Item talk:Q102578
From geokb
{
"USGS Publications Warehouse": { "schema": { "@context": "https://schema.org", "@type": "CreativeWork", "additionalType": "USGS Numbered Series", "name": "Automation of an ion chromatograph for precipitation analysis with computerized data reduction", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "wri8178", "url": "https://pubs.usgs.gov/publication/wri8178" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 27624 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.3133/wri8178", "url": "https://doi.org/10.3133/wri8178" } ], "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Water-Resources Investigations Report" } ], "datePublished": "1982", "dateModified": "2017-10-03", "abstract": "Interconnection of an ion chromatograph, an autosampler, and a computing integrator to form an analytical system for simultaneous determination of fluoride, chloride, orthophosphate, bromide, nitrate, and sulfate in precipitation samples is described. Computer programs provided with the integrator are modified to implement ionchromatographic data reduction and data storage. The liquid-flow scheme for the ion chromatograph is changed by addition of a second suppressor column for greater analytical capacity. An additional vave enables selection of either suppressor column for analysis, as the other column is regenerated and stabilized with concentrated eluent.Minimum limits of detection and quantitation for each anion are calculated; these limits are a function of suppressor exhaustion. Precision for replicate analyses of six precipitation samples for fluoride, chloride, orthophosphate, nitrate, and sulfate ranged from 0.003 to 0.027 milligrams per liter. To determine accuracy of results, the same samples were spiked with known concentrations of the above mentioned anions. Average recovery was 108 percent.", "description": "iv, 33 p.", "publisher": { "@type": "Organization", "name": "U.S. Geological Survey" }, "author": [ { "@type": "Person", "name": "Hedley, Arthur G.", "givenName": "Arthur G.", "familyName": "Hedley" }, { "@type": "Person", "name": "Fishman, Marvin J.", "givenName": "Marvin J.", "familyName": "Fishman" } ] } }, "OpenAlex": { "abstract_inverted_index": { "Interconnection": [ 0 ], "of": [ 1, 19, 59, 73, 91, 105, 112, 134, 144 ], "an": [ 2, 5, 13 ], "ion": [ 3, 53 ], "chromatograph,": [ 4 ], "autosampler,": [ 6 ], "and": [ 7, 25, 45, 85, 93, 121 ], "a": [ 8, 60, 103 ], "computing": [ 9 ], "integrator": [ 10, 37 ], "to": [ 11, 40, 126 ], "form": [ 12 ], "analytical": [ 14, 66 ], "system": [ 15 ], "for": [ 16, 51, 64, 77, 95, 109, 116 ], "simultaneous": [ 17 ], "determination": [ 18 ], "fluoride,": [ 20, 117 ], "chloride,": [ 21, 118 ], "orthophosphate,": [ 22, 119 ], "bromide,": [ 23 ], "nitrate,": [ 24, 120 ], "sulfate": [ 26, 122 ], "in": [ 27 ], "precipitation": [ 28, 114 ], "samples": [ 29, 115, 138 ], "is": [ 30, 55, 83 ], "described.": [ 31 ], "Computer": [ 32 ], "programs": [ 33 ], "provided": [ 34 ], "with": [ 35, 87, 141 ], "the": [ 36, 52, 80, 136, 145 ], "are": [ 38, 98, 102 ], "modified": [ 39 ], "implement": [ 41 ], "ionchromatographic": [ 42 ], "data": [ 43, 46 ], "reduction": [ 44 ], "storage.": [ 47 ], "The": [ 48 ], "liquid-flow": [ 49 ], "scheme": [ 50 ], "chromatograph": [ 54 ], "changed": [ 56 ], "by": [ 57 ], "addition": [ 58 ], "second": [ 61 ], "suppressor": [ 62, 75, 106 ], "column": [ 63, 76, 82 ], "greater": [ 65 ], "capacity.": [ 67 ], "An": [ 68 ], "additional": [ 69 ], "vave": [ 70 ], "enables": [ 71 ], "selection": [ 72 ], "either": [ 74 ], "analysis,": [ 78 ], "as": [ 79 ], "other": [ 81 ], "regenerated": [ 84 ], "stabilized": [ 86 ], "concentrated": [ 88 ], "eluent.Minimum": [ 89 ], "limits": [ 90, 101 ], "detection": [ 92 ], "quantitation": [ 94 ], "each": [ 96 ], "anion": [ 97 ], "calculated;": [ 99 ], "these": [ 100 ], "function": [ 104 ], "exhaustion.": [ 107 ], "Precision": [ 108 ], "replicate": [ 110 ], "analyses": [ 111 ], "six": [ 113 ], "ranged": [ 123 ], "from": [ 124 ], "0.003": [ 125 ], "0.027": [ 127 ], "milligrams": [ 128 ], "per": [ 129 ], "liter.": [ 130 ], "To": [ 131 ], "determine": [ 132 ], "accuracy": [ 133 ], "results,": [ 135 ], "same": [ 137 ], "were": [ 139 ], "spiked": [ 140 ], "known": [ 142 ], "concentrations": [ 143 ], "above": [ 146 ], "mentioned": [ 147 ], "anions.": [ 148 ], "Average": [ 149 ], "recovery": [ 150 ], "was": [ 151 ], "108": [ 152 ], "percent.": [ 153 ] }, "apc_list": null, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5087156377", "display_name": "Arthur G. Hedley", "orcid": null }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] }, { "id": "https://openalex.org/I2800772125", "display_name": "Denver Federal Center", "ror": "https://ror.org/05pxjag90", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1280600231", "https://openalex.org/I2800772125" ] }, { "id": "https://openalex.org/I4210147635", "display_name": "Denver School of Nursing", "ror": "https://ror.org/043j8fa20", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I4210147635" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Arthur Hedley", "raw_affiliation_strings": [ "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "Denver, Colorado 1982 UNITED STATES", "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "U.S. Geological Survey, Water Resources Division, 11.", "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, 11.", "institution_ids": [ "https://openalex.org/I1286329397" ] }, { "raw_affiliation_string": "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "institution_ids": [ "https://openalex.org/I2800772125" ] }, { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225", "institution_ids": [] }, { "raw_affiliation_string": "Denver, Colorado 1982 UNITED STATES", "institution_ids": [ "https://openalex.org/I4210147635" ] }, { "raw_affiliation_string": "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "institution_ids": [] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5077116656", "display_name": "Marvin A. Fishman", "orcid": null }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] }, { "id": "https://openalex.org/I2800772125", "display_name": "Denver Federal Center", "ror": "https://ror.org/05pxjag90", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1280600231", "https://openalex.org/I2800772125" ] }, { "id": "https://openalex.org/I4210147635", "display_name": "Denver School of Nursing", "ror": "https://ror.org/043j8fa20", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I4210147635" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Marvin Fishman", "raw_affiliation_strings": [ "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "Denver, Colorado 1982 UNITED STATES", "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "U.S. Geological Survey, Water Resources Division, 11.", "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, 11.", "institution_ids": [ "https://openalex.org/I1286329397" ] }, { "raw_affiliation_string": "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "institution_ids": [ "https://openalex.org/I2800772125" ] }, { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225", "institution_ids": [] }, { "raw_affiliation_string": "Denver, Colorado 1982 UNITED STATES", "institution_ids": [ "https://openalex.org/I4210147635" ] }, { "raw_affiliation_string": "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "institution_ids": [] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5007975648", "display_name": "James Watt", "orcid": null }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] }, { "id": "https://openalex.org/I2800772125", "display_name": "Denver Federal Center", "ror": "https://ror.org/05pxjag90", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1280600231", "https://openalex.org/I2800772125" ] }, { "id": "https://openalex.org/I4210147635", "display_name": "Denver School of Nursing", "ror": "https://ror.org/043j8fa20", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I4210147635" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "James Watt", "raw_affiliation_strings": [ "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "Denver, Colorado 1982 UNITED STATES", "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "U.S. Geological Survey, Water Resources Division, 11.", "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, 11.", "institution_ids": [ "https://openalex.org/I1286329397" ] }, { "raw_affiliation_string": "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "institution_ids": [ "https://openalex.org/I2800772125" ] }, { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225", "institution_ids": [] }, { "raw_affiliation_string": "Denver, Colorado 1982 UNITED STATES", "institution_ids": [ "https://openalex.org/I4210147635" ] }, { "raw_affiliation_string": "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "institution_ids": [] } ] }, { "author_position": "last", "author": { "id": "https://openalex.org/A5028586909", "display_name": "Dallas Peck", "orcid": null }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] }, { "id": "https://openalex.org/I2800772125", "display_name": "Denver Federal Center", "ror": "https://ror.org/05pxjag90", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1280600231", "https://openalex.org/I2800772125" ] }, { "id": "https://openalex.org/I4210147635", "display_name": "Denver School of Nursing", "ror": "https://ror.org/043j8fa20", "country_code": "US", "type": "education", "lineage": [ "https://openalex.org/I4210147635" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Dallas Peck", "raw_affiliation_strings": [ "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "Denver, Colorado 1982 UNITED STATES", "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "U.S. Geological Survey, Water Resources Division, 11.", "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, 11.", "institution_ids": [ "https://openalex.org/I1286329397" ] }, { "raw_affiliation_string": "Box 25046, Denver Federal Center, Mail Stop 407 (c) Lakewood, Colorado 80225", "institution_ids": [ "https://openalex.org/I2800772125" ] }, { "raw_affiliation_string": "Geological Survey Water Resources Division Box 25046, Mail Stop 407 Denver Federal Center Lakewood, Colorado 80225", "institution_ids": [] }, { "raw_affiliation_string": "U.S. Geological Survey, Water Resources Division, Final March_ 1989 Box 25046, Denver Federal Center, Mail Stop 407 14. Lakewood, Colorado 80225", "institution_ids": [] }, { "raw_affiliation_string": "Denver, Colorado 1982 UNITED STATES", "institution_ids": [ "https://openalex.org/I4210147635" ] } ] } ], "best_oa_location": { "is_oa": true, "landing_page_url": "https://doi.org/10.3133/wri8178", "pdf_url": "https://pubs.usgs.gov/wri/1981/0078/report.pdf", "source": null, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true }, "biblio": { "volume": null, "issue": null, "first_page": null, "last_page": null }, "citation_normalized_percentile": { "value": 0.6, "is_in_top_1_percent": false, "is_in_top_10_percent": false }, "cited_by_api_url": "https://api.openalex.org/works?filter=cites:W1504573884", "cited_by_count": 6, "cited_by_percentile_year": { "min": 76, "max": 78 }, "concepts": [ { "id": "https://openalex.org/c2776300020", "wikidata": "https://www.wikidata.org/wiki/Q422423", "display_name": "Bromide", "level": 2, "score": 0.69411236, "qid": null }, { "id": "https://openalex.org/c185592680", "wikidata": "https://www.wikidata.org/wiki/Q2329", "display_name": "Chemistry", "level": 0, "score": 0.6864598, "qid": "Q166089" }, { "id": "https://openalex.org/c2778695967", "wikidata": "https://www.wikidata.org/wiki/Q44791900", "display_name": "Chloride", "level": 2, "score": 0.66837674, "qid": null }, { "id": "https://openalex.org/c43617362", "wikidata": "https://www.wikidata.org/wiki/Q170050", "display_name": "Chromatography", "level": 1, "score": 0.6221601, "qid": "Q158809" }, { "id": "https://openalex.org/c206967267", "wikidata": "https://www.wikidata.org/wiki/Q905749", "display_name": "Ion chromatography", "level": 2, "score": 0.61815304, "qid": null }, { "id": "https://openalex.org/c2780828025", "wikidata": "https://www.wikidata.org/wiki/Q44793182", "display_name": "Fluoride", "level": 2, "score": 0.57822394, "qid": null }, { "id": "https://openalex.org/c2778343803", "wikidata": "https://www.wikidata.org/wiki/Q172290", "display_name": "Sulfate", "level": 2, "score": 0.56037694, "qid": null }, { "id": "https://openalex.org/c2776384668", "wikidata": "https://www.wikidata.org/wiki/Q182168", "display_name": "Nitrate", "level": 2, "score": 0.54499936, "qid": null }, { "id": "https://openalex.org/c107054158", "wikidata": "https://www.wikidata.org/wiki/Q25257", "display_name": "Precipitation", "level": 2, "score": 0.47884345, "qid": null }, { "id": "https://openalex.org/c51724486", "wikidata": "https://www.wikidata.org/wiki/Q908955", "display_name": "Column chromatography", "level": 2, "score": 0.45994064, "qid": null }, { "id": "https://openalex.org/c79518650", "wikidata": "https://www.wikidata.org/wiki/Q2081431", "display_name": "Integrator", "level": 3, "score": 0.42376238, "qid": null }, { "id": "https://openalex.org/c145148216", "wikidata": "https://www.wikidata.org/wiki/Q36496", "display_name": "Ion", "level": 2, "score": 0.4113418, "qid": null }, { "id": "https://openalex.org/c113196181", "wikidata": "https://www.wikidata.org/wiki/Q485223", "display_name": "Analytical Chemistry (journal)", "level": 2, "score": 0.34058714, "qid": null }, { "id": "https://openalex.org/c179104552", "wikidata": "https://www.wikidata.org/wiki/Q11165", "display_name": "Inorganic chemistry", "level": 1, "score": 0.19331968, "qid": "Q166171" }, { "id": "https://openalex.org/c165801399", "wikidata": "https://www.wikidata.org/wiki/Q25428", "display_name": "Voltage", "level": 2, "score": 0.071522295, "qid": null }, { "id": "https://openalex.org/c178790620", "wikidata": "https://www.wikidata.org/wiki/Q11351", "display_name": "Organic chemistry", "level": 1, "score": 0.0663645, "qid": "Q166197" }, { "id": "https://openalex.org/c153294291", "wikidata": "https://www.wikidata.org/wiki/Q25261", "display_name": "Meteorology", "level": 1, "score": 0.0, "qid": "Q159006" }, { "id": "https://openalex.org/c121332964", "wikidata": "https://www.wikidata.org/wiki/Q413", "display_name": "Physics", "level": 0, "score": 0.0, "qid": "Q166093" }, { "id": "https://openalex.org/c62520636", "wikidata": "https://www.wikidata.org/wiki/Q944", "display_name": "Quantum mechanics", "level": 1, "score": 0.0, "qid": "Q226309" } ], "corresponding_author_ids": [], "corresponding_institution_ids": [], "countries_distinct_count": 1, "counts_by_year": [], "created_date": "2016-06-24", "datasets": [], "display_name": "Automation of an ion chromatograph for precipitation analysis with computerized data reduction", "doi": "https://doi.org/10.3133/wri8178", "fwci": null, "grants": [], "has_fulltext": false, "id": "https://openalex.org/W1504573884", "ids": { "openalex": "https://openalex.org/W1504573884", "doi": "https://doi.org/10.3133/wri8178", "mag": "1504573884" }, "indexed_in": [ "crossref" ], "institutions_distinct_count": 3, "is_paratext": false, "is_retracted": false, "keywords": [ { "id": "https://openalex.org/keywords/ion-chromatography", "display_name": "Ion chromatography", "score": 0.61815304 }, { "id": "https://openalex.org/keywords/hydrophilic-interaction-chromatography-(hilic)", "display_name": "Hydrophilic Interaction Chromatography (HILIC)", "score": 0.528627 }, { "id": "https://openalex.org/keywords/liquid-chromatography", "display_name": "Liquid Chromatography", "score": 0.516554 }, { "id": "https://openalex.org/keywords/high-performance-liquid-chromatography-(hplc)", "display_name": "High-Performance Liquid Chromatography (HPLC)", "score": 0.513937 }, { "id": "https://openalex.org/keywords/two-dimensional-chromatography", "display_name": "Two-Dimensional Chromatography", "score": 0.507068 } ], "language": "en", "locations": [ { "is_oa": true, "landing_page_url": "https://doi.org/10.3133/wri8178", "pdf_url": "https://pubs.usgs.gov/wri/1981/0078/report.pdf", "source": null, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true } ], "locations_count": 1, "mesh": [], "ngrams_url": "https://api.openalex.org/works/W1504573884/ngrams", "open_access": { "is_oa": true, "oa_status": "bronze", "oa_url": "https://pubs.usgs.gov/wri/1981/0078/report.pdf", "any_repository_has_fulltext": true }, "primary_location": { "is_oa": true, "landing_page_url": "https://doi.org/10.3133/wri8178", "pdf_url": "https://pubs.usgs.gov/wri/1981/0078/report.pdf", "source": null, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true }, "primary_topic": { "id": "https://openalex.org/T11472", "display_name": "Advances in Chemical Sensor Technologies", "score": 0.9742, "subfield": { "id": "https://openalex.org/subfields/1502", "display_name": "Bioengineering" }, "field": { "id": "https://openalex.org/fields/15", "display_name": "Chemical Engineering" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, "publication_date": "1982-01-01", "publication_year": 1982, "referenced_works": [ "https://openalex.org/W2008459204" ], "referenced_works_count": 1, "related_works": [ "https://openalex.org/W4211258064", "https://openalex.org/W2387813316", "https://openalex.org/W2382880712", "https://openalex.org/W2373573005", "https://openalex.org/W2351268774", "https://openalex.org/W2090394376", "https://openalex.org/W2051877286", "https://openalex.org/W2035479014", "https://openalex.org/W2002129656", "https://openalex.org/W2000732407" ], "sustainable_development_goals": [ { "score": 0.58, "id": "https://metadata.un.org/sdg/6", "display_name": "Clean water and sanitation" } ], "title": "Automation of an ion chromatograph for precipitation analysis with computerized data reduction", "topics": [ { "id": "https://openalex.org/T11472", "display_name": "Advances in Chemical Sensor Technologies", "score": 0.9742, "subfield": { "id": "https://openalex.org/subfields/1502", "display_name": "Bioengineering" }, "field": { "id": "https://openalex.org/fields/15", "display_name": "Chemical Engineering" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T10908", "display_name": "Chiral Separation in Chromatography", "score": 0.9676, "subfield": { "id": "https://openalex.org/subfields/1607", "display_name": "Spectroscopy" }, "field": { "id": "https://openalex.org/fields/16", "display_name": "Chemistry" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T11667", "display_name": "Breath Analysis Technology", "score": 0.9673, "subfield": { "id": "https://openalex.org/subfields/2204", "display_name": "Biomedical Engineering" }, "field": { "id": "https://openalex.org/fields/22", "display_name": "Engineering" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } } ], "type": "report", "type_crossref": "report", "updated_date": "2024-08-10T09:23:50.914354", "versions": [], "qid": "Q102578" }
}