Item talk:Q238257
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{
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Online heating is an emerging approach for this need, but is relatively untested and major questions of how to best deliver standards and assess interference by organics have not been evaluated. We examined these issues in our application of measuring woody stem xylem of sagebrush using a Picarro laser spectrometer with online induction heating. We determined (1) effects of cryogenic compared to induction-heating extraction, (2) effects of delivery of standards on filter media compared to on woody stem sections, and (3) spectral interference from organic compounds for these approaches (and developed a technique to do so). Our results suggest that matching sample and standard media improves accuracy, but that isotopic values differ with the extraction method in ways that are not due to spectral interference from organics.", "description": "17 p.", "publisher": { "@type": "Organization", "name": "Taylor & Francis" }, "author": [ { "@type": "Person", "name": "Lazarus, Brynne E. blazarus@usgs.gov", "givenName": "Brynne E.", "familyName": "Lazarus", "email": "blazarus@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-6352-486X", "url": "https://orcid.org/0000-0002-6352-486X" }, "affiliation": [ { "@type": "Organization", "name": "Forest and Rangeland Ecosys Science Center", "url": "https://www.usgs.gov/centers/forest-and-rangeland-ecosystem-science-center" }, { "@type": "Organization", "name": "Forest and Rangeland Ecosystem Science Center", "url": "https://www.usgs.gov/centers/forest-and-rangeland-ecosystem-science-center" } ] }, { "@type": "Person", "name": "Vander Veen, Jessica L.", "givenName": "Jessica L.", "familyName": "Vander Veen", "affiliation": [ { "@type": "Organization", "name": "USGS FRESC" } ] }, { "@type": "Person", "name": "Germino, Matthew J. mgermino@usgs.gov", "givenName": "Matthew J.", "familyName": "Germino", "email": "mgermino@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0001-6326-7579", "url": "https://orcid.org/0000-0001-6326-7579" }, "affiliation": [ { "@type": "Organization", "name": "Forest and Rangeland Ecosys Science Center", "url": "https://www.usgs.gov/centers/forest-and-rangeland-ecosystem-science-center" }, { "@type": "Organization", "name": "Forest and Rangeland Ecosystem Science Center", "url": "https://www.usgs.gov/centers/forest-and-rangeland-ecosystem-science-center" } ] } ], "funder": [ { "@type": "Organization", "name": "Forest and Rangeland Ecosystem Science Center", "url": "https://www.usgs.gov/centers/forest-and-rangeland-ecosystem-science-center" } ] }, "OpenAlex": { "abstract_inverted_index": { "Application": [ 0 ], "of": [ 1, 4, 8, 17, 41, 63, 68, 83, 91, 93 ], "stable": [ 2 ], "isotopes": [ 3 ], "water": [ 5, 19 ], "to": [ 6, 43, 86, 99, 118, 147 ], "studies": [ 7 ], "plant\u2013soil": [ 9 ], "interactions": [ 10 ], "often": [ 11 ], "requires": [ 12 ], "a": [ 13, 71, 116 ], "substantial": [ 14 ], "preparatory": [ 15 ], "step": [ 16 ], "extracting": [ 18 ], "from": [ 20, 108, 150 ], "samples": [ 21 ], "without": [ 22 ], "fractionating": [ 23 ], "isotopes.": [ 24 ], "Online": [ 25 ], "heating": [ 26 ], "is": [ 27, 35 ], "an": [ 28 ], "emerging": [ 29 ], "approach": [ 30 ], "for": [ 31, 111 ], "this": [ 32 ], "need,": [ 33 ], "but": [ 34, 132 ], "relatively": [ 36 ], "untested": [ 37 ], "and": [ 38, 47, 104, 127 ], "major": [ 39 ], "questions": [ 40 ], "how": [ 42 ], "best": [ 44 ], "deliver": [ 45 ], "standards": [ 46, 94 ], "assess": [ 48 ], "interference": [ 49, 107, 149 ], "by": [ 50 ], "organics": [ 51 ], "have": [ 52 ], "not": [ 53, 145 ], "been": [ 54 ], "evaluated.": [ 55 ], "We": [ 56, 79 ], "examined": [ 57 ], "these": [ 58, 112 ], "issues": [ 59 ], "in": [ 60, 141 ], "our": [ 61 ], "application": [ 62 ], "measuring": [ 64 ], "woody": [ 65, 101 ], "stem": [ 66, 102 ], "xylem": [ 67 ], "sagebrush": [ 69 ], "using": [ 70 ], "Picarro": [ 72 ], "laser": [ 73 ], "spectrometer": [ 74 ], "with": [ 75, 137 ], "online": [ 76 ], "induction": [ 77 ], "heating.": [ 78 ], "determined": [ 80 ], "(1)": [ 81 ], "effects": [ 82, 90 ], "cryogenic": [ 84 ], "compared": [ 85, 98 ], "induction-heating": [ 87 ], "extraction,": [ 88 ], "(2)": [ 89 ], "delivery": [ 92 ], "on": [ 95, 100 ], "filter": [ 96 ], "media": [ 97, 129 ], "sections,": [ 103 ], "(3)": [ 105 ], "spectral": [ 106, 148 ], "organic": [ 109 ], "compounds": [ 110 ], "approaches": [ 113 ], "(and": [ 114 ], "developed": [ 115 ], "technique": [ 117 ], "do": [ 119 ], "so).": [ 120 ], "Our": [ 121 ], "results": [ 122 ], "suggest": [ 123 ], "that": [ 124, 133, 143 ], "matching": [ 125 ], "sample": [ 126 ], "standard": [ 128 ], "improves": [ 130 ], "accuracy,": [ 131 ], "isotopic": [ 134 ], "values": [ 135 ], "differ": [ 136 ], "the": [ 138 ], "extraction": [ 139 ], "method": [ 140 ], "ways": [ 142 ], "are": [ 144 ], "due": [ 146 ], "organics.": [ 151 ] }, "apc_list": null, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5023230044", "display_name": "Brynne E. 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