Item talk:Q249882
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Development of a solenoid pumped in situ zinc analyzer for environmental monitoring", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70029638", "url": "https://pubs.usgs.gov/publication/70029638" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70029638 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1016/j.aca.2005.04.046", "url": "https://doi.org/10.1016/j.aca.2005.04.046" }, { "@type": "PropertyValue", "propertyID": "ISSN", "value": "00032670" } ], "journal": { "@type": "Periodical", "name": "Analytica Chimica Acta", "volumeNumber": "543", "issueNumber": "1-2" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Analytica Chimica Acta" } ], "datePublished": "2005", "dateModified": "2018-11-05", "abstract": "A battery powered submersible chemical analyzer, the Zn-DigiScan (Zn Digital Submersible Chemical Analyzer), has been developed for near real-time, in situ monitoring of\u00a0zinc\u00a0in aquatic systems.\u00a0Microprocessor\u00a0controlled solenoid pumps propel sample and carrier through an\u00a0anion exchange\u00a0column to separate zinc from interferences, add\u00a0colorimetric reagents, and propel the reaction complex through a simple photometric detector. The Zn-DigiScan is capable of self-calibration with periodic injections of standards and blanks. The detection limit with this approach was 30\u00a0\u03bcg\u00a0L\u22121. Precision was 5\u201310% relative standard deviation (R.S.D.) below 100\u00a0\u03bcg\u00a0L\u22121, improving to 1% R.S.D. at 1000\u00a0\u03bcg\u00a0L\u22121. The linear range extended from 30 to 3000\u00a0\u03bcg\u00a0L\u22121. In situ field results were in agreement with samples analyzed by\u00a0inductively coupled plasma mass spectrometry\u00a0(ICPMS). This pump technology is quite versatile and colorimetric methods with complex online manipulations such as column reduction,\u00a0preconcentration, and dilution can be performed with the DigiScan. However, long-term field deployments in shallow\u00a0high altitude\u00a0streams were hampered by air\u00a0bubble formation\u00a0in the photometric detector.", "description": "10 p.", "publisher": { "@type": "Organization", "name": "Elsevier" }, "author": [ { "@type": "Person", "name": "Chapin, T.P.", "givenName": "T.P.", "familyName": "Chapin", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0001-6587-0734", "url": "https://orcid.org/0000-0001-6587-0734" } }, { "@type": "Person", "name": "Wanty, R. B.", "givenName": "R. B.", "familyName": "Wanty", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-2063-6423", "url": "https://orcid.org/0000-0002-2063-6423" } } ], "funder": [ { "@type": "Organization", "name": "Toxic Substances Hydrology Program", "url": null } ] }, "OpenAlex": { "abstract_inverted_index": { "Abstract": [ 0 ], "A": [ 3 ], "battery": [ 4 ], "powered": [ 5 ], "submersible": [ 6 ], "chemical": [ 7 ], "analyzer,": [ 8 ], "the": [ 9, 53, 154, 172 ], "Zn-DigiScan": [ 10, 62 ], "(Zn": [ 11 ], "Digital": [ 12 ], "Submersible": [ 13 ], "Chemical": [ 14 ], "Analyzer),": [ 15 ], "has": [ 16 ], "been": [ 17 ], "developed": [ 18 ], "for": [ 19 ], "near": [ 20 ], "real-time,": [ 21 ], "in": [ 22, 27, 118, 160, 171 ], "situ": [ 23, 114 ], "monitoring": [ 24 ], "of": [ 25, 65, 70 ], "zinc": [ 26, 45 ], "aquatic": [ 28 ], "systems.": [ 29 ], "Microprocessor": [ 30 ], "controlled": [ 31 ], "solenoid": [ 32 ], "pumps": [ 33 ], "propel": [ 34, 52 ], "sample": [ 35 ], "and": [ 36, 51, 72, 136, 148 ], "carrier": [ 37 ], "through": [ 38, 56 ], "an": [ 39 ], "anion": [ 40 ], "exchange": [ 41 ], "column": [ 42, 145 ], "to": [ 43, 96, 109 ], "separate": [ 44 ], "from": [ 46, 107 ], "interferences,": [ 47 ], "add": [ 48 ], "colorimetric": [ 49, 137 ], "reagents,": [ 50 ], "reaction": [ 54 ], "complex": [ 55, 140 ], "a": [ 57 ], "simple": [ 58 ], "photometric": [ 59, 173 ], "detector.": [ 60, 174 ], "The": [ 61, 74, 103 ], "is": [ 63, 133 ], "capable": [ 64 ], "self-calibration": [ 66 ], "with": [ 67, 77, 120, 139, 153 ], "periodic": [ 68 ], "injections": [ 69 ], "standards": [ 71 ], "blanks.": [ 73 ], "detection": [ 75 ], "limit": [ 76 ], "this": [ 78 ], "approach": [ 79 ], "was": [ 80, 85 ], "30\u00a0\u03bcg\u00a0L": [ 81 ], "\u22121": [ 82, 93, 101, 111 ], ".": [ 83, 102, 112 ], "Precision": [ 84 ], "5\u201310%": [ 86 ], "relative": [ 87 ], "standard": [ 88 ], "deviation": [ 89 ], "(R.S.D.)": [ 90 ], "below": [ 91 ], "100\u00a0\u03bcg\u00a0L": [ 92 ], ",": [ 94 ], "improving": [ 95 ], "1%": [ 97 ], "R.S.D.": [ 98 ], "at": [ 99 ], "1000\u00a0\u03bcg\u00a0L": [ 100 ], "linear": [ 104 ], "range": [ 105 ], "extended": [ 106 ], "30": [ 108 ], "3000\u00a0\u03bcg\u00a0L": [ 110 ], "In": [ 113 ], "field": [ 115, 158 ], "results": [ 116 ], "were": [ 117, 165 ], "agreement": [ 119 ], "samples": [ 121 ], "analyzed": [ 122 ], "by": [ 123, 167 ], "inductively": [ 124 ], "coupled": [ 125 ], "plasma": [ 126 ], "mass": [ 127 ], "spectrometry": [ 128 ], "(ICPMS).": [ 129 ], "This": [ 130 ], "pump": [ 131 ], "technology": [ 132 ], "quite": [ 134 ], "versatile": [ 135 ], "methods": [ 138 ], "online": [ 141 ], "manipulations": [ 142 ], "such": [ 143 ], "as": [ 144 ], "reduction,": [ 146 ], "preconcentration,": [ 147 ], "dilution": [ 149 ], "can": [ 150 ], "be": [ 151 ], "performed": [ 152 ], "DigiScan.": [ 155 ], "However,": [ 156 ], "long-term": [ 157 ], "deployments": [ 159 ], "shallow": [ 161 ], "high": [ 162 ], "altitude": [ 163 ], "streams": [ 164 ], "hampered": [ 166 ], "air": [ 168 ], "bubble": [ 169 ], "formation": [ 170 ] }, "apc_list": { "value": 3910, "currency": "USD", "value_usd": 3910, "provenance": "doaj" }, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5015888052", "display_name": "Thomas P. 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