Item talk:Q249374

From geokb

{

 "USGS Publications Warehouse": {
   "@context": "https://schema.org",
   "@type": "Article",
   "additionalType": "Journal Article",
   "name": "Acquisition and evaluation of thermodynamic data for bieberite-moorhouseite equilibria at 0.1 MPa",
   "identifier": [
     {
       "@type": "PropertyValue",
       "propertyID": "USGS Publications Warehouse IndexID",
       "value": "70029270",
       "url": "https://pubs.usgs.gov/publication/70029270"
     },
     {
       "@type": "PropertyValue",
       "propertyID": "USGS Publications Warehouse Internal ID",
       "value": 70029270
     },
     {
       "@type": "PropertyValue",
       "propertyID": "DOI",
       "value": "10.2138/am.2005.1695",
       "url": "https://doi.org/10.2138/am.2005.1695"
     },
     {
       "@type": "PropertyValue",
       "propertyID": "ISSN",
       "value": "0003004X"
     }
   ],
   "journal": {
     "@type": "Periodical",
     "name": "American Mineralogist",
     "volumeNumber": "90",
     "issueNumber": "5-6"
   },
   "inLanguage": "en",
   "isPartOf": [
     {
       "@type": "CreativeWorkSeries",
       "name": "American Mineralogist"
     }
   ],
   "datePublished": "2005",
   "dateModified": "2012-03-12",
   "abstract": "Published estimates for the equilibrium relative humidity (RH) at 25 deg;C for the reaction: bieberite (CoSO4??7H2O) = moorhouseite (CoSO4??6H2O) + H2O, range from 69.8 to 74.5%. To evaluate these data, the humidity-buffer technique was used to determine equilibrium constants for this reaction between 14 and 43 ??C at 0.1 MPa. Reversals along five humidity-buffer curves yield In K = 18.03-6509.43/T, where K is the equilibrium constant, and T is temperature in K. The derived standard Gibbs free energy of reaction is 9.43 kJ/mol, which agrees well with several previously reported values based on vapor-pressure measurements. It also agrees well with values calculated from the data derived mostly from calorimetric measurements. Previous studies indicated that the temperature of the invariant point for the assemblage bieberite-moorhouseite-aqueous solution-vapor is near 44.7 ??C, and our extrapolated data predict 91.1% RH at this temperature; the predicted position for the invariant point is in excellent agreement with those reported previously.",
   "publisher": {
     "@type": "Organization",
     "name": "U.S. Geological Survey"
   },
   "author": [
     {
       "@type": "Person",
       "name": "Chou, I.-Ming",
       "givenName": "I.-Ming",
       "familyName": "Chou",
       "identifier": {
         "@type": "PropertyValue",
         "propertyID": "ORCID",
         "value": "0000-0001-5233-6479",
         "url": "https://orcid.org/0000-0001-5233-6479"
       },
       "affiliation": [
         {
           "@type": "Organization",
           "name": "Eastern Mineral and Environmental Resources Science Center",
           "url": "https://www.usgs.gov/centers/geology-energy-and-minerals-science-center"
         }
       ]
     },
     {
       "@type": "Person",
       "name": "Seal, R.R. II",
       "givenName": "R.R.",
       "familyName": "Seal"
     }
   ]
 },
 "OpenAlex": {
   "abstract_inverted_index": {
     "Published": [
       0
     ],
     "estimates": [
       1
     ],
     "for": [
       2,
       11,
       39,
       120,
       142
     ],
     "the": [
       3,
       12,
       30,
       63,
       103,
       114,
       117,
       121,
       139,
       143
     ],
     "equilibrium": [
       4,
       37,
       64
     ],
     "relative": [
       5
     ],
     "humidity": [
       6
     ],
     "(RH)": [
       7
     ],
     "at": [
       8,
       47,
       136
     ],
     "25": [
       9
     ],
     "\u00b0C": [
       10,
       46
     ],
     "reaction:": [
       13
     ],
     "bieberite": [
       14
     ],
     "(CoSO4\u00b77H2O)": [
       15
     ],
     "=": [
       16,
       58
     ],
     "moorhouseite": [
       17
     ],
     "(CoSO4\u00b76H2O)": [
       18
     ],
     "+": [
       19
     ],
     "H2O,": [
       20
     ],
     "range": [
       21
     ],
     "from": [
       22,
       102,
       107
     ],
     "69.8": [
       23
     ],
     "to": [
       24,
       35
     ],
     "74.5%.": [
       25
     ],
     "To": [
       26
     ],
     "evaluate": [
       27
     ],
     "these": [
       28
     ],
     "data,": [
       29
     ],
     "humidity-buffer": [
       31,
       53
     ],
     "technique": [
       32
     ],
     "was": [
       33
     ],
     "used": [
       34
     ],
     "determine": [
       36
     ],
     "constants": [
       38
     ],
     "this": [
       40,
       137
     ],
     "reaction": [
       41,
       79
     ],
     "between": [
       42
     ],
     "14": [
       43
     ],
     "and": [
       44,
       66,
       129
     ],
     "43": [
       45
     ],
     "0.1": [
       48
     ],
     "MPa.": [
       49
     ],
     "Reversals": [
       50
     ],
     "along": [
       51
     ],
     "five": [
       52
     ],
     "curves": [
       54
     ],
     "yield": [
       55
     ],
     "ln": [
       56
     ],
     "K": [
       57,
       61
     ],
     "18.03\u20136509.43/T,": [
       59
     ],
     "where": [
       60
     ],
     "is": [
       62,
       68,
       80,
       125,
       146
     ],
     "constant,": [
       65
     ],
     "T": [
       67
     ],
     "temperature": [
       69,
       115
     ],
     "in": [
       70,
       147
     ],
     "K.": [
       71
     ],
     "The": [
       72
     ],
     "derived": [
       73,
       105
     ],
     "standard": [
       74
     ],
     "Gibbs": [
       75
     ],
     "free": [
       76
     ],
     "energy": [
       77
     ],
     "of": [
       78,
       116
     ],
     "9.43": [
       81
     ],
     "kJ/mol,": [
       82
     ],
     "which": [
       83
     ],
     "agrees": [
       84,
       97
     ],
     "well": [
       85,
       98
     ],
     "with": [
       86,
       99,
       150
     ],
     "several": [
       87
     ],
     "previously": [
       88
     ],
     "reported": [
       89,
       152
     ],
     "values": [
       90,
       100
     ],
     "based": [
       91
     ],
     "on": [
       92
     ],
     "vaporpressure": [
       93
     ],
     "measurements.": [
       94,
       109
     ],
     "It": [
       95
     ],
     "also": [
       96
     ],
     "calculated": [
       101
     ],
     "data": [
       104,
       132
     ],
     "mostly": [
       106
     ],
     "calorimetric": [
       108
     ],
     "Previous": [
       110
     ],
     "studies": [
       111
     ],
     "indicated": [
       112
     ],
     "that": [
       113
     ],
     "invariant": [
       118,
       144
     ],
     "point": [
       119,
       145
     ],
     "assemblage": [
       122
     ],
     "bieberite-moorhouseite-aqueous": [
       123
     ],
     "solution-vapor": [
       124
     ],
     "near": [
       126
     ],
     "44.7": [
       127
     ],
     "\u00b0C,": [
       128
     ],
     "our": [
       130
     ],
     "extrapolated": [
       131
     ],
     "predict": [
       133
     ],
     "91.1%": [
       134
     ],
     "RH": [
       135
     ],
     "temperature;": [
       138
     ],
     "predicted": [
       140
     ],
     "position": [
       141
     ],
     "excellent": [
       148
     ],
     "agreement": [
       149
     ],
     "those": [
       151
     ],
     "previously.": [
       153
     ]
   },
   "apc_list": null,
   "apc_paid": null,
   "authorships": [
     {
       "author_position": "first",
       "author": {
         "id": "https://openalex.org/A5074729117",
         "display_name": "I\u2010Ming Chou",
         "orcid": "https://orcid.org/0000-0001-5233-6479"
       },
       "institutions": [
         {
           "id": "https://openalex.org/I1286329397",
           "display_name": "United States Geological Survey",
           "ror": "https://ror.org/035a68863",
           "country_code": "US",
           "type": "government",
           "lineage": [
             "https://openalex.org/I1286329397",
             "https://openalex.org/I1335927249"
           ]
         }
       ],
       "countries": [
         "US"
       ],
       "is_corresponding": false,
       "raw_author_name": "I-Ming Chou",
       "raw_affiliation_strings": [
         "954 National Center, U.S. Geological Survey, Reston, Virginia 20192, U.S.A."
       ],
       "affiliations": [
         {
           "raw_affiliation_string": "954 National Center, U.S. Geological Survey, Reston, Virginia 20192, U.S.A.",
           "institution_ids": [
             "https://openalex.org/I1286329397"
           ]
         }
       ]
     },
     {
       "author_position": "last",
       "author": {
         "id": "https://openalex.org/A5086220081",
         "display_name": "Robert R. Seal",
         "orcid": "https://orcid.org/0000-0003-0901-2529"
       },
       "institutions": [
         {
           "id": "https://openalex.org/I1286329397",
           "display_name": "United States Geological Survey",
           "ror": "https://ror.org/035a68863",
           "country_code": "US",
           "type": "government",
           "lineage": [
             "https://openalex.org/I1286329397",
             "https://openalex.org/I1335927249"
           ]
         }
       ],
       "countries": [
         "US"
       ],
       "is_corresponding": false,
       "raw_author_name": "Robert R. Seal",
       "raw_affiliation_strings": [
         "954 National Center, U.S. Geological Survey, Reston, Virginia 20192, U.S.A."
       ],
       "affiliations": [
         {
           "raw_affiliation_string": "954 National Center, U.S. Geological Survey, Reston, Virginia 20192, U.S.A.",
           "institution_ids": [
             "https://openalex.org/I1286329397"
           ]
         }
       ]
     }
   ],
   "best_oa_location": {
     "is_oa": true,
     "landing_page_url": "http://digitalcommons.unl.edu/cgi/viewcontent.cgi?article=1342&context=usgsstaffpub",
     "pdf_url": "http://digitalcommons.unl.edu/cgi/viewcontent.cgi?article=1342&context=usgsstaffpub",
     "source": {
       "id": "https://openalex.org/S4377196105",
       "display_name": "Digital Commons - University of Nebraska Lincoln (University of Nebraska\u2013Lincoln)",
       "issn_l": null,
       "issn": null,
       "is_oa": false,
       "is_in_doaj": false,
       "is_core": false,
       "host_organization": "https://openalex.org/I114395901",
       "host_organization_name": "University of Nebraska\u2013Lincoln",
       "host_organization_lineage": [
         "https://openalex.org/I114395901"
       ],
       "host_organization_lineage_names": [
         "University of Nebraska\u2013Lincoln"
       ],
       "type": "repository"
     },
     "license": null,
     "license_id": null,
     "version": "submittedVersion",
     "is_accepted": false,
     "is_published": false
   },
   "biblio": {
     "volume": "90",
     "issue": "5-6",
     "first_page": "912",
     "last_page": "917"
   },
   "citation_normalized_percentile": {
     "value": 0.647059,
     "is_in_top_1_percent": false,
     "is_in_top_10_percent": false
   },
   "cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2145282721",
   "cited_by_count": 11,
   "cited_by_percentile_year": {
     "min": 83,
     "max": 84
   },
   "concepts": [
     {
       "id": "https://openalex.org/C146477669",
       "wikidata": "https://www.wikidata.org/wiki/Q334631",
       "display_name": "Gibbs free energy",
       "level": 2,
       "score": 0.71386635
     },
     {
       "id": "https://openalex.org/C97355855",
       "wikidata": "https://www.wikidata.org/wiki/Q11473",
       "display_name": "Thermodynamics",
       "level": 1,
       "score": 0.69896454
     },
     {
       "id": "https://openalex.org/C185592680",
       "wikidata": "https://www.wikidata.org/wiki/Q2329",
       "display_name": "Chemistry",
       "level": 0,
       "score": 0.69294906
     },
     {
       "id": "https://openalex.org/C10710636",
       "wikidata": "https://www.wikidata.org/wiki/Q857809",
       "display_name": "Equilibrium constant",
       "level": 2,
       "score": 0.64524454
     },
     {
       "id": "https://openalex.org/C39353612",
       "wikidata": "https://www.wikidata.org/wiki/Q5283759",
       "display_name": "Atmospheric temperature range",
       "level": 2,
       "score": 0.5620042
     },
     {
       "id": "https://openalex.org/C151420433",
       "wikidata": "https://www.wikidata.org/wiki/Q180600",
       "display_name": "Humidity",
       "level": 2,
       "score": 0.54082704
     },
     {
       "id": "https://openalex.org/C134121241",
       "wikidata": "https://www.wikidata.org/wiki/Q899301",
       "display_name": "Yield (engineering)",
       "level": 2,
       "score": 0.5253498
     },
     {
       "id": "https://openalex.org/C158960510",
       "wikidata": "https://www.wikidata.org/wiki/Q180600",
       "display_name": "Relative humidity",
       "level": 2,
       "score": 0.48837632
     },
     {
       "id": "https://openalex.org/C131157278",
       "wikidata": "https://www.wikidata.org/wiki/Q51363",
       "display_name": "Thermodynamic equilibrium",
       "level": 2,
       "score": 0.45023048
     },
     {
       "id": "https://openalex.org/C184651966",
       "wikidata": "https://www.wikidata.org/wiki/Q906356",
       "display_name": "Aqueous solution",
       "level": 2,
       "score": 0.44921425
     },
     {
       "id": "https://openalex.org/C113196181",
       "wikidata": "https://www.wikidata.org/wiki/Q485223",
       "display_name": "Analytical Chemistry (journal)",
       "level": 2,
       "score": 0.371274
     },
     {
       "id": "https://openalex.org/C147789679",
       "wikidata": "https://www.wikidata.org/wiki/Q11372",
       "display_name": "Physical chemistry",
       "level": 1,
       "score": 0.23580489
     },
     {
       "id": "https://openalex.org/C121332964",
       "wikidata": "https://www.wikidata.org/wiki/Q413",
       "display_name": "Physics",
       "level": 0,
       "score": 0.089954704
     },
     {
       "id": "https://openalex.org/C43617362",
       "wikidata": "https://www.wikidata.org/wiki/Q170050",
       "display_name": "Chromatography",
       "level": 1,
       "score": 0.08107123
     }
   ],
   "corresponding_author_ids": [],
   "corresponding_institution_ids": [],
   "countries_distinct_count": 1,
   "counts_by_year": [
     {
       "year": 2022,
       "cited_by_count": 1
     },
     {
       "year": 2019,
       "cited_by_count": 1
     },
     {
       "year": 2017,
       "cited_by_count": 1
     },
     {
       "year": 2013,
       "cited_by_count": 1
     }
   ],
   "created_date": "2016-06-24",
   "datasets": [],
   "display_name": "Acquisition and evaluation of thermodynamic data for bieberite-moorhouseite equilibria at 0.1 MPa",
   "doi": "https://doi.org/10.2138/am.2005.1695",
   "fulltext_origin": "ngrams",
   "fwci": 1.052,
   "grants": [],
   "has_fulltext": true,
   "id": "https://openalex.org/W2145282721",
   "ids": {
     "openalex": "https://openalex.org/W2145282721",
     "doi": "https://doi.org/10.2138/am.2005.1695",
     "mag": "2145282721"
   },
   "indexed_in": [
     "crossref"
   ],
   "institutions_distinct_count": 1,
   "is_paratext": false,
   "is_retracted": false,
   "keywords": [
     {
       "id": "https://openalex.org/keywords/atmospheric-temperature-range",
       "display_name": "Atmospheric temperature range",
       "score": 0.5620042
     },
     {
       "id": "https://openalex.org/keywords/thermoanalytical-data",
       "display_name": "Thermoanalytical Data",
       "score": 0.468934
     }
   ],
   "language": "en",
   "locations": [
     {
       "is_oa": false,
       "landing_page_url": "https://doi.org/10.2138/am.2005.1695",
       "pdf_url": null,
       "source": {
         "id": "https://openalex.org/S80733542",
         "display_name": "American Mineralogist",
         "issn_l": "0003-004X",
         "issn": [
           "0003-004X",
           "1945-3027"
         ],
         "is_oa": false,
         "is_in_doaj": false,
         "is_core": true,
         "host_organization": "https://openalex.org/P4310319932",
         "host_organization_name": "Mineralogical Society of America",
         "host_organization_lineage": [
           "https://openalex.org/P4310319932"
         ],
         "host_organization_lineage_names": [
           "Mineralogical Society of America"
         ],
         "type": "journal"
       },
       "license": null,
       "license_id": null,
       "version": null,
       "is_accepted": false,
       "is_published": false
     },
     {
       "is_oa": true,
       "landing_page_url": "http://digitalcommons.unl.edu/cgi/viewcontent.cgi?article=1342&context=usgsstaffpub",
       "pdf_url": "http://digitalcommons.unl.edu/cgi/viewcontent.cgi?article=1342&context=usgsstaffpub",
       "source": {
         "id": "https://openalex.org/S4377196105",
         "display_name": "Digital Commons - University of Nebraska Lincoln (University of Nebraska\u2013Lincoln)",
         "issn_l": null,
         "issn": null,
         "is_oa": false,
         "is_in_doaj": false,
         "is_core": false,
         "host_organization": "https://openalex.org/I114395901",
         "host_organization_name": "University of Nebraska\u2013Lincoln",
         "host_organization_lineage": [
           "https://openalex.org/I114395901"
         ],
         "host_organization_lineage_names": [
           "University of Nebraska\u2013Lincoln"
         ],
         "type": "repository"
       },
       "license": null,
       "license_id": null,
       "version": "submittedVersion",
       "is_accepted": false,
       "is_published": false
     },
     {
       "is_oa": true,
       "landing_page_url": "http://digitalcommons.unl.edu/usgsstaffpub/335",
       "pdf_url": "https://digitalcommons.unl.edu/cgi/viewcontent.cgi?article=1342&context=usgsstaffpub",
       "source": {
         "id": "https://openalex.org/S4377196105",
         "display_name": "Digital Commons - University of Nebraska Lincoln (University of Nebraska\u2013Lincoln)",
         "issn_l": null,
         "issn": null,
         "is_oa": false,
         "is_in_doaj": false,
         "is_core": false,
         "host_organization": "https://openalex.org/I114395901",
         "host_organization_name": "University of Nebraska\u2013Lincoln",
         "host_organization_lineage": [
           "https://openalex.org/I114395901"
         ],
         "host_organization_lineage_names": [
           "University of Nebraska\u2013Lincoln"
         ],
         "type": "repository"
       },
       "license": null,
       "license_id": null,
       "version": "submittedVersion",
       "is_accepted": false,
       "is_published": false
     }
   ],
   "locations_count": 3,
   "mesh": [],
   "ngrams_url": "https://api.openalex.org/works/W2145282721/ngrams",
   "open_access": {
     "is_oa": true,
     "oa_status": "green",
     "oa_url": "http://digitalcommons.unl.edu/cgi/viewcontent.cgi?article=1342&context=usgsstaffpub",
     "any_repository_has_fulltext": true
   },
   "primary_location": {
     "is_oa": false,
     "landing_page_url": "https://doi.org/10.2138/am.2005.1695",
     "pdf_url": null,
     "source": {
       "id": "https://openalex.org/S80733542",
       "display_name": "American Mineralogist",
       "issn_l": "0003-004X",
       "issn": [
         "0003-004X",
         "1945-3027"
       ],
       "is_oa": false,
       "is_in_doaj": false,
       "is_core": true,
       "host_organization": "https://openalex.org/P4310319932",
       "host_organization_name": "Mineralogical Society of America",
       "host_organization_lineage": [
         "https://openalex.org/P4310319932"
       ],
       "host_organization_lineage_names": [
         "Mineralogical Society of America"
       ],
       "type": "journal"
     },
     "license": null,
     "license_id": null,
     "version": null,
     "is_accepted": false,
     "is_published": false
   },
   "primary_topic": {
     "id": "https://openalex.org/T11936",
     "display_name": "Aqueous Two-Phase Systems in Separation Science",
     "score": 0.9998,
     "subfield": {
       "id": "https://openalex.org/subfields/1506",
       "display_name": "Filtration and Separation"
     },
     "field": {
       "id": "https://openalex.org/fields/15",
       "display_name": "Chemical Engineering"
     },
     "domain": {
       "id": "https://openalex.org/domains/3",
       "display_name": "Physical Sciences"
     }
   },
   "publication_date": "2005-05-01",
   "publication_year": 2005,
   "referenced_works": [
     "https://openalex.org/W13656261",
     "https://openalex.org/W1535281152",
     "https://openalex.org/W1601630492",
     "https://openalex.org/W1603007854",
     "https://openalex.org/W1626708004",
     "https://openalex.org/W1790743573",
     "https://openalex.org/W1951446495",
     "https://openalex.org/W1968868266",
     "https://openalex.org/W2007003740",
     "https://openalex.org/W2009764300",
     "https://openalex.org/W2010637454",
     "https://openalex.org/W2023188254",
     "https://openalex.org/W2028983793",
     "https://openalex.org/W2055247397",
     "https://openalex.org/W2091875739",
     "https://openalex.org/W2117669255",
     "https://openalex.org/W2121288943",
     "https://openalex.org/W2139412699",
     "https://openalex.org/W2327830762",
     "https://openalex.org/W2334014271",
     "https://openalex.org/W2492120737",
     "https://openalex.org/W2597403016",
     "https://openalex.org/W4861424"
   ],
   "referenced_works_count": 23,
   "related_works": [
     "https://openalex.org/W4390758803",
     "https://openalex.org/W2510617629",
     "https://openalex.org/W2380249611",
     "https://openalex.org/W2366365583",
     "https://openalex.org/W2181379992",
     "https://openalex.org/W2076148711",
     "https://openalex.org/W2013511864",
     "https://openalex.org/W2011354860",
     "https://openalex.org/W1642018725",
     "https://openalex.org/W1586733611"
   ],
   "sustainable_development_goals": [
     {
       "id": "https://metadata.un.org/sdg/7",
       "display_name": "Affordable and clean energy",
       "score": 0.4
     }
   ],
   "title": "Acquisition and evaluation of thermodynamic data for bieberite-moorhouseite equilibria at 0.1 MPa",
   "topics": [
     {
       "id": "https://openalex.org/T11936",
       "display_name": "Aqueous Two-Phase Systems in Separation Science",
       "score": 0.9998,
       "subfield": {
         "id": "https://openalex.org/subfields/1506",
         "display_name": "Filtration and Separation"
       },
       "field": {
         "id": "https://openalex.org/fields/15",
         "display_name": "Chemical Engineering"
       },
       "domain": {
         "id": "https://openalex.org/domains/3",
         "display_name": "Physical Sciences"
       }
     },
     {
       "id": "https://openalex.org/T11881",
       "display_name": "Crystallization Processes and Control",
       "score": 0.999,
       "subfield": {
         "id": "https://openalex.org/subfields/2505",
         "display_name": "Materials Chemistry"
       },
       "field": {
         "id": "https://openalex.org/fields/25",
         "display_name": "Materials Science"
       },
       "domain": {
         "id": "https://openalex.org/domains/3",
         "display_name": "Physical Sciences"
       }
     },
     {
       "id": "https://openalex.org/T12358",
       "display_name": "Kinetic Analysis of Thermal Processes in Materials",
       "score": 0.9971,
       "subfield": {
         "id": "https://openalex.org/subfields/2505",
         "display_name": "Materials Chemistry"
       },
       "field": {
         "id": "https://openalex.org/fields/25",
         "display_name": "Materials Science"
       },
       "domain": {
         "id": "https://openalex.org/domains/3",
         "display_name": "Physical Sciences"
       }
     }
   ],
   "type": "article",
   "type_crossref": "journal-article",
   "updated_date": "2024-08-12T08:29:01.559832",
   "versions": []
 }

}