Item talk:Q235924
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Acetogenic microbial degradation of vinyl chloride", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70022544", "url": "https://pubs.usgs.gov/publication/70022544" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70022544 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1021/es991371m", "url": "https://doi.org/10.1021/es991371m" }, { "@type": "PropertyValue", "propertyID": "ISSN", "value": "0013936X" } ], "journal": { "@type": "Periodical", "name": "Environmental Science & Technology", "volumeNumber": "34", "issueNumber": "13" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Environmental Science & Technology" } ], "datePublished": "2000", "dateModified": "2018-12-12", "abstract": "Under methanogenic conditions, microbial degradation of [1,2-14C]vinyl chloride (VC) resulted in significant (14 \u00b1 3% maximum recovery) but transient recovery of radioactivity as\u00a014C-acetate. Subsequently,\u00a014C-acetate was degraded to\u00a014CH4\u00a0and\u00a014CO2\u00a0(18 \u00b1 2% and 54 \u00b1 3% final recoveries, respectively). In contrast, under 2-bromoethanesulfonic acid (BES) amended conditions,\u00a014C-acetate recovery remained high (27 \u00b1 1% maximum recovery) throughout the study, no\u00a014CH4\u00a0was produced, and the final recovery of\u00a014CO2\u00a0was only 35 \u00b1 4%. These results demonstrate that oxidative acetogenesis may be an important mechanism for anaerobic VC biodegradation. Moreover, these results (1) demonstrate that microbial degradation of VC to CH4and CO2\u00a0may involve oxidative acetogenesis followed by acetotrophic methanogenesis and (2) suggest that oxidative acetogenesis may be the initial step in the net oxidation of VC to CO2reported previously under Fe(III)-reducing, SO4-reducing, and humic acids-reducing conditions.", "description": "3 p.", "publisher": { "@type": "Organization", "name": "ACS" }, "author": [ { "@type": "Person", "name": "Bradley, P. M.", "givenName": "P. M.", "familyName": "Bradley", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0001-7522-8606", "url": "https://orcid.org/0000-0001-7522-8606" } }, { "@type": "Person", "name": "Chapelle, F. H.", "givenName": "F. H.", "familyName": "Chapelle" } ], "funder": [ { "@type": "Organization", "name": "Toxic Substances Hydrology Program", "url": null } ] }, "OpenAlex": { "abstract_inverted_index": { "Under": [ 0 ], "methanogenic": [ 1 ], "conditions,": [ 2, 49 ], "microbial": [ 3, 98 ], "degradation": [ 4, 99 ], "of": [ 5, 20, 70, 100, 129 ], "[1,2-14C]vinyl": [ 6 ], "chloride": [ 7 ], "(VC)": [ 8 ], "resulted": [ 9 ], "in": [ 10, 125 ], "significant": [ 11 ], "(14": [ 12 ], "\u00b1": [ 13, 33, 37, 55, 75 ], "3%": [ 14, 38 ], "maximum": [ 15, 57 ], "recovery)": [ 16, 58 ], "but": [ 17 ], "transient": [ 18 ], "recovery": [ 19, 51, 69 ], "radioactivity": [ 21 ], "as": [ 22 ], "14C-acetate.": [ 23 ], "Subsequently,": [ 24 ], "14C-acetate": [ 25, 50 ], "was": [ 26, 64, 72 ], "degraded": [ 27 ], "to": [ 28, 102, 131 ], "14CH4": [ 29, 63 ], "and": [ 30, 35, 66, 104, 114, 138 ], "14CO2": [ 31, 71 ], "(18": [ 32 ], "2%": [ 34 ], "54": [ 36 ], "final": [ 39, 68 ], "recoveries,": [ 40 ], "respectively).": [ 41 ], "In": [ 42 ], "contrast,": [ 43 ], "under": [ 44, 135 ], "2-bromoethanesulfonic": [ 45 ], "acid": [ 46 ], "(BES)": [ 47 ], "amended": [ 48 ], "remained": [ 52 ], "high": [ 53 ], "(27": [ 54 ], "1%": [ 56 ], "throughout": [ 59 ], "the": [ 60, 67, 122, 126 ], "study,": [ 61 ], "no": [ 62 ], "produced,": [ 65 ], "only": [ 73 ], "35": [ 74 ], "4%.": [ 76 ], "These": [ 77 ], "results": [ 78, 94 ], "demonstrate": [ 79, 96 ], "that": [ 80, 97, 117 ], "oxidative": [ 81, 108, 118 ], "acetogenesis": [ 82, 109, 119 ], "may": [ 83, 106, 120 ], "be": [ 84, 121 ], "an": [ 85 ], "important": [ 86 ], "mechanism": [ 87 ], "for": [ 88 ], "anaerobic": [ 89 ], "VC": [ 90, 101, 130 ], "biodegradation.": [ 91 ], "Moreover,": [ 92 ], "these": [ 93 ], "(1)": [ 95 ], "CH4": [ 103 ], "CO2": [ 105, 132 ], "involve": [ 107 ], "followed": [ 110 ], "by": [ 111 ], "acetotrophic": [ 112 ], "methanogenesis": [ 113 ], "(2)": [ 115 ], "suggest": [ 116 ], "initial": [ 123 ], "step": [ 124 ], "net": [ 127 ], "oxidation": [ 128 ], "reported": [ 133 ], "previously": [ 134 ], "Fe(III)-reducing,": [ 136 ], "SO4-reducing,": [ 137 ], "humic": [ 139 ], "acids-reducing": [ 140 ], "conditions.": [ 141 ] }, "apc_list": null, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5075056636", "display_name": "Paul M. 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