Item talk:Q265742
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Arsenic in petroleum-contaminated groundwater near Bemidji, Minnesota is predicted to persist for centuries", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70220873", "url": "https://pubs.usgs.gov/publication/70220873" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70220873 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.3390/w13111485", "url": "https://doi.org/10.3390/w13111485" } ], "journal": { "@type": "Periodical", "name": "Water", "volumeNumber": "13", "issueNumber": "11" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Water" } ], "datePublished": "2021", "dateModified": "2021-05-27", "abstract": "We used a reactive transport model to investigate the cycling of geogenic arsenic (As) in a petroleum-contaminated aquifer. We simulated As mobilization and sequestration using surface complexation reactions with Fe(OH)3\u00a0during petroleum biodegradation coupled with Fe-reduction. Model results predict that dissolved As in the plume will exceed the U.S. and EU 10 \u00b5g/L drinking water standard for ~400 years. Non-volatile dissolved organic carbon (NVDOC) in the model promotes As mobilization by exerting oxygen demand, which maintains anoxic conditions in the aquifer. After NVDOC degrades, As re-associates with Fe(OH)3\u00a0as oxygenated conditions are re-established. Over the 400-year simulation, As transport resembles a \u201croll front\u201d in which: (1) arsenic sorbed to Fe(OH)3\u00a0is released during Fe-reduction coupled to petroleum biodegradation; (2) dissolved As resorbs to Fe(OH)3\u00a0at the plume\u2019s leading edge; and (3) over time, the plume expands, and resorbed As is re-released into groundwater. This \u201croll front\u201d behavior underscores the transience of sorption as an As attenuation mechanism. Over the plume\u2019s lifespan, simulations suggest that As will contaminate more groundwater than benzene from the oil spill. At its maximum, the model simulates that ~5.7\u00d7 more groundwater will be contaminated by As than benzene, suggesting that As could pose a greater long-term water quality threat than benzene in this petroleum-contaminated aquifer.", "description": "1485, 24 p.", "publisher": { "@type": "Organization", "name": "MDPI" }, "author": [ { "@type": "Person", "name": "Ziegler, Brady A.", "givenName": "Brady A.", "familyName": "Ziegler", "affiliation": [ { "@type": "Organization", "name": "Department of Geosciences, Trinity University" } ] }, { "@type": "Person", "name": "Ng, G.-H. Crystal", "givenName": "G.-H. 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