Item talk:Q239197
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Spatial dependence of reduced sulfur in Everglades dissolved organic matter controlled by sulfate enrichment", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70187107", "url": "https://pubs.usgs.gov/publication/70187107" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70187107 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1021/acs.est.6b04142", "url": "https://doi.org/10.1021/acs.est.6b04142" } ], "journal": { "@type": "Periodical", "name": "Environmental Science & Technology", "volumeNumber": "51", "issueNumber": "7" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Environmental Science & Technology" } ], "datePublished": "2017", "dateModified": "2018-04-02", "abstract": "Sulfate inputs to the Florida Everglades stimulate sulfidic conditions in freshwater wetland sediments that affect ecological and biogeochemical processes. An unexplored implication of sulfate enrichment is alteration of the content and speciation of sulfur in dissolved organic matter (DOM), which influences the reactivity of DOM with trace metals. Here, we describe the vertical and lateral spatial dependence of sulfur chemistry in the hydrophobic organic acid fraction of DOM from unimpacted and sulfate-impacted Everglades wetlands using X-ray absorption spectroscopy and ultrahigh-resolution mass spectrometry. Spatial variation in DOM sulfur content and speciation reflects the degree of sulfate enrichment and resulting sulfide concentrations in sediment pore waters. Sulfur is incorporated into DOM predominantly as highly reduced species in sulfidic pore waters. Sulfur-enriched DOM in sediment pore waters exchanges with overlying surface waters and the sulfur likely undergoes oxidative transformations in the water column. Across all wetland sites and depths, the total sulfur content of DOM correlated with the relative abundance of highly reduced sulfur functionality. The results identify sulfate input as a primary determinant on DOM sulfur chemistry to be considered in the context of wetland restoration and sulfur and trace metal cycling.", "description": "10 p.", "publisher": { "@type": "Organization", "name": "American Chemical Society" }, "author": [ { "@type": "Person", "name": "Ryan, Joseph N.", "givenName": "Joseph N.", "familyName": "Ryan", "affiliation": [ { "@type": "Organization", "name": "University of Colorado- Boulder" } ] }, { "@type": "Person", "name": "Nagy, Kathryn L.", "givenName": "Kathryn L.", "familyName": "Nagy" }, { "@type": "Person", "name": "Stubbins, Aron", "givenName": "Aron", "familyName": "Stubbins" }, { "@type": "Person", "name": "Dittmar, Thorsten", "givenName": "Thorsten", "familyName": "Dittmar" }, { "@type": "Person", "name": "Orem, William H. borem@usgs.gov", "givenName": "William H.", "familyName": "Orem", "email": "borem@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-4990-0539", "url": "https://orcid.org/0000-0003-4990-0539" }, "affiliation": [ { "@type": "Organization", "name": "Eastern Energy Resources Science Center", "url": "https://www.usgs.gov/centers/geology-energy-and-minerals-science-center" } ] }, { "@type": "Person", "name": "Krabbenhoft, David P. dpkrabbe@usgs.gov", "givenName": "David P.", "familyName": "Krabbenhoft", "email": "dpkrabbe@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-1964-5020", "url": "https://orcid.org/0000-0003-1964-5020" }, "affiliation": [ { "@type": "Organization", "name": "National Research Program - Central Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" }, { "@type": "Organization", "name": "Wisconsin Water Science Center", "url": "https://www.usgs.gov/centers/upper-midwest-water-science-center" }, { "@type": "Organization", "name": "WMA - Laboratory & Analytical Services Division", "url": "https://www.usgs.gov/mission-areas/water-resources" }, { "@type": "Organization", "name": "Upper Midwest Water Science Center", "url": "https://www.usgs.gov/centers/upper-midwest-water-science-center" } ] }, { "@type": "Person", "name": "Aiken, George R. graiken@usgs.gov", "givenName": "George R.", "familyName": "Aiken", "email": "graiken@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0001-8454-0984", "url": "https://orcid.org/0000-0001-8454-0984" }, "affiliation": [ { "@type": "Organization", "name": "National Research Program - Central Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" }, { "@type": "Organization", "name": "Colorado Water Science Center", "url": "https://www.usgs.gov/centers/colorado-water-science-center" } ] }, { "@type": "Person", "name": "Poulin, Brett A. bpoulin@usgs.gov", "givenName": "Brett A.", "familyName": "Poulin", "email": "bpoulin@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-5555-7733", "url": "https://orcid.org/0000-0002-5555-7733" }, "affiliation": [ { "@type": "Organization", "name": "National Research Program - Central Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" } ] } ], "funder": [ { "@type": "Organization", "name": "National Research Program - Central Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" } ], "spatialCoverage": [ { "@type": "Place", "additionalType": "country", "name": "United States", "url": "https://geonames.org/4074035" }, { "@type": "Place", "additionalType": "state", "name": "Florida" }, { "@type": "Place", "additionalType": "unknown", "name": "Everglades National Park" }, { "@type": "Place", "geo": [ { "@type": "GeoShape", "additionalProperty": { "@type": "PropertyValue", "name": "GeoJSON", "value": { "type": "FeatureCollection", "features": [ { "type": "Feature", "properties": {}, "geometry": { "type": "Polygon", "coordinates": [ [ 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67, 85, 108, 119, 151, 172 ], "with": [ 45, 125, 153 ], "trace": [ 46, 187 ], "metals.": [ 47 ], "Here,": [ 48 ], "we": [ 49 ], "describe": [ 50 ], "vertical": [ 52 ], "lateral": [ 54 ], "spatial": [ 55 ], "dependence": [ 56 ], "chemistry": [ 59, 174 ], "hydrophobic": [ 62 ], "acid": [ 64 ], "fraction": [ 65 ], "from": [ 68 ], "unimpacted": [ 69 ], "sulfate-impacted": [ 71 ], "wetlands": [ 73 ], "using": [ 74 ], "X-ray": [ 75 ], "absorption": [ 76 ], "spectroscopy": [ 77 ], "ultrahigh-resolution": [ 79 ], "mass": [ 80 ], "spectrometry.": [ 81 ], "Spatial": [ 82 ], "variation": [ 83 ], "reflects": [ 90 ], "degree": [ 92 ], "resulting": [ 97 ], "sulfide": [ 98 ], "concentrations": [ 99 ], "sediment": [ 101, 121 ], "pore": [ 102, 116, 122 ], "waters.": [ 103, 117 ], "Sulfur": [ 104 ], "incorporated": [ 106 ], "into": [ 107 ], "predominantly": [ 109 ], "as": [ 110, 167 ], "highly": [ 111, 158 ], "reduced": [ 112, 159 ], "species": [ 113 ], "Sulfur-enriched": [ 118 ], "waters": [ 123, 128 ], "exchanges": [ 124 ], "overlying": [ 126 ], "surface": [ 127 ], "likely": [ 132 ], "undergoes": [ 133 ], "oxidative": [ 134 ], "transformations": [ 135 ], "water": [ 138 ], "column.": [ 139 ], "Across": [ 140 ], "all": [ 141 ], "sites": [ 143 ], "depths,": [ 145 ], "total": [ 147 ], "correlated": [ 152 ], "relative": [ 155 ], "abundance": [ 156 ], "functionality.": [ 161 ], "The": [ 162 ], "results": [ 163 ], "identify": [ 164 ], "input": [ 166 ], "a": [ 168 ], "primary": [ 169 ], "determinant": [ 170 ], "on": [ 171 ], "be": [ 176 ], "considered": [ 177 ], "context": [ 180 ], "restoration": [ 183 ], "metal": [ 188 ], "cycling.": [ 189 ] }, "apc_list": null, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5069523001", "display_name": "Brett A. 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Poulin", "raw_affiliation_strings": [ "Department of Civil, Environmental, and Architectural Engineering, University of Colorado Boulder , Boulder, Colorado 80309, United States.", "U.S. Geological Survey , Boulder, Colorado 80303, United States." ], "affiliations": [ { "raw_affiliation_string": "Department of Civil, Environmental, and Architectural Engineering, University of Colorado Boulder , Boulder, Colorado 80309, United States.", "institution_ids": [ "https://openalex.org/I188538660" ] }, { "raw_affiliation_string": "U.S. Geological Survey , Boulder, Colorado 80303, United States.", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5003947910", "display_name": "Joseph N. Ryan", "orcid": "https://orcid.org/0000-0002-0308-0590" }, "institutions": [ { "id": "https://openalex.org/I188538660", "display_name": "University of Colorado Boulder", "ror": "https://ror.org/02ttsq026", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I188538660" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Joseph N. Ryan", "raw_affiliation_strings": [ "Department of Civil, Environmental, and Architectural Engineering , University of Colorado Boulder , Boulder , Colorado 80309 , United States." ], "affiliations": [ { "raw_affiliation_string": "Department of Civil, Environmental, and Architectural Engineering , University of Colorado Boulder , Boulder , Colorado 80309 , United States.", "institution_ids": [ "https://openalex.org/I188538660" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5056521299", "display_name": "Kathryn L. Nagy", "orcid": "https://orcid.org/0000-0002-4997-7547" }, "institutions": [ { "id": "https://openalex.org/I39422238", "display_name": "University of Illinois at Chicago", "ror": "https://ror.org/02mpq6x41", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I39422238" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Kathryn L. Nagy", "raw_affiliation_strings": [ "Department of Earth and Environmental Sciences , University of Illinois at Chicago , Chicago , Illinois 60607 , United States." ], "affiliations": [ { "raw_affiliation_string": "Department of Earth and Environmental Sciences , University of Illinois at Chicago , Chicago , Illinois 60607 , United States.", "institution_ids": [ "https://openalex.org/I39422238" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5045728989", "display_name": "Aron Stubbins", "orcid": "https://orcid.org/0000-0002-3994-1946" }, "institutions": [ { "id": "https://openalex.org/I165733156", "display_name": "University of Georgia", "ror": "https://ror.org/00te3t702", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I165733156" ] }, { "id": "https://openalex.org/I122690471", "display_name": "Skidaway Institute of Oceanography", "ror": "https://ror.org/03hjqxp26", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I122690471", "https://openalex.org/I165733156" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Aron Stubbins", "raw_affiliation_strings": [ "Skidaway\rInstitute of Oceanography, Marine Sciences Department, University of Georgia, Savannah, Georgia 31401, United States" ], "affiliations": [ { "raw_affiliation_string": "Skidaway\rInstitute of Oceanography, Marine Sciences Department, University of Georgia, Savannah, Georgia 31401, United States", "institution_ids": [ "https://openalex.org/I165733156", "https://openalex.org/I122690471" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5043332209", "display_name": "Thorsten Dittmar", "orcid": "https://orcid.org/0000-0002-3462-0107" }, "institutions": [ { "id": "https://openalex.org/I129877168", "display_name": "Carl von Ossietzky Universit\u00e4t Oldenburg", "ror": "https://ror.org/033n9gh91", "country_code": "DE", "type": "education", "lineage": [ "https://openalex.org/I129877168" ] } ], "countries": [ "DE" ], "is_corresponding": false, "raw_author_name": "Thorsten Dittmar", "raw_affiliation_strings": [ "Research Group for Marine Geochemistry, Institute for Chemistry and Biology of the Marine Environment (ICBM), University of Oldenburg , Carl-von-Ossietzky-Strasse 9-11, D-26129 Oldenburg, Germany." ], "affiliations": [ { "raw_affiliation_string": "Research Group for Marine Geochemistry, Institute for Chemistry and Biology of the Marine Environment (ICBM), University of Oldenburg , Carl-von-Ossietzky-Strasse 9-11, D-26129 Oldenburg, Germany.", "institution_ids": [ "https://openalex.org/I129877168" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5014418110", "display_name": "William H. 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