Item talk:Q269579
From geokb
{
"USGS Publications Warehouse": {
"@context": "https://schema.org",
"@type": "Article",
"additionalType": "Journal Article",
"name": "The solubility of BaCO3(cr) (witherite) in CO2-H2O solutions between 0 and 90\u00b0C, evaluation of the association constants of BaHCO3+(aq) and BaCO30(aq) between 5 and 80\u00b0C, and a preliminary evaluation of the thermodynamic properties of Ba2+(aq)",
"identifier": [
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse IndexID",
"value": "70015035",
"url": "https://pubs.usgs.gov/publication/70015035"
},
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse Internal ID",
"value": 70015035
},
{
"@type": "PropertyValue",
"propertyID": "DOI",
"value": "10.1016/0016-7037(86)90077-3",
"url": "https://doi.org/10.1016/0016-7037(86)90077-3"
},
{
"@type": "PropertyValue",
"propertyID": "ISSN",
"value": "00167037"
}
],
"journal": {
"@type": "Periodical",
"name": "Geochimica et Cosmochimica Acta",
"volumeNumber": "50",
"issueNumber": "10"
},
"inLanguage": "en",
"isPartOf": [
{
"@type": "CreativeWorkSeries",
"name": "Geochimica et Cosmochimica Acta"
}
],
"datePublished": "1986",
"dateModified": "2018-03-21",
"abstract": "One hundred and fifty new measurements of the solubility of witherite were used to evaluate the equilibrium constant of the reaction\u00a0BaCO3(cr) =\u00a0Ba2+(aq) +\u00a0CO32\u2212(aq) between 0 and 90\u00b0C and 1 atm total pressure. The temperature dependence of the equilibrium constant is given by\u00a0logK\u00a0= 607.642 + 0.121098T\u00a0\u2212 20011.25/T\u00a0\u2212 236.4948\u00a0logT\u00a0where\u00a0T\u00a0is in degrees Kelvin. The\u00a0logK\u00a0of BaCO3(cr), the Gibbs energy, the enthalpy and entropy of the reaction at 298.15 K are \u22128.562, 48.87 kJ \u00b7 mol\u22121, 2.94 kJ \u00b7 mol\u22121and \u2212154.0 J \u00b7 mol\u22121\u00a0\u00b7 K\u22121, respectively. The equilibrium constants are consistent with an aqueous model that includes the ion pairs BaHCO3+(aq) and BaCO30(aq) Three different methods were used to evaluate the association constant of BaHCO3+(aq), and all yielded similar results. The temperature dependence of the association constant for the reaction\u00a0Ba2+(aq) +\u00a0HCO3\u2212(aq) =\u00a0BaHCO3+(aq) is given by\u00a0logKBaHCO3+\u00a0= \u22123.0938 + 0.013669T.\nThe log of the association constant, the Gibbs energy, the enthalpy and entropy of the reaction at 298.15\u00b0K are 0.982, \u22125.606 kJ \u00b7 mol\u22121, 23.26 kJ \u00b7 mol\u22121\u00a0and 96.8 J \u00b7 mol\u22121\u00a0\u00b7 K\u22121, respectively. The temperature dependence of the equilibrium constant for the reaction\u00a0Ba2+(aq) +\u00a0CO2\u22123(aq) =\u00a0BaCO03(aq) is given bylogKBaCO30\u00a0= 0.113 + 0.008721T.\nThe log of the association constant, the Gibbs energy, the enthalpy and entropy of the reaction at 298.15\u00b0 K are 2.71, \u221215.49 kJ \u00b7 mol\u22121, 14.84 kJ \u00b7 mol\u22121\u00a0and 101.7 J\u00b7 mol\u22121\u00a0\u00b7 K\u22121.\nThe above model leads to reliable calculations of the aqueous speciation and solubility of witherite in the system BaCO3-CO2-H2O from 0 to more than 90\u00b0C. Literature data on witherite solubility were re-evaluated and compared with the results of this study.\nProblems in the thennodynamic selections of Ba compounds are considered. Newer data require the revision of \u0394fH\u00b0 and \u0394fG\u00b0 of Ba2+(aq) to \u2212532.5 and \u2212555.36 kJ \u00b7 mol\u22121, respectively, for agreement with solubility data.",
"description": "9 p.",
"publisher": {
"@type": "Organization",
"name": "Elsevier"
},
"author": [
{
"@type": "Person",
"name": "Busenberg, Eurybiades ebusenbe@usgs.gov",
"givenName": "Eurybiades",
"familyName": "Busenberg",
"email": "ebusenbe@usgs.gov",
"affiliation": [
{
"@type": "Organization",
"name": "National Research Program - Eastern Branch",
"url": "https://www.usgs.gov/centers/arizona-water-science-center"
}
]
},
{
"@type": "Person",
"name": "Plummer, Niel nplummer@usgs.gov",
"givenName": "Niel",
"familyName": "Plummer",
"email": "nplummer@usgs.gov",
"identifier": {
"@type": "PropertyValue",
"propertyID": "ORCID",
"value": "0000-0002-4020-1013",
"url": "https://orcid.org/0000-0002-4020-1013"
},
"affiliation": [
{
"@type": "Organization",
"name": "National Research Program - Eastern Branch",
"url": "https://www.usgs.gov/centers/arizona-water-science-center"
}
]
}
]
},
"OpenAlex": {
"_id": "https://openalex.org/w2047953929",
"abstract_inverted_index": {
"One": [
0
],
"hundred": [
1
],
"and": [
2,
28,
30,
70,
88,
111,
125,
164,
181,
223,
241,
258,
279,
304,
310
],
"fifty": [
3
],
"new": [
4
],
"measurements": [
5
],
"of": [
6,
9,
18,
38,
63,
72,
123,
133,
155,
166,
192,
214,
225,
254,
260,
284,
292,
302,
306
],
"the": [
7,
15,
19,
39,
65,
68,
73,
107,
120,
134,
138,
156,
159,
162,
167,
193,
197,
215,
218,
221,
226,
255,
263,
282,
289,
300
],
"solubility": [
8,
259,
276,
319
],
"witherite": [
10,
261,
275
],
"were": [
11,
116,
277
],
"used": [
12,
117
],
"to": [
13,
118,
251,
268,
308
],
"evaluate": [
14,
119
],
"equilibrium": [
16,
40,
97,
194
],
"constant": [
17,
41,
122,
136,
195
],
"reaction": [
20,
74,
139,
168,
198,
227
],
"BaCO3(cr)": [
21
],
"=": [
22,
46,
143,
149,
202,
208
],
"Ba2+(aq)": [
23,
140,
199,
307
],
"+": [
24,
48,
141,
151,
200,
210
],
"CO32\u2212(aq)": [
25
],
"between": [
26
],
"0": [
27,
267
],
"90\u00b0C": [
29
],
"1": [
31
],
"atm": [
32
],
"total": [
33
],
"pressure.": [
34
],
"The": [
35,
61,
96,
130,
153,
189,
212,
247
],
"temperature": [
36,
131,
190
],
"dependence": [
37,
132,
191
],
"is": [
42,
57,
145,
204
],
"given": [
43,
146,
205
],
"by": [
44,
147,
206
],
"logK": [
45,
62
],
"607.642": [
47
],
"0.121098T": [
49
],
"\u2212": [
50,
52
],
"20011.25/T": [
51
],
"236.4948": [
53
],
"logT": [
54
],
"where": [
55
],
"T": [
56
],
"in": [
58,
262,
288
],
"degrees": [
59
],
"Kelvin.": [
60
],
"BaCO3(cr),": [
64
],
"Gibbs": [
66,
160,
219
],
"energy,": [
67,
161,
220
],
"enthalpy": [
69,
163,
222
],
"entropy": [
71,
165,
224
],
"at": [
75,
169,
228
],
"298.15": [
76
],
"K": [
77,
230
],
"are": [
78,
99,
171,
231,
295
],
"\u22128.562,": [
79
],
"48.87": [
80
],
"kJ": [
81,
85,
174,
178,
234,
238,
312
],
"\u00b7": [
82,
86,
91,
93,
175,
179,
184,
186,
235,
239,
245,
313
],
"mol\u22121,": [
83,
176,
236,
314
],
"2.94": [
84
],
"mol\u22121": [
87,
92,
180,
185,
240,
244
],
"\u2212154.0": [
89
],
"J": [
90,
183
],
"K\u22121,": [
94,
187
],
"respectively.": [
95,
188
],
"constants": [
98
],
"consistent": [
100
],
"with": [
101,
281,
318
],
"an": [
102
],
"aqueous": [
103,
256
],
"model": [
104,
249
],
"that": [
105
],
"includes": [
106
],
"ion": [
108
],
"pairs": [
109
],
"BaHCO3+(aq)": [
110,
144
],
"BaCO30(aq)": [
112
],
"Three": [
113
],
"different": [
114
],
"methods": [
115
],
"association": [
121,
135,
157,
216
],
"BaHCO3+(aq),": [
124
],
"all": [
126
],
"yielded": [
127
],
"similar": [
128
],
"results.": [
129
],
"for": [
137,
196,
316
],
"HCO3\u2212(aq)": [
142
],
"logKBaHCO3+": [
148
],
"\u22123.0938": [
150
],
"0.013669T.": [
152
],
"log": [
154,
213
],
"constant,": [
158,
217
],
"298.15\u00b0K": [
170
],
"0.982,": [
172
],
"\u22125.606": [
173
],
"23.26": [
177
],
"96.8": [
182
],
"CO2\u22123(aq)": [
201
],
"BaCO03(aq)": [
203
],
"logKBaCO30": [
207
],
"0.113": [
209
],
"0.008721T.": [
211
],
"298.15\u00b0": [
229
],
"2.71,": [
232
],
"\u221215.49": [
233
],
"14.84": [
237
],
"101.7": [
242
],
"J\u00b7": [
243
],
"K\u22121.": [
246
],
"above": [
248
],
"leads": [
250
],
"reliable": [
252
],
"calculations": [
253
],
"speciation": [
257
],
"system": [
264
],
"BaCO3-CO2-H2O": [
265
],
"from": [
266
],
"more": [
269
],
"than": [
270
],
"90\u00b0C.": [
271
],
"Literature": [
272
],
"data": [
273,
298
],
"on": [
274
],
"re-evaluated": [
278
],
"compared": [
280
],
"results": [
283
],
"this": [
285
],
"study.": [
286
],
"Problems": [
287
],
"thennodynamic": [
290
],
"selections": [
291
],
"Ba": [
293
],
"compounds": [
294
],
"considered.": [
296
],
"Newer": [
297
],
"require": [
299
],
"revision": [
301
],
"\u0394fH\u00b0": [
303
],
"\u0394fG\u00b0": [
305
],
"\u2212532.5": [
309
],
"\u2212555.36": [
311
],
"respectively,": [
315
],
"agreement": [
317
],
"data.": [
320
]
},
"apc_list": {
"value": 3690,
"currency": "USD",
"value_usd": 3690,
"provenance": "doaj"
},
"apc_paid": null,
"authorships": [
{
"author_position": "first",
"author": {
"id": "https://openalex.org/A5037997406",
"display_name": "Eurybiades Busenberg",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Eurybiades Busenberg",
"raw_affiliation_strings": [
"U.S. Geological Survey, Mail Stop 432, Reston, VA 22092 U.S.A."
],
"affiliations": [
{
"raw_affiliation_string": "U.S. Geological Survey, Mail Stop 432, Reston, VA 22092 U.S.A.",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
},
{
"author_position": "last",
"author": {
"id": "https://openalex.org/A5074715793",
"display_name": "Niel Plummer",
"orcid": "https://orcid.org/0000-0002-4020-1013"
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "L.Niel Plummer",
"raw_affiliation_strings": [
"U.S. Geological Survey, Mail Stop 432, Reston, VA 22092 U.S.A."
],
"affiliations": [
{
"raw_affiliation_string": "U.S. Geological Survey, Mail Stop 432, Reston, VA 22092 U.S.A.",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
}
],
"best_oa_location": null,
"biblio": {
"volume": "50",
"issue": "10",
"first_page": "2225",
"last_page": "2233"
},
"citation_normalized_percentile": {
"value": 0.90553,
"is_in_top_1_percent": false,
"is_in_top_10_percent": true
},
"cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2047953929",
"cited_by_count": 56,
"cited_by_percentile_year": {
"min": 94,
"max": 95
},
"concepts": [
{
"id": "https://openalex.org/C3288061",
"wikidata": "https://www.wikidata.org/wiki/Q161064",
"display_name": "Enthalpy",
"level": 2,
"score": 0.82473576
},
{
"id": "https://openalex.org/C146477669",
"wikidata": "https://www.wikidata.org/wiki/Q334631",
"display_name": "Gibbs free energy",
"level": 2,
"score": 0.7873461
},
{
"id": "https://openalex.org/C10710636",
"wikidata": "https://www.wikidata.org/wiki/Q857809",
"display_name": "Equilibrium constant",
"level": 2,
"score": 0.7750225
},
{
"id": "https://openalex.org/C185592680",
"wikidata": "https://www.wikidata.org/wiki/Q2329",
"display_name": "Chemistry",
"level": 0,
"score": 0.7555387
},
{
"id": "https://openalex.org/C56566620",
"wikidata": "https://www.wikidata.org/wiki/Q863829",
"display_name": "Solubility equilibrium",
"level": 3,
"score": 0.56321114
},
{
"id": "https://openalex.org/C97355855",
"wikidata": "https://www.wikidata.org/wiki/Q11473",
"display_name": "Thermodynamics",
"level": 1,
"score": 0.54699266
},
{
"id": "https://openalex.org/C155574463",
"wikidata": "https://www.wikidata.org/wiki/Q170731",
"display_name": "Solubility",
"level": 2,
"score": 0.54194343
},
{
"id": "https://openalex.org/C184651966",
"wikidata": "https://www.wikidata.org/wiki/Q906356",
"display_name": "Aqueous solution",
"level": 2,
"score": 0.50620073
},
{
"id": "https://openalex.org/C93391505",
"wikidata": "https://www.wikidata.org/wiki/Q658700",
"display_name": "Reaction rate constant",
"level": 3,
"score": 0.493041
},
{
"id": "https://openalex.org/C147789679",
"wikidata": "https://www.wikidata.org/wiki/Q11372",
"display_name": "Physical chemistry",
"level": 1,
"score": 0.4262535
},
{
"id": "https://openalex.org/C113196181",
"wikidata": "https://www.wikidata.org/wiki/Q485223",
"display_name": "Analytical Chemistry (journal)",
"level": 2,
"score": 0.35218418
},
{
"id": "https://openalex.org/C148898269",
"wikidata": "https://www.wikidata.org/wiki/Q1108792",
"display_name": "Kinetics",
"level": 2,
"score": 0.12117997
},
{
"id": "https://openalex.org/C178790620",
"wikidata": "https://www.wikidata.org/wiki/Q11351",
"display_name": "Organic chemistry",
"level": 1,
"score": 0.08230525
},
{
"id": "https://openalex.org/C121332964",
"wikidata": "https://www.wikidata.org/wiki/Q413",
"display_name": "Physics",
"level": 0,
"score": 0.07314116
},
{
"id": "https://openalex.org/C62520636",
"wikidata": "https://www.wikidata.org/wiki/Q944",
"display_name": "Quantum mechanics",
"level": 1,
"score": 0.0
}
],
"corresponding_author_ids": [],
"corresponding_institution_ids": [],
"countries_distinct_count": 1,
"counts_by_year": [
{
"year": 2024,
"cited_by_count": 2
},
{
"year": 2023,
"cited_by_count": 3
},
{
"year": 2022,
"cited_by_count": 2
},
{
"year": 2021,
"cited_by_count": 2
},
{
"year": 2020,
"cited_by_count": 3
},
{
"year": 2019,
"cited_by_count": 1
},
{
"year": 2018,
"cited_by_count": 6
},
{
"year": 2017,
"cited_by_count": 2
},
{
"year": 2016,
"cited_by_count": 1
},
{
"year": 2015,
"cited_by_count": 2
},
{
"year": 2014,
"cited_by_count": 2
},
{
"year": 2013,
"cited_by_count": 3
},
{
"year": 2012,
"cited_by_count": 4
}
],
"created_date": "2016-06-24",
"datasets": [],
"display_name": "The solubility of BaCO3(cr) (witherite) in CO2-H2O solutions between 0 and 90\u00b0C, evaluation of the association constants of BaHCO3+(aq) and BaCO30(aq) between 5 and 80\u00b0C, and a preliminary evaluation of the thermodynamic properties of Ba2+(aq)",
"doi": "https://doi.org/10.1016/0016-7037(86)90077-3",
"fulltext_origin": "ngrams",
"fwci": 0.455,
"grants": [],
"has_fulltext": true,
"id": "https://openalex.org/W2047953929",
"ids": {
"openalex": "https://openalex.org/W2047953929",
"doi": "https://doi.org/10.1016/0016-7037(86)90077-3",
"mag": "2047953929"
},
"indexed_in": [
"crossref"
],
"institutions_distinct_count": 1,
"is_paratext": false,
"is_retracted": false,
"keywords": [
{
"id": "https://openalex.org/keywords/solubility-equilibrium",
"display_name": "Solubility equilibrium",
"score": 0.56321114
},
{
"id": "https://openalex.org/keywords/solubility",
"display_name": "Solubility",
"score": 0.509101
}
],
"language": "en",
"locations": [
{
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/0016-7037(86)90077-3",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
}
],
"locations_count": 1,
"mesh": [],
"ngrams_url": "https://api.openalex.org/works/W2047953929/ngrams",
"open_access": {
"is_oa": false,
"oa_status": "closed",
"oa_url": null,
"any_repository_has_fulltext": false
},
"primary_location": {
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/0016-7037(86)90077-3",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
},
"primary_topic": {
"id": "https://openalex.org/T11936",
"display_name": "Aqueous Two-Phase Systems in Separation Science",
"score": 0.9989,
"subfield": {
"id": "https://openalex.org/subfields/1506",
"display_name": "Filtration and Separation"
},
"field": {
"id": "https://openalex.org/fields/15",
"display_name": "Chemical Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
"publication_date": "1986-10-01",
"publication_year": 1986,
"referenced_works": [
"https://openalex.org/W1511357296",
"https://openalex.org/W1544274225",
"https://openalex.org/W1545336444",
"https://openalex.org/W1571370716",
"https://openalex.org/W1626708004",
"https://openalex.org/W1676011433",
"https://openalex.org/W1856219842",
"https://openalex.org/W1980340963",
"https://openalex.org/W1982061723",
"https://openalex.org/W1989678446",
"https://openalex.org/W2003685350",
"https://openalex.org/W2014901561",
"https://openalex.org/W2026815685",
"https://openalex.org/W2034272914",
"https://openalex.org/W2049140635",
"https://openalex.org/W2066539744",
"https://openalex.org/W2067774119",
"https://openalex.org/W2087994142",
"https://openalex.org/W2168649638",
"https://openalex.org/W2316125440",
"https://openalex.org/W2320661767",
"https://openalex.org/W2323731626",
"https://openalex.org/W2323992941",
"https://openalex.org/W2346335390",
"https://openalex.org/W2582618049",
"https://openalex.org/W2610561363",
"https://openalex.org/W2610871296",
"https://openalex.org/W4230569323",
"https://openalex.org/W4233109596",
"https://openalex.org/W4249097198"
],
"referenced_works_count": 30,
"related_works": [
"https://openalex.org/W4361028552",
"https://openalex.org/W4200319877",
"https://openalex.org/W2961753284",
"https://openalex.org/W2383548838",
"https://openalex.org/W2373625723",
"https://openalex.org/W2369175295",
"https://openalex.org/W2363151802",
"https://openalex.org/W2348400056",
"https://openalex.org/W2011354860",
"https://openalex.org/W1988863621"
],
"sustainable_development_goals": [],
"title": "The solubility of BaCO3(cr) (witherite) in CO2-H2O solutions between 0 and 90\u00b0C, evaluation of the association constants of BaHCO3+(aq) and BaCO30(aq) between 5 and 80\u00b0C, and a preliminary evaluation of the thermodynamic properties of Ba2+(aq)",
"topics": [
{
"id": "https://openalex.org/T11936",
"display_name": "Aqueous Two-Phase Systems in Separation Science",
"score": 0.9989,
"subfield": {
"id": "https://openalex.org/subfields/1506",
"display_name": "Filtration and Separation"
},
"field": {
"id": "https://openalex.org/fields/15",
"display_name": "Chemical Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T11278",
"display_name": "Bioinspired Structural Materials and Biomineralization",
"score": 0.9987,
"subfield": {
"id": "https://openalex.org/subfields/2502",
"display_name": "Biomaterials"
},
"field": {
"id": "https://openalex.org/fields/25",
"display_name": "Materials Science"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T11881",
"display_name": "Crystallization Processes and Control",
"score": 0.9884,
"subfield": {
"id": "https://openalex.org/subfields/2505",
"display_name": "Materials Chemistry"
},
"field": {
"id": "https://openalex.org/fields/25",
"display_name": "Materials Science"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
}
],
"type": "article",
"type_crossref": "journal-article",
"updated_date": "2024-08-15T02:15:12.961264",
"versions": []
}
}
