https://openalex.org/c1965285",
"wikidata": "https://www.wikidata.org/wiki/Q8008",
"display_name": "Earth science",
"level": 1,
"score": 0.5939028,
"qid": "Q158971"
},
{
"id": "https://openalex.org/c518881349",
"wikidata": "https://www.wikidata.org/wiki/Q682",
"display_name": "Sulfur",
"level": 2,
"score": 0.56329024,
"qid": "Q384"
},
{
"id": "https://openalex.org/c127313418",
"wikidata": "https://www.wikidata.org/wiki/Q1069",
"display_name": "Geology",
"level": 0,
"score": 0.5372287,
"qid": "Q158984"
},
{
"id": "https://openalex.org/c164304813",
"wikidata": "https://www.wikidata.org/wiki/Q25276",
"display_name": "Isotope",
"level": 2,
"score": 0.4420872,
"qid": null
},
{
"id": "https://openalex.org/c113754120",
"wikidata": "https://www.wikidata.org/wiki/Q40157",
"display_name": "Lava",
"level": 3,
"score": 0.42566538,
"qid": null
},
{
"id": "https://openalex.org/c185592680",
"wikidata": "https://www.wikidata.org/wiki/Q2329",
"display_name": "Chemistry",
"level": 0,
"score": 0.4142862,
"qid": "Q166089"
},
{
"id": "https://openalex.org/c185544564",
"wikidata": "https://www.wikidata.org/wiki/Q81197",
"display_name": "Nuclear physics",
"level": 1,
"score": 0.06441745,
"qid": "Q226283"
},
{
"id": "https://openalex.org/c178790620",
"wikidata": "https://www.wikidata.org/wiki/Q11351",
"display_name": "Organic chemistry",
"level": 1,
"score": 0.0,
"qid": "Q166197"
},
{
"id": "https://openalex.org/c121332964",
"wikidata": "https://www.wikidata.org/wiki/Q413",
"display_name": "Physics",
"level": 0,
"score": 0.0,
"qid": "Q166093"
}
],
"corresponding_author_ids": [],
"corresponding_institution_ids": [],
"countries_distinct_count": 2,
"counts_by_year": [
{
"year": 2024,
"cited_by_count": 6
},
{
"year": 2023,
"cited_by_count": 6
},
{
"year": 2022,
"cited_by_count": 3
},
{
"year": 2021,
"cited_by_count": 11
},
{
"year": 2020,
"cited_by_count": 4
},
{
"year": 2019,
"cited_by_count": 4
},
{
"year": 2018,
"cited_by_count": 6
},
{
"year": 2017,
"cited_by_count": 3
},
{
"year": 2016,
"cited_by_count": 2
},
{
"year": 2015,
"cited_by_count": 4
},
{
"year": 2014,
"cited_by_count": 5
},
{
"year": 2013,
"cited_by_count": 4
},
{
"year": 2012,
"cited_by_count": 3
}
],
"created_date": "2016-06-24",
"datasets": [],
"display_name": "Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano, Hawaii",
"doi": "https://doi.org/10.1016/0016-7037(82)90024-2",
"fulltext_origin": "ngrams",
"fwci": 12.11,
"grants": [],
"has_fulltext": true,
"id": "https://openalex.org/W1990322558",
"ids": {
"openalex": "https://openalex.org/W1990322558",
"doi": "https://doi.org/10.1016/0016-7037(82)90024-2",
"mag": "1990322558"
},
"indexed_in": [
"crossref"
],
"institutions_distinct_count": 2,
"is_paratext": false,
"is_retracted": false,
"keywords": [
{
"id": "https://openalex.org/keywords/volcanic-gases",
"display_name": "Volcanic Gases",
"score": 0.714537
},
{
"id": "https://openalex.org/keywords/water-quality",
"display_name": "Water Quality",
"score": 0.402497
}
],
"language": "en",
"locations": [
{
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/0016-7037(82)90024-2",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
}
],
"locations_count": 1,
"mesh": [],
"ngrams_url": "https://api.openalex.org/works/W1990322558/ngrams",
"open_access": {
"is_oa": false,
"oa_status": "closed",
"oa_url": null,
"any_repository_has_fulltext": false
},
"primary_location": {
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/0016-7037(82)90024-2",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
},
"primary_topic": {
"id": "https://openalex.org/T10398",
"display_name": "Stable Isotope Analysis of Groundwater and Precipitation",
"score": 0.9966,
"subfield": {
"id": "https://openalex.org/subfields/1906",
"display_name": "Geochemistry and Petrology"
},
"field": {
"id": "https://openalex.org/fields/19",
"display_name": "Earth and Planetary Sciences"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
"publication_date": "1982-05-01",
"publication_year": 1982,
"referenced_works": [
"https://openalex.org/W1535539135",
"https://openalex.org/W1969405693",
"https://openalex.org/W1971600926",
"https://openalex.org/W1972862584",
"https://openalex.org/W1979148089",
"https://openalex.org/W1994723472",
"https://openalex.org/W1997967270",
"https://openalex.org/W1999444127",
"https://openalex.org/W2007492582",
"https://openalex.org/W2010170309",
"https://openalex.org/W2016458399",
"https://openalex.org/W2022311425",
"https://openalex.org/W2022552529",
"https://openalex.org/W2032495803",
"https://openalex.org/W2054227193",
"https://openalex.org/W2059132518",
"https://openalex.org/W2062389607",
"https://openalex.org/W2066154623",
"https://openalex.org/W2073012543",
"https://openalex.org/W2076702980",
"https://openalex.org/W2079137305",
"https://openalex.org/W2090764219",
"https://openalex.org/W2091891080",
"https://openalex.org/W2097756509",
"https://openalex.org/W2102148551",
"https://openalex.org/W2109221183",
"https://openalex.org/W2212178433",
"https://openalex.org/W2268175363",
"https://openalex.org/W2328806222",
"https://openalex.org/W2424119641",
"https://openalex.org/W2561562271",
"https://openalex.org/W2972510377",
"https://openalex.org/W3124647335",
"https://openalex.org/W4210873307",
"https://openalex.org/W80621457"
],
"referenced_works_count": 35,
"related_works": [
"https://openalex.org/W4212913516",
"https://openalex.org/W35690215",
"https://openalex.org/W3211145083",
"https://openalex.org/W2885319399",
"https://openalex.org/W2564934923",
"https://openalex.org/W2524526054",
"https://openalex.org/W2134931224",
"https://openalex.org/W2014367936",
"https://openalex.org/W2011988295",
"https://openalex.org/W2006660804"
],
"sustainable_development_goals": [
{
"id": "https://metadata.un.org/sdg/14",
"display_name": "Life below water",
"score": 0.88
}
],
"title": "Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano, Hawaii",
"topics": [
{
"id": "https://openalex.org/T10398",
"display_name": "Stable Isotope Analysis of Groundwater and Precipitation",
"score": 0.9966,
"subfield": {
"id": "https://openalex.org/subfields/1906",
"display_name": "Geochemistry and Petrology"
},
"field": {
"id": "https://openalex.org/fields/19",
"display_name": "Earth and Planetary Sciences"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T10017",
"display_name": "Climate Change and Paleoclimatology",
"score": 0.9957,
"subfield": {
"id": "https://openalex.org/subfields/1902",
"display_name": "Atmospheric Science"
},
"field": {
"id": "https://openalex.org/fields/19",
"display_name": "Earth and Planetary Sciences"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T10109",
"display_name": "Paleoredox and Paleoproductivity Proxies",
"score": 0.9931,
"subfield": {
"id": "https://openalex.org/subfields/1911",
"display_name": "Paleontology"
},
"field": {
"id": "https://openalex.org/fields/19",
"display_name": "Earth and Planetary Sciences"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
}
],
"type": "article",
"type_crossref": "journal-article",
"updated_date": "2024-08-10T15:28:52.970395",
"versions": [],
"qid": null
}
}
