Item talk:Q233619
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Calorimetry of heterogeneous systems: H+ binding to TiO2 in NaCl", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70015517", "url": "https://pubs.usgs.gov/publication/70015517" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70015517 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1016/0040-6031(89)87125-4", "url": "https://doi.org/10.1016/0040-6031(89)87125-4" }, { "@type": "PropertyValue", "propertyID": "ISSN", "value": "00406031" } ], "journal": { "@type": "Periodical", "name": "Thermochimica Acta", "volumeNumber": "154", "issueNumber": "1" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Thermochimica Acta" } ], "datePublished": "1989", "dateModified": "2020-01-12", "abstract": "A simultaneous calorimetric and potentiometric technique has been developed for measuring the thermodynamics of proton binding to mineral oxides in the presence of a supporting electrolyte. Modifications made to a commercial titration calorimeter to add a combination pH electrode and maintain an inert atmosphere in the calorimeter reaction vessel are described. A procedure to calibrate potentiometric measurements in heterogeneous systems to correct for the suspension effect on pH is given.The enthalpy change for proton dissociation from TiO2\u00a0in aqueous suspension as a function of pH is reported for 0.01, 0.1, and 0.5 M NaCl. The enthalpy change for proton dissociation is endothermic, ranging from 10.5 \u00b1 3.8 to 45.0 \u00b1 3.8 kJ mol\u22121\u00a0over the pH range from 4 to 10.", "description": "15 p.", "publisher": { "@type": "Organization", "name": "Elsevier" }, "author": [ { "@type": "Person", "name": "Mehr, S.R.", "givenName": "S.R.", "familyName": "Mehr" }, { "@type": "Person", "name": "Hansen, L.D.", "givenName": "L.D.", "familyName": "Hansen" }, { "@type": "Person", "name": "Davis, J.A.", "givenName": "J.A.", "familyName": "Davis" }, { "@type": "Person", "name": "Lewis, E.A.", "givenName": "E.A.", "familyName": "Lewis" }, { "@type": "Person", "name": "Eatough, D.J.", "givenName": "D.J.", "familyName": "Eatough" } ], "funder": [ { "@type": "Organization", "name": "Toxic Substances Hydrology Program", "url": null } ] }, "OpenAlex": { "abstract_inverted_index": { "A": [ 0, 51 ], "simultaneous": [ 1 ], "calorimetric": [ 2 ], "and": [ 3, 39, 91 ], "potentiometric": [ 4, 55 ], "technique": [ 5 ], "has": [ 6 ], "been": [ 7 ], "developed": [ 8 ], "for": [ 9, 62, 73, 88, 98 ], "measuring": [ 10 ], "the": [ 11, 20, 45, 63, 115 ], "thermodynamics": [ 12 ], "of": [ 13, 22, 84 ], "proton": [ 14, 74, 99 ], "binding": [ 15 ], "to": [ 16, 28, 33, 53, 60, 108, 120 ], "mineral": [ 17 ], "oxides": [ 18 ], "in": [ 19, 44, 57, 78 ], "presence": [ 21 ], "a": [ 23, 29, 35, 82 ], "supporting": [ 24 ], "electrolyte.": [ 25 ], "Modifications": [ 26 ], "made": [ 27 ], "commercial": [ 30 ], "titration": [ 31 ], "calorimeter": [ 32, 46 ], "add": [ 34 ], "combination": [ 36 ], "pH": [ 37, 67, 85, 116 ], "electrode": [ 38 ], "maintain": [ 40 ], "an": [ 41 ], "inert": [ 42 ], "atmosphere": [ 43 ], "reaction": [ 47 ], "vessel": [ 48 ], "are": [ 49 ], "described.": [ 50 ], "procedure": [ 52 ], "calibrate": [ 54 ], "measurements": [ 56 ], "heterogeneous": [ 58 ], "systems": [ 59 ], "correct": [ 61 ], "suspension": [ 64, 80 ], "effect": [ 65 ], "on": [ 66 ], "is": [ 68, 86, 101 ], "given.": [ 69 ], "The": [ 70, 95 ], "enthalpy": [ 71, 96 ], "change": [ 72, 97 ], "dissociation": [ 75, 100 ], "from": [ 76, 104, 118 ], "TiO2": [ 77 ], "aqueous": [ 79 ], "as": [ 81 ], "function": [ 83 ], "reported": [ 87 ], "0.01,": [ 89 ], "0.1,": [ 90 ], "0.5": [ 92 ], "M": [ 93 ], "NaCl.": [ 94 ], "endothermic,": [ 102 ], "ranging": [ 103 ], "10.5": [ 105 ], "\u00b1": [ 106, 110 ], "3.8": [ 107, 111 ], "45.0": [ 109 ], "kJ": [ 112 ], "mol\u22121": [ 113 ], "over": [ 114 ], "range": [ 117 ], "4": [ 119 ], "10.": [ 121 ] }, "apc_list": { "value": 3520, "currency": "USD", "value_usd": 3520, "provenance": "doaj" }, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5018553565", "display_name": "Scott R. 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