Item talk:Q237739
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Influence of natural organic matter on the adsorption of metal ion onto clay particles", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70185180", "url": "https://pubs.usgs.gov/publication/70185180" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70185180 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1021/es010271p", "url": "https://doi.org/10.1021/es010271p" } ], "journal": { "@type": "Periodical", "name": "Environmental Science & Technology", "volumeNumber": "36", "issueNumber": "13" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Environmental Science & Technology" } ], "datePublished": "2002", "dateModified": "2018-11-26", "abstract": "The influence of natural organic matter (NOM) on the adsorption of Al, Fe, Zn, and Pb onto clay minerals was investigated. Adsorption experiments were carried out at pH = 5 and pH = 7 in the presence and absence of NOM. In general, the presence of NOM decreased the adsorption of metal ions onto the clay particles. Al and Fe were strongly influenced by NOM, whereas Zn and Pb adsorption was only slightly altered. The interaction of the metal ions with the minerals and the influence of NOM on this interaction was investigated by coupling SdFFF with an inductively coupled plasma mass spectrometer (ICPMS) or an inductively coupled plasma atomic emission spectrometer (ICPAES). Quantitative atomization of the clay particles in the ICP was confirmed by comparing elemental content determined by direct injection of the clay into the ICPMS with values from acid digestion. Particle sizes of the clays were found to be between 0.1 and 1 \u03bcm by sedimentation field-flow fractionation (SdFFF) with UV detection. Aggregation of particles due to metal adsorption was observed using SdFFF-ICPMS measurements. 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R.", "familyName": "Aiken", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0001-8454-0984", "url": "https://orcid.org/0000-0001-8454-0984" } }, { "@type": "Person", "name": "Roth, D.A.", "givenName": "D.A.", "familyName": "Roth" }, { "@type": "Person", "name": "Frimmel, F.H.", "givenName": "F.H.", "familyName": "Frimmel" } ], "funder": [ { "@type": "Organization", "name": "Toxic Substances Hydrology Program", "url": null } ] }, "OpenAlex": { "abstract_inverted_index": { "The": [ 0, 74 ], "influence": [ 1, 85 ], "of": [ 2, 10, 39, 45, 50, 76, 86, 115, 132, 145, 166, 191 ], "natural": [ 3 ], "organic": [ 4 ], "matter": [ 5 ], "(NOM)": [ 6 ], "on": [ 7, 88, 181 ], "the": [ 8, 35, 43, 48, 54, 77, 81, 84, 116, 120, 133, 136, 146, 182, 189 ], "adsorption": [ 9, 49, 69, 171 ], "Al,": [ 11 ], "Fe,": [ 12 ], "Zn,": [ 13 ], "and": [ 14, 30, 37, 58, 67, 83, 154, 186, 193 ], "Pb": [ 15, 68 ], "onto": [ 16, 53 ], "clay": [ 17, 55, 117, 134 ], "minerals": [ 18, 82 ], "was": [ 19, 70, 91, 122, 172, 179 ], "investigated.": [ 20 ], "Adsorption": [ 21 ], "experiments": [ 22 ], "were": [ 23, 60, 148 ], "carried": [ 24 ], "out": [ 25 ], "at": [ 26, 194 ], "pH": [ 27, 31, 196 ], "=": [ 28, 32 ], "5": [ 29 ], "7": [ 33 ], "in": [ 34, 119, 188 ], "presence": [ 36, 44, 190 ], "absence": [ 38 ], "NOM.": [ 40 ], "In": [ 41 ], "general,": [ 42 ], "NOM": [ 46, 87, 192 ], "decreased": [ 47, 187 ], "metal": [ 51, 78, 170, 184 ], "ions": [ 52, 79 ], "particles.": [ 56 ], "Al": [ 57 ], "Fe": [ 59 ], "strongly": [ 61 ], "influenced": [ 62 ], "by": [ 63, 93, 124, 129, 157 ], "NOM,": [ 64 ], "whereas": [ 65 ], "Zn": [ 66 ], "only": [ 71 ], "slightly": [ 72 ], "altered.": [ 73 ], "interaction": [ 75, 90 ], "with": [ 80, 96, 138, 162 ], "this": [ 89 ], "investigated": [ 92 ], "coupling": [ 94 ], "SdFFF": [ 95 ], "an": [ 97, 105 ], "inductively": [ 98, 106 ], "coupled": [ 99, 107 ], "plasma": [ 100, 108 ], "mass": [ 101 ], "spectrometer": [ 102, 111 ], "(ICPMS)": [ 103 ], "or": [ 104 ], "atomic": [ 109 ], "emission": [ 110 ], "(ICPAES).": [ 112 ], "Quantitative": [ 113 ], "atomization": [ 114 ], "particles": [ 118, 167 ], "ICP": [ 121 ], "confirmed": [ 123 ], "comparing": [ 125 ], "elemental": [ 126 ], "content": [ 127 ], "determined": [ 128 ], "direct": [ 130 ], "injection": [ 131 ], "into": [ 135 ], "ICPMS": [ 137 ], "values": [ 139 ], "from": [ 140 ], "acid": [ 141 ], "digestion.": [ 142 ], "Particle": [ 143 ], "sizes": [ 144 ], "clays": [ 147 ], "found": [ 149 ], "to": [ 150, 169 ], "be": [ 151 ], "between": [ 152 ], "0.1": [ 153 ], "1": [ 155 ], "\u03bcm": [ 156 ], "sedimentation": [ 158 ], "field-flow": [ 159 ], "fractionation": [ 160 ], "(SdFFF)": [ 161 ], "UV": [ 163 ], "detection.": [ 164 ], "Aggregation": [ 165 ], "due": [ 168 ], "observed": [ 173 ], "using": [ 174 ], "SdFFF-ICPMS": [ 175 ], "measurements.": [ 176 ], "This": [ 177 ], "aggregation": [ 178 ], "dependent": [ 180 ], "specific": [ 183 ], "ion": [ 185 ], "higher": [ 195 ], "value.": [ 197 ] }, "apc_list": null, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5053154374", "display_name": "Daniel Schmitt", "orcid": "https://orcid.org/0000-0003-4314-5819" }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "D. 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