Item talk:Q259975

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   "name": "The inverse problem of argon diffusion from minerals: Determination of kinetic parameters from stepwise-heating experiments",
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   "abstract": "Results of two routine\u00a040Ar/39Ar stepwise heating experiments on a biotite and a basanite are interpreted in terms of Fick's and Arrhenius' laws. Both patterns represent a saddle-shaped\u00a039Ar release. Argon isotope spectra are suggested to be controlled by the activation energy of diffusion\u00a0E\u00a0and the frequency factor\u00a0Do\u00a0. The activation energy of\u00a039Ar is lower than the one of\u00a040Ar. This results in a preferable release of\u00a040Ar relatively to\u00a039Ar at high-temperature steps and an increasing high-temperature wing in the saddle-shaped age spectrum. At low temperatures, considerable losses and irregularities in release of mainly\u00a039Ar are observed, which cause the decreasing low-temperature wing in the \u201csaddle\u201d. The suggestion of argon losses (mainly of\u00a039Ar) from a loose, \u201cunstable\u201d zone of the mineral structures becomes justified. The\u00a0n-irradiation of the samples and the shift of\u00a0E\u00a0of\u00a039Ar towards lower values seems to explain the saddle-shaped age-spectra often encountered in\u00a040Ar/39Ar-geochronometry.",
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