Item talk:Q242508
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{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Methodological considerations regarding the use of inorganic 197Hg(II) radiotracer to assess mercury methylation potential rates in lake sediment", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70031156", "url": "https://pubs.usgs.gov/publication/70031156" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70031156 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1016/j.apradiso.2007.04.010", "url": "https://doi.org/10.1016/j.apradiso.2007.04.010" }, { "@type": "PropertyValue", "propertyID": "ISSN", "value": "09698043" } ], "journal": { "@type": "Periodical", "name": "Applied Radiation and Isotopes", "volumeNumber": "65", "issueNumber": "9" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Applied Radiation and Isotopes" } ], "datePublished": "2007", "dateModified": "2023-07-27", "abstract": "Methodological considerations on the determination of benthic methyl-mercury (CH3Hg) production potentials were investigated on lake sediment, using\u00a0197Hg radiotracer. Three methods to arrest bacterial activity were compared: flash freezing, thermal sterilization, and\u00a0\u03b3-irradiation. Flash freezing showed similar CH3Hg recoveries as thermal sterilization, which was both 50% higher than the recoveries obtained with\u00a0\u03b3-ray irradiation. No additional radiolabel was recovered in kill-control samples after an additional 24 or 65\u00a0h of incubation, suggesting that all treatments were effective at arresting Hg(II)-methylating bacterial activity, and that the initial recoveries are likely due to non-methylated\u00a0197Hg(II) carry-over in the organic extraction and/or [197Hg]CH3Hg produced via abiotic reactions. Two CH3Hg extraction methods from sediment were compared: (a) direct extraction into toluene after sediment leaching with CuSO4\u00a0and HCl and (b) the same extraction with an additional back-extraction step to thiosulphate. Similar information was obtained with both methods, but the low efficiency observed and the extra work associated with the back-extraction procedure represent significant disadvantages, even tough the direct extraction involves higher Hg(II) carry over.", "description": "8 p.", "publisher": { "@type": "Organization", "name": "Elsevier" }, "author": [ { "@type": "Person", "name": "Guevara, S.R.", "givenName": "S.R.", "familyName": "Guevara" }, { "@type": "Person", "name": "Perez, Catan S.", "givenName": "Catan S.", "familyName": "Perez" }, { "@type": "Person", "name": "Marvin-DiPasquale, Mark C. mmarvin@usgs.gov", "givenName": "Mark C.", "familyName": "Marvin-DiPasquale", "email": "mmarvin@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-8186-9167", "url": "https://orcid.org/0000-0002-8186-9167" }, "affiliation": [ { "@type": "Organization", "name": "WMA - Earth System Processes Division", "url": "https://www.usgs.gov/mission-areas/water-resources" }, { "@type": "Organization", "name": "National Research Program - Western Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" } ] }, { "@type": "Person", "name": "Magnavacca, C.", "givenName": "C.", "familyName": "Magnavacca" }, { "@type": "Person", "name": "Cohen, I.M.", "givenName": "I.M.", "familyName": "Cohen" }, { "@type": "Person", "name": "Arribere, M.", "givenName": "M.", "familyName": "Arribere" } ], "funder": [ { "@type": "Organization", "name": "Toxic Substances Hydrology Program", "url": null } ] }, "OpenAlex": { "abstract_inverted_index": { "Methodological": [ 0 ], "considerations": [ 1 ], "on": [ 2, 13 ], "the": [ 3, 48, 84, 95, 126, 144, 149, 154, 162 ], "determination": [ 4 ], "of": [ 5, 69 ], "benthic": [ 6 ], "methyl-mercury": [ 7 ], "(CH3Hg)": [ 8 ], "production": [ 9 ], "potentials": [ 10 ], "were": [ 11, 25, 75, 110 ], "investigated": [ 12 ], "lake": [ 14 ], "sediment,": [ 15 ], "using": 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