Item talk:Q239116
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"abstract": "Dacites dominate the large-volume, explosive eruptions in magmatic arcs, and compositionally similar granodiorites and tonalites constitute the bulk of convergent margin batholiths. Shallow, pre-eruptive storage conditions are well known for many dacitic arc magmas through melt inclusions, Fe\u2013Ti oxides, and experiments, but their potential origins deeper in the crust are not well determined. Accordingly, we report experimental results identifying the P\u2013T\u2013H2O conditions under which hydrous dacitic liquid may segregate from hornblende (hbl)-gabbroic sources either during crystallization\u2013differentiation or partial melting. Two compositions were investigated: (1) MSH\u2013Yn\u22121 dacite (SiO2: 65\u00a0wt%) from Mount St. Helens\u2019 voluminous Yn tephra and (2) MSH\u2013Yn\u22121\u2009+\u200910% cpx to force saturation with cpx and map a portion of the cpx\u2009+\u2009melt\u2009=\u2009hbl peritectic reaction boundary. H2O-undersaturated (3, 6, and 9\u00a0wt% H2O) piston cylinder experiments were conducted at pressures, temperatures, and fO2 appropriate for the middle to lower arc crust (400, 700, and 900\u00a0MPa, 825\u20131100\u2009\u00b0C, and the Re\u2013ReO2 buffer\u2009\u2248\u2009Ni\u2013NiO\u2009+\u20092). Results for MSH\u2013Yn\u22121 indicate near-liquidus equilibrium with a cpx-free hbl-gabbro residue (hbl, plg, magnetite, \u00b1 opx, and ilmeno-hematite) with 6\u20137\u00a0wt% dissolved H2O, 925\u2009\u00b0C, and 700\u2013900\u00a0MPa. Opx disappears down-temperature consistent with the reaction opx\u2009+\u2009melt\u2009=\u2009hbl. Cpx-added phase relations are similar in that once ~10% cpx crystallizes, multiple saturation is attained with cpx, hbl, and plg, +/\u2212 opx, at 6\u20137\u00a0wt% dissolved H2O, 940\u2009\u00b0C, and 700\u2013900\u00a0MPa. Plg\u2013hbl\u2013cpx saturated liquids diverge from plg\u2013hbl\u2013opx saturated liquids, consistent with the MSH\u2013Yn\u22121 dacite marking a liquid composition along a peritectic distributary reaction boundary where hbl appears down-temperature as opx\u2009+\u2009cpx are consumed. The abundance of saturating phases along this distributary peritectic (liquid\u2009+\u2009hbl\u2009+\u2009opx\u2009+\u2009cpx\u2009+\u2009plg\u2009+\u2009oxides) reduces the variance, so liquids are restricted to dacite\u2013granodiorite\u2013tonalite compositions. Higher-K dacites than the Yn would also saturate with biotite, further limiting their compositional diversity. Theoretical evaluation of the energetics of peritectic melting of pargasitic amphiboles indicates that melting and crystallization of amphibole occur abruptly, proximal to amphibole\u2019s high-temperature stability limit, which causes the system to dwell thermally under the conditions that produce dacitic compositions. This process may account for the compositional homogeneity of dacites, granodiorites, and tonalites in arc settings, but their relative mobility compared to rhyolitic/granitic liquids likely accounts for their greater abundance.",
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