Item talk:Q236330
From geokb
{
"USGS Publications Warehouse": {
"@context": "https://schema.org",
"@type": "Article",
"additionalType": "Journal Article",
"name": "Compositional and stable carbon isotopic fractionation during non-autocatalytic thermochemical sulfate reduction by gaseous hydrocarbons",
"identifier": [
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse IndexID",
"value": "70112026",
"url": "https://pubs.usgs.gov/publication/70112026"
},
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse Internal ID",
"value": 70112026
},
{
"@type": "PropertyValue",
"propertyID": "DOI",
"value": "10.1016/j.gca.2014.05.004",
"url": "https://doi.org/10.1016/j.gca.2014.05.004"
}
],
"journal": {
"@type": "Periodical",
"name": "Geochimica et Cosmochimica Acta",
"volumeNumber": "139",
"issueNumber": null
},
"inLanguage": "en",
"isPartOf": [
{
"@type": "CreativeWorkSeries",
"name": "Geochimica et Cosmochimica Acta"
}
],
"datePublished": "2014",
"dateModified": "2014-06-10",
"abstract": "The possibility of autocatalysis during thermochemical sulfate reduction (TSR) by gaseous hydrocarbons was investigated by examination of previously reported laboratory and field data. This reaction was found to be a kinetically controlled non-autocatalytic process, and the apparent lack of autocatalysis is thought to be due to the absence of the required intermediate species. Kinetic parameters for chemical and carbon isotopic fractionations of gaseous hydrocarbons affected by TSR were calculated and found to be consistent with experimentally derived values for TSR involving long-chain hydrocarbons. Model predictions based on these kinetic values indicate that TSR by gaseous hydrocarbon requires high-temperature conditions. The oxidation of C2\u20135 hydrocarbons by sulfate reduction is accompanied by carbon isotopic fractionation with the residual C2\u20135 hydrocarbons becoming more enriched in 13C. Kinetic parameters were calculated for the stable carbon isotopic fractionation of gaseous hydrocarbons that have experienced TSR. Model predictions based on these kinetics indicate that it may be difficult to distinguish the effects of TSR from those of thermal maturation at lower levels of hydrocarbon oxidation; however, unusually heavy \u03b413C2+ values (>\u221210\u2030) can be diagnostic of high levels of conversion (>50%). Stoichiometric and stable carbon isotopic data show that methane is stable under the investigated reaction conditions and is likely a product of TSR by other gaseous hydrocarbons rather than a significant reactant. These results indicate that the overall TSR reaction mechanism for oxidation of organic substrates containing long-chain hydrocarbons involves three distinct phases as follows: (1) an initial slow and non-autocatalytic stage characterized by the reduction of reactive sulfate by long-chain saturated hydrocarbons; (2) a second autocatalytic reaction phase dominated by reactions involving reduced sulfur species and partially oxidized hydrocarbons; (3) and a final, or late-stage, TSR reaction in which hydrocarbon oxidation continues at a slower rate via the non-autocatalytic reduction of sulfate by gaseous hydrocarbons.",
"description": "15 p.",
"publisher": {
"@type": "Organization",
"name": "Elsevier"
},
"author": [
{
"@type": "Person",
"name": "Ellis, Geoffrey S. gsellis@usgs.gov",
"givenName": "Geoffrey S.",
"familyName": "Ellis",
"email": "gsellis@usgs.gov",
"identifier": {
"@type": "PropertyValue",
"propertyID": "ORCID",
"value": "0000-0003-4519-3320",
"url": "https://orcid.org/0000-0003-4519-3320"
},
"affiliation": [
{
"@type": "Organization",
"name": "Central Energy Resources Science Center",
"url": "https://www.usgs.gov/centers/central-energy-resources-science-center"
}
]
},
{
"@type": "Person",
"name": "Ma, Qisheng",
"givenName": "Qisheng",
"familyName": "Ma"
},
{
"@type": "Person",
"name": "Xia, Xinyu",
"givenName": "Xinyu",
"familyName": "Xia"
},
{
"@type": "Person",
"name": "Tang, Yongchun",
"givenName": "Yongchun",
"familyName": "Tang"
}
],
"funder": [
{
"@type": "Organization",
"name": "Central Energy Resources Science Center",
"url": "https://www.usgs.gov/centers/central-energy-resources-science-center"
}
]
},
"OpenAlex": {
"abstract_inverted_index": {
"The": [
0,
99
],
"possibility": [
1
],
"of": [
2,
16,
38,
48,
61,
101,
133,
156,
160,
166,
178,
181,
205,
227,
250,
295
],
"autocatalysis": [
3,
39
],
"during": [
4
],
"thermochemical": [
5
],
"sulfate": [
6,
105,
252,
296
],
"reduction": [
7,
106,
249,
294
],
"(TSR)": [
8
],
"by": [
9,
14,
65,
93,
104,
109,
207,
247,
253,
264,
297
],
"gaseous": [
10,
62,
94,
134,
209,
298
],
"hydrocarbons": [
11,
63,
103,
117,
135,
210,
232
],
"was": [
12,
25
],
"investigated": [
13,
197
],
"examination": [
15
],
"previously": [
17
],
"reported": [
18
],
"laboratory": [
19
],
"and": [
20,
34,
57,
69,
185,
200,
243,
270,
275
],
"field": [
21
],
"data.": [
22
],
"This": [
23
],
"reaction": [
24,
198,
223,
261,
281
],
"found": [
26,
70
],
"to": [
27,
42,
45,
71,
152
],
"be": [
28,
43,
72,
150,
176
],
"a": [
29,
203,
213,
258,
276,
288
],
"kinetically": [
30
],
"controlled": [
31
],
"non-autocatalytic": [
32,
244,
293
],
"process,": [
33
],
"the": [
35,
46,
49,
114,
128,
154,
196,
220,
248,
292
],
"apparent": [
36
],
"lack": [
37
],
"is": [
40,
107,
193,
201
],
"thought": [
41
],
"due": [
44
],
"absence": [
47
],
"required": [
50
],
"intermediate": [
51
],
"species.": [
52
],
"Kinetic": [
53,
123
],
"parameters": [
54,
124
],
"for": [
55,
78,
127,
225
],
"chemical": [
56
],
"carbon": [
58,
110,
130,
187
],
"isotopic": [
59,
111,
131,
188
],
"fractionations": [
60
],
"affected": [
64
],
"TSR": [
66,
79,
92,
157,
206,
222,
280
],
"were": [
67,
125
],
"calculated": [
68,
126
],
"consistent": [
73
],
"with": [
74,
113
],
"experimentally": [
75
],
"derived": [
76
],
"values": [
77,
89,
173
],
"involving": [
80,
266
],
"long-chain": [
81,
231,
254
],
"hydrocarbons.": [
82,
299
],
"Model": [
83,
140
],
"predictions": [
84,
141
],
"based": [
85,
142
],
"on": [
86,
143
],
"these": [
87,
144
],
"kinetic": [
88
],
"indicate": [
90,
146,
218
],
"that": [
91,
136,
147,
191,
219
],
"hydrocarbon": [
95,
167,
284
],
"requires": [
96
],
"high-temperature": [
97
],
"conditions.": [
98
],
"oxidation": [
100,
226,
285
],
"C2\u20135": [
102,
116
],
"accompanied": [
108
],
"fractionation": [
112,
132
],
"residual": [
115
],
"becoming": [
118
],
"more": [
119
],
"enriched": [
120
],
"in": [
121,
282
],
"13C.": [
122
],
"stable": [
129,
186,
194
],
"have": [
137
],
"experienced": [
138
],
"TSR.": [
139
],
"kinetics": [
145
],
"it": [
148
],
"may": [
149
],
"difficult": [
151
],
"distinguish": [
153
],
"effects": [
155
],
"from": [
158
],
"those": [
159
],
"thermal": [
161
],
"maturation": [
162
],
"at": [
163,
287
],
"lower": [
164
],
"levels": [
165,
180
],
"oxidation;": [
168
],
"however,": [
169
],
"unusually": [
170
],
"heavy": [
171
],
"\u03b413C2+": [
172
],
"(>\u221210\u2030)": [
174
],
"can": [
175
],
"diagnostic": [
177
],
"high": [
179
],
"conversion": [
182
],
"(>50%).": [
183
],
"Stoichiometric": [
184
],
"data": [
189
],
"show": [
190
],
"methane": [
192
],
"under": [
195
],
"conditions": [
199
],
"likely": [
202
],
"product": [
204
],
"other": [
208
],
"rather": [
211
],
"than": [
212
],
"significant": [
214
],
"reactant.": [
215
],
"These": [
216
],
"results": [
217
],
"overall": [
221
],
"mechanism": [
224
],
"organic": [
228
],
"substrates": [
229
],
"containing": [
230
],
"involves": [
233
],
"three": [
234
],
"distinct": [
235
],
"phases": [
236
],
"as": [
237
],
"follows:": [
238
],
"(1)": [
239
],
"an": [
240
],
"initial": [
241
],
"slow": [
242
],
"stage": [
245
],
"characterized": [
246
],
"reactive": [
251
],
"saturated": [
255
],
"hydrocarbons;": [
256,
273
],
"(2)": [
257
],
"second": [
259
],
"autocatalytic": [
260
],
"phase": [
262
],
"dominated": [
263
],
"reactions": [
265
],
"reduced": [
267
],
"sulfur": [
268
],
"species": [
269
],
"partially": [
271
],
"oxidized": [
272
],
"(3)": [
274
],
"final,": [
277
],
"or": [
278
],
"late-stage,": [
279
],
"which": [
283
],
"continues": [
286
],
"slower": [
289
],
"rate": [
290
],
"via": [
291
]
},
"apc_list": {
"value": 3690,
"currency": "USD",
"value_usd": 3690,
"provenance": "doaj"
},
"apc_paid": null,
"authorships": [
{
"author_position": "first",
"author": {
"id": "https://openalex.org/A5076446591",
"display_name": "Xinyu Xia",
"orcid": "https://orcid.org/0000-0003-2773-2829"
},
"institutions": [
{
"id": "https://openalex.org/I16718484",
"display_name": "Hess (United States)",
"ror": "https://ror.org/00zbk1w77",
"country_code": "US",
"type": "company",
"lineage": [
"https://openalex.org/I16718484"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Xinyu Xia",
"raw_affiliation_strings": [
"Hess Corporation, Houston, TX 77010, USA"
],
"affiliations": [
{
"raw_affiliation_string": "Hess Corporation, Houston, TX 77010, USA",
"institution_ids": [
"https://openalex.org/I16718484"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5006144755",
"display_name": "Geoffrey S. Ellis",
"orcid": "https://orcid.org/0000-0003-4519-3320"
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Geoffrey S. Ellis",
"raw_affiliation_strings": [
"U.S. Geological Survey, Denver CO 80225, USA"
],
"affiliations": [
{
"raw_affiliation_string": "U.S. Geological Survey, Denver CO 80225, USA",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5032499598",
"display_name": "Qisheng Ma",
"orcid": "https://orcid.org/0000-0001-6884-0477"
},
"institutions": [],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Qisheng Ma",
"raw_affiliation_strings": [
"Power Environmental Energy Research Institute, Covina, CA 91722, USA"
],
"affiliations": [
{
"raw_affiliation_string": "Power Environmental Energy Research Institute, Covina, CA 91722, USA",
"institution_ids": []
}
]
},
{
"author_position": "last",
"author": {
"id": "https://openalex.org/A5100836026",
"display_name": "Yongchun Tang",
"orcid": null
},
"institutions": [],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Yongchun Tang",
"raw_affiliation_strings": [
"Power Environmental Energy Research Institute, Covina, CA 91722, USA"
],
"affiliations": [
{
"raw_affiliation_string": "Power Environmental Energy Research Institute, Covina, CA 91722, USA",
"institution_ids": []
}
]
}
],
"best_oa_location": null,
"biblio": {
"volume": "139",
"issue": null,
"first_page": "472",
"last_page": "486"
},
"citation_normalized_percentile": {
"value": 0.903719,
"is_in_top_1_percent": false,
"is_in_top_10_percent": true
},
"cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2092206175",
"cited_by_count": 44,
"cited_by_percentile_year": {
"min": 95,
"max": 96
},
"concepts": [
{
"id": "https://openalex.org/C37263863",
"wikidata": "https://www.wikidata.org/wiki/Q786897",
"display_name": "Autocatalysis",
"level": 3,
"score": 0.91279626
},
{
"id": "https://openalex.org/C185592680",
"wikidata": "https://www.wikidata.org/wiki/Q2329",
"display_name": "Chemistry",
"level": 0,
"score": 0.75376076
},
{
"id": "https://openalex.org/C2777207669",
"wikidata": "https://www.wikidata.org/wiki/Q43648",
"display_name": "Hydrocarbon",
"level": 2,
"score": 0.70553565
},
{
"id": "https://openalex.org/C516920438",
"wikidata": "https://www.wikidata.org/wiki/Q37129",
"display_name": "Methane",
"level": 2,
"score": 0.6161864
},
{
"id": "https://openalex.org/C97428945",
"wikidata": "https://www.wikidata.org/wiki/Q15305109",
"display_name": "Fractionation",
"level": 2,
"score": 0.5549861
},
{
"id": "https://openalex.org/C140205800",
"wikidata": "https://www.wikidata.org/wiki/Q5860",
"display_name": "Carbon fibers",
"level": 3,
"score": 0.5384327
},
{
"id": "https://openalex.org/C2778343803",
"wikidata": "https://www.wikidata.org/wiki/Q172290",
"display_name": "Sulfate",
"level": 2,
"score": 0.4478147
},
{
"id": "https://openalex.org/C185059815",
"wikidata": "https://www.wikidata.org/wiki/Q471790",
"display_name": "Isotopes of carbon",
"level": 3,
"score": 0.42403486
},
{
"id": "https://openalex.org/C161790260",
"wikidata": "https://www.wikidata.org/wiki/Q82264",
"display_name": "Catalysis",
"level": 2,
"score": 0.20659828
},
{
"id": "https://openalex.org/C107872376",
"wikidata": "https://www.wikidata.org/wiki/Q321355",
"display_name": "Environmental chemistry",
"level": 1,
"score": 0.17700088
},
{
"id": "https://openalex.org/C178790620",
"wikidata": "https://www.wikidata.org/wiki/Q11351",
"display_name": "Organic chemistry",
"level": 1,
"score": 0.17513737
},
{
"id": "https://openalex.org/C192562407",
"wikidata": "https://www.wikidata.org/wiki/Q228736",
"display_name": "Materials science",
"level": 0,
"score": 0.1151883
},
{
"id": "https://openalex.org/C158787203",
"wikidata": "https://www.wikidata.org/wiki/Q900291",
"display_name": "Total organic carbon",
"level": 2,
"score": 0.064576775
},
{
"id": "https://openalex.org/C104779481",
"wikidata": "https://www.wikidata.org/wiki/Q50707",
"display_name": "Composite number",
"level": 2,
"score": 0.0
},
{
"id": "https://openalex.org/C159985019",
"wikidata": "https://www.wikidata.org/wiki/Q181790",
"display_name": "Composite material",
"level": 1,
"score": 0.0
}
],
"corresponding_author_ids": [],
"corresponding_institution_ids": [],
"countries_distinct_count": 1,
"counts_by_year": [
{
"year": 2024,
"cited_by_count": 4
},
{
"year": 2023,
"cited_by_count": 4
},
{
"year": 2022,
"cited_by_count": 6
},
{
"year": 2021,
"cited_by_count": 6
},
{
"year": 2020,
"cited_by_count": 6
},
{
"year": 2019,
"cited_by_count": 7
},
{
"year": 2018,
"cited_by_count": 2
},
{
"year": 2017,
"cited_by_count": 2
},
{
"year": 2016,
"cited_by_count": 2
},
{
"year": 2015,
"cited_by_count": 5
}
],
"created_date": "2016-06-24",
"datasets": [],
"display_name": "Compositional and stable carbon isotopic fractionation during non-autocatalytic thermochemical sulfate reduction by gaseous hydrocarbons",
"doi": "https://doi.org/10.1016/j.gca.2014.05.004",
"fulltext_origin": "ngrams",
"fwci": 1.592,
"grants": [],
"has_fulltext": true,
"id": "https://openalex.org/W2092206175",
"ids": {
"openalex": "https://openalex.org/W2092206175",
"doi": "https://doi.org/10.1016/j.gca.2014.05.004",
"mag": "2092206175"
},
"indexed_in": [
"crossref"
],
"institutions_distinct_count": 2,
"is_paratext": false,
"is_retracted": false,
"keywords": [
{
"id": "https://openalex.org/keywords/autocatalysis",
"display_name": "Autocatalysis",
"score": 0.91279626
},
{
"id": "https://openalex.org/keywords/carbon-fibers",
"display_name": "Carbon fibers",
"score": 0.5384327
},
{
"id": "https://openalex.org/keywords/flue-gas-desulfurization",
"display_name": "Flue Gas Desulfurization",
"score": 0.509897
},
{
"id": "https://openalex.org/keywords/hydrogen-sulfide-adsorption",
"display_name": "Hydrogen Sulfide Adsorption",
"score": 0.502477
}
],
"language": "en",
"locations": [
{
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/j.gca.2014.05.004",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
}
],
"locations_count": 1,
"mesh": [],
"ngrams_url": "https://api.openalex.org/works/W2092206175/ngrams",
"open_access": {
"is_oa": false,
"oa_status": "closed",
"oa_url": null,
"any_repository_has_fulltext": false
},
"primary_location": {
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/j.gca.2014.05.004",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
},
"primary_topic": {
"id": "https://openalex.org/T11802",
"display_name": "Chemical-Looping Technologies",
"score": 0.9931,
"subfield": {
"id": "https://openalex.org/subfields/2204",
"display_name": "Biomedical Engineering"
},
"field": {
"id": "https://openalex.org/fields/22",
"display_name": "Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
"publication_date": "2014-08-01",
"publication_year": 2014,
"referenced_works": [
"https://openalex.org/W1251722559",
"https://openalex.org/W1491454731",
"https://openalex.org/W1604035276",
"https://openalex.org/W1974924765",
"https://openalex.org/W1976086351",
"https://openalex.org/W1979730646",
"https://openalex.org/W1982560855",
"https://openalex.org/W1983940179",
"https://openalex.org/W1986817539",
"https://openalex.org/W2000093983",
"https://openalex.org/W2006872251",
"https://openalex.org/W2008830429",
"https://openalex.org/W2010368000",
"https://openalex.org/W2012425818",
"https://openalex.org/W2014070369",
"https://openalex.org/W2017604168",
"https://openalex.org/W2021157842",
"https://openalex.org/W2025270360",
"https://openalex.org/W2025727078",
"https://openalex.org/W2025895735",
"https://openalex.org/W2028593781",
"https://openalex.org/W2030785057",
"https://openalex.org/W2031557742",
"https://openalex.org/W2033681646",
"https://openalex.org/W2038217202",
"https://openalex.org/W2041184157",
"https://openalex.org/W2047334413",
"https://openalex.org/W2054420874",
"https://openalex.org/W2062113626",
"https://openalex.org/W2066776684",
"https://openalex.org/W2075921416",
"https://openalex.org/W2092041781",
"https://openalex.org/W2108356947",
"https://openalex.org/W2125760267",
"https://openalex.org/W2133403406",
"https://openalex.org/W2150925076",
"https://openalex.org/W2171854569",
"https://openalex.org/W2196488394",
"https://openalex.org/W2330273574",
"https://openalex.org/W2499870883"
],
"referenced_works_count": 40,
"related_works": [
"https://openalex.org/W2471743621",
"https://openalex.org/W2383333462",
"https://openalex.org/W2378774883",
"https://openalex.org/W2372780047",
"https://openalex.org/W2367144928",
"https://openalex.org/W2366462696",
"https://openalex.org/W2169762021",
"https://openalex.org/W2091699432",
"https://openalex.org/W2057015319",
"https://openalex.org/W2037417330"
],
"sustainable_development_goals": [],
"title": "Compositional and stable carbon isotopic fractionation during non-autocatalytic thermochemical sulfate reduction by gaseous hydrocarbons",
"topics": [
{
"id": "https://openalex.org/T11802",
"display_name": "Chemical-Looping Technologies",
"score": 0.9931,
"subfield": {
"id": "https://openalex.org/subfields/2204",
"display_name": "Biomedical Engineering"
},
"field": {
"id": "https://openalex.org/fields/22",
"display_name": "Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T12425",
"display_name": "Sulfur Compounds Removal Technologies",
"score": 0.9907,
"subfield": {
"id": "https://openalex.org/subfields/2210",
"display_name": "Mechanical Engineering"
},
"field": {
"id": "https://openalex.org/fields/22",
"display_name": "Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T10399",
"display_name": "Characterization of Shale Gas Pore Structure",
"score": 0.9905,
"subfield": {
"id": "https://openalex.org/subfields/2211",
"display_name": "Mechanics of Materials"
},
"field": {
"id": "https://openalex.org/fields/22",
"display_name": "Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
}
],
"type": "article",
"type_crossref": "journal-article",
"updated_date": "2024-08-15T09:01:28.740428",
"versions": []
}
}
