Item talk:Q265824
From geokb
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"name": "Aluminum mobility in mildly acidic mine drainage: Interactions between hydrobasaluminite, silica and trace metals from the nano to the meso-scale",
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"abstract": "Aluminum precipitates control the\u00a0hydrochemistry\u00a0and\u00a0mineralogy\u00a0of a broad variety of environments on Earth (e.g.,\u00a0acid mine drainage, AMD,\u00a0coastal wetlands, boreal and alpine streams, tropical\u00a0acid sulfate soils,\u00a0laterites\u00a0and\u00a0bauxites, \u2026). However, the geochemical and mineralogical processes controlling Al (and other associated metals and metalloids) transport and removal in those environments are not fully understood. The geochemical system of Paradise Portal (Colorado, USA) comprises sulfate-rich mildly acidic waters, the hydrochemistry of which is directly controlled by the massive precipitation of hydrobasaluminite Al4(SO4)(OH)10\u00b712-36H2O. Three connected but discernible aluminum precipitation stages were identified and described: 1)\u00a0nanoparticle\u00a0formation and size decrease along the creek, 2) hydrobasaluminite neoformation on the riverbed, and 3) precipitate accretion and accumulation on the riverbed leading to Al and Fe banded formations. The co-occurrence of Al and Si in the system was observed, recording significant amounts of Si accompanying the three different components of the system (i.e., nanoparticles and fresh and aged Al-precipitates). Also, abrupt and minor changes in the sedimentary record were described and proposed to be the response of the system to seasonal and interannual changes in AMD chemistry. Concerning the mobility of other metals and\u00a0metalloids, P, Th, V, W, Ti and B showed a tendency to be preferentially incorporated into hydrobasaluminite, while others like Be, As, Se or Ba tend to remain dissolved in the water.",
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