Item talk:Q240793
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{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Two new organic reference materials for \u03b413C and \u03b415N measurements and a new value for the \u03b413C of NBS 22 oil", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70185128", "url": "https://pubs.usgs.gov/publication/70185128" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70185128 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1002/rcm.1219", "url": "https://doi.org/10.1002/rcm.1219" } ], "journal": { "@type": "Periodical", "name": "Rapid Communications in Mass Spectrometry", "volumeNumber": "17", "issueNumber": "22" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Rapid Communications in Mass Spectrometry" } ], "datePublished": "2003", "dateModified": "2017-06-02", "abstract": "Analytical grade L-glutamic acid is chemically stable and has a C/N mole ratio of 5, which is close to that of many of natural biological materials, such as blood and animal tissue. Two L-glutamic acid reference materials with substantially different 13C and 15N abundances have been prepared for use as organic reference materials for C and N isotopic measurements. USGS40 is analytical grade L-glutamic acid and has a \u03b413C value of \u221226.24\u2030 relative to VPDB and a \u03b415N value of \u22124.52\u2030 relative to N2 in air. USGS41 was prepared by dissolving analytical grade L-glutamic acid with L-glutamic acid enriched in 13C and 15N. USGS41 has a \u03b413C value of +37.76\u2030 and a \u03b415N value of +47.57\u2030. The \u03b413C and \u03b415N values of both materials were measured against the international reference materials NBS 19 calcium carbonate (\u03b413C\u2009=\u2009+1.95\u2030), L-SVEC lithium carbonate (\u03b413C\u2009=\u2009\u221246.48\u2030), IAEA-N-1 ammonium sulfate (\u03b415N\u2009=\u20090.43\u2030), and USGS32 potassium nitrate (\u03b415N\u2009=\u2009180\u2030) by on-line combustion continuous-flow and off-line dual-inlet isotope-ratio mass spectrometry. Both USGS40 and USGS41 are isotopically homogeneous; reproducibility of \u03b413C is better than 0.13\u2030, and that of \u03b415N is better than 0.13\u2030 in 100-\u03bcg amounts. These two isotopic reference materials can be used for (i) calibrating local laboratory reference materials, and (ii) quantifying drift with time, mass-dependent fractionations, and isotope-ratio-scale contraction in the isotopic analysis of various biological materials. Isotopic results presented in this paper yield a \u03b413C value for NBS 22 oil of \u221229.91\u2030, in contrast to the commonly accepted value of \u221229.78\u2030 for which off-line blank corrections probably have not been quantified satisfactorily.", "description": "5 p. ", "publisher": { "@type": "Organization", "name": "Wiley" }, "author": [ { "@type": "Person", "name": "Qi, Haiping haipingq@usgs.gov", "givenName": "Haiping", "familyName": "Qi", "email": "haipingq@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-8339-744X", "url": "https://orcid.org/0000-0002-8339-744X" }, "affiliation": [ { "@type": "Organization", "name": "National Research Program - Eastern Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" } ] }, { "@type": "Person", "name": "Coplen, Tyler B. tbcoplen@usgs.gov", "givenName": "Tyler B.", "familyName": "Coplen", "email": "tbcoplen@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-4884-6008", "url": "https://orcid.org/0000-0003-4884-6008" }, "affiliation": [ { "@type": "Organization", "name": "WMA - Earth System Processes Division", "url": "https://www.usgs.gov/mission-areas/water-resources" }, { "@type": 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"PropertyValue", "propertyID": "ORCID", "value": "0000-0001-5693-6455", "url": "https://orcid.org/0000-0001-5693-6455" } } ], "funder": [ { "@type": "Organization", "name": "Toxic Substances Hydrology Program", "url": null } ] }, "OpenAlex": { "abstract_inverted_index": { "Analytical": [ 0 ], "grade": [ 1, 62, 96 ], "L-glutamic": [ 2, 33, 63, 97, 100 ], "acid": [ 3, 34, 64, 98, 101 ], "is": [ 4, 16, 60, 189, 199 ], "chemically": [ 5 ], "stable": [ 6 ], "and": [ 7, 29, 41, 55, 65, 77, 105, 116, 126, 161, 173, 181, 195, 223, 231 ], "has": [ 8, 66, 108 ], "a": [ 9, 67, 78, 109, 117, 249 ], "C/N": [ 10 ], "mole": [ 11 ], "ratio": [ 12 ], "of": [ 13, 20, 22, 70, 81, 112, 120, 129, 187, 197, 238, 256, 267 ], "5,": [ 14 ], "which": [ 15, 272 ], "close": [ 17 ], "to": [ 18, 75, 86, 262 ], "that": [ 19, 196 ], "many": [ 21 ], "natural": [ 23 ], "biological": [ 24, 240 ], "materials,": [ 25, 222 ], "such": [ 26 ], "as": [ 27, 49 ], "blood": [ 28 ], "animal": [ 30 ], "tissue.": [ 31 ], "Two": [ 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