Item talk:Q273808
From geokb
{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Studies in the system MgO-SiO2-CO2-H2O(I): The activity-product constant of chrysotile", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70010458", "url": "https://pubs.usgs.gov/publication/70010458" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70010458 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1016/0016-7037(68)90041-0", "url": "https://doi.org/10.1016/0016-7037(68)90041-0" }, { "@type": "PropertyValue", "propertyID": "ISSN", "value": "00167037" } ], "journal": { "@type": "Periodical", "name": "Geochimica et Cosmochimica Acta", "volumeNumber": "32", "issueNumber": "5" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Geochimica et Cosmochimica Acta" } ], "datePublished": "1968", "dateModified": "2020-11-29", "abstract": "Chrysotile dissolves congruently in water according to the reaction:\u00a0Mg3Si2O6(OH)4c\u00a0+ 5H2Ol\u00a0= 3Mgaq2+\u00a0+ 6OHaq\u2212\u00a0+ 2H4SiO4aq. Experimental determination of the activity-product constant of chrysotile,\u00a0Kchr\u00a0= [Mg2+]3[OH\u2212]6[H4SiO4aq]2, at 90\u00b0C, yields the value of\u00a0Kchr\u00a0= 10\u221249.2\u00a0\u00b1 100.5. A synthetic sample and a natural sample from New Idria, California, were used in the determination.Values of\u00a0Kchr\u00a0were calculated for temperatures ranging from 0\u00b0C to 200\u00b0C, using the thermochemical data of\u00a0Kinget al. (1967) for chrysotile and antigorite, various solubility data for silica, and ionic partial molal heat capacities estimated by the method of criss and Cobble (1964a).\u00a0Kchr\u00a0is 10\u221254.1\u00a0at 0\u00b0C, rises to a maximum value of 10\u221248.5\u00a0at approximately 135\u00b0C, and is 10\u221249.1\u00a0at 200\u00b0C (all values for the three-phase system, chrysotile plus solution plus vapor). The calculated 90\u00b0C value is 10\u221249.1, in excellent agreement with the experimental value; for 25\u00b0C, the calculated value is 10\u221250.8.", "description": "13 p.", "publisher": { "@type": "Organization", "name": "Elsevier" }, "author": [ { "@type": "Person", "name": "Christ, C. L.", "givenName": "C. L.", "familyName": "Christ" }, { "@type": "Person", "name": "Hostetler, P. B.", "givenName": "P. B.", "familyName": "Hostetler", "affiliation": [ { "@type": "Organization", "name": "Department of Geology, University of Missouri" } ] } ] }, "OpenAlex": { "_id": "https://openalex.org/w1988575076", "abstract_inverted_index": { "Chrysotile": [ 0 ], "dissolves": [ 1 ], "congruently": [ 2 ], "in": [ 3, 53, 137 ], "water": [ 4 ], "according": [ 5 ], "to": [ 6, 66, 106 ], "the": [ 7, 21, 32, 54, 69, 93, 123, 141, 146 ], "reaction:": [ 8 ], "Mg3Si2O6(OH)4c": [ 9 ], "+": [ 10, 14, 16 ], "5H2Ol": [ 11 ], "=": [ 12, 27, 36 ], "3Mgaq2+": [ 13 ], "6OHaq\u2212": [ 15 ], "2H4SiO4aq.": [ 17 ], "Experimental": [ 18 ], "determination": [ 19 ], "of": [ 20, 24, 34, 57, 72, 95, 110 ], "activity-product": [ 22 ], "constant": [ 23 ], "chrysotile,": [ 25 ], "Kchr": [ 26, 35, 58, 100 ], "[Mg2+]3[OH\u2212]6[H4SiO4aq]2,": [ 28 ], "at": [ 29, 103, 112, 118 ], "90\u00b0C,": [ 30 ], "yields": [ 31 ], "value": [ 33, 109, 134, 148 ], "10\u221249.2": [ 37 ], "\u00b1": [ 38 ], "100.5.": [ 39 ], "A": [ 40 ], "synthetic": [ 41 ], "sample": [ 42, 46 ], "and": [ 43, 78, 85, 97, 115 ], "a": [ 44, 107 ], "natural": [ 45 ], "from": [ 47, 64 ], "New": [ 48 ], "Idria,": [ 49 ], "California,": [ 50 ], "were": [ 51, 59 ], "used": [ 52 ], "determination.": [ 55 ], "Values": [ 56 ], "calculated": [ 60, 132, 147 ], "for": [ 61, 76, 83, 122, 144 ], "temperatures": [ 62 ], "ranging": [ 63 ], "0\u00b0C": [ 65 ], "200\u00b0C,": [ 67 ], "using": [ 68 ], "thermochemical": [ 70 ], "data": [ 71, 82 ], "Kinget": [ 73 ], "al.": [ 74 ], "(1967)": [ 75 ], "chrysotile": [ 77, 126 ], "antigorite,": [ 79 ], "various": [ 80 ], "solubility": [ 81 ], "silica,": [ 84 ], "ionic": [ 86 ], "partial": [ 87 ], "molal": [ 88 ], "heat": [ 89 ], "capacities": [ 90 ], "estimated": [ 91 ], "by": [ 92 ], "method": [ 94 ], "criss": [ 96 ], "Cobble": [ 98 ], "(1964a).": [ 99 ], "is": [ 101, 116, 135, 149 ], "10\u221254.1": [ 102 ], "0\u00b0C,": [ 104 ], "rises": [ 105 ], "maximum": [ 108 ], "10\u221248.5": [ 111 ], "approximately": [ 113 ], "135\u00b0C,": [ 114 ], "10\u221249.1": [ 117 ], "200\u00b0C": [ 119 ], "(all": [ 120 ], "values": [ 121 ], "three-phase": [ 124 ], "system,": [ 125 ], "plus": [ 127, 129 ], "solution": [ 128 ], "vapor).": [ 130 ], "The": [ 131 ], "90\u00b0C": [ 133 ], "10\u221249.1,": [ 136 ], "excellent": [ 138 ], "agreement": [ 139 ], "with": [ 140 ], "experimental": [ 142 ], "value;": [ 143 ], "25\u00b0C,": [ 145 ], "10\u221250.8.": [ 150 ] }, "apc_list": { "value": 3690, "currency": "USD", "value_usd": 3690, "provenance": "doaj" }, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5033516997", "display_name": "P. B. Hostetler", "orcid": null }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "P.B Hostetler", "raw_affiliation_strings": [ "U.S. Geological Survey, Menlo Park, California 94025 U.S.A." ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Menlo Park, California 94025 U.S.A.", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] }, { "author_position": "last", "author": { "id": "https://openalex.org/A5031553194", "display_name": "C. L. Christ", "orcid": null }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "C.L Christ", "raw_affiliation_strings": [ "U.S. Geological Survey, Menlo Park, California 94025 U.S.A." ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Menlo Park, California 94025 U.S.A.", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] } ], "best_oa_location": null, "biblio": { "volume": "32", "issue": "5", "first_page": "485", "last_page": "497" }, "citation_normalized_percentile": { "value": 0.890816, "is_in_top_1_percent": false, "is_in_top_10_percent": false }, "cited_by_api_url": "https://api.openalex.org/works?filter=cites:W1988575076", "cited_by_count": 69, "cited_by_percentile_year": { "min": 96, "max": 97 }, "concepts": [ { "id": "https://openalex.org/C111963520", "wikidata": "https://www.wikidata.org/wiki/Q118781", "display_name": "Chrysotile", "level": 3, "score": 0.8955387 }, { "id": "https://openalex.org/C185592680", "wikidata": "https://www.wikidata.org/wiki/Q2329", "display_name": "Chemistry", "level": 0, "score": 0.6021605 }, { "id": "https://openalex.org/C16946580", "wikidata": "https://www.wikidata.org/wiki/Q172623", "display_name": "Molality", "level": 3, "score": 0.57166034 }, { "id": "https://openalex.org/C56566620", "wikidata": "https://www.wikidata.org/wiki/Q863829", "display_name": "Solubility equilibrium", "level": 3, "score": 0.48353934 }, { "id": "https://openalex.org/C113196181", "wikidata": "https://www.wikidata.org/wiki/Q485223", "display_name": "Analytical Chemistry (journal)", "level": 2, "score": 0.4757126 }, { "id": "https://openalex.org/C199289684", "wikidata": "https://www.wikidata.org/wiki/Q83353", "display_name": "Mineralogy", "level": 1, "score": 0.43225485 }, { "id": "https://openalex.org/C155574463", "wikidata": "https://www.wikidata.org/wiki/Q170731", "display_name": "Solubility", "level": 2, "score": 0.38562793 }, { "id": "https://openalex.org/C97355855", "wikidata": "https://www.wikidata.org/wiki/Q11473", "display_name": "Thermodynamics", "level": 1, "score": 0.3410092 }, { "id": "https://openalex.org/C192562407", "wikidata": "https://www.wikidata.org/wiki/Q228736", "display_name": "Materials science", "level": 0, "score": 0.18332344 }, { "id": "https://openalex.org/C191897082", "wikidata": "https://www.wikidata.org/wiki/Q11467", "display_name": "Metallurgy", "level": 1, "score": 0.15829921 }, { "id": "https://openalex.org/C43617362", "wikidata": "https://www.wikidata.org/wiki/Q170050", "display_name": "Chromatography", "level": 1, "score": 0.15100676 }, { "id": "https://openalex.org/C184651966", "wikidata": "https://www.wikidata.org/wiki/Q906356", "display_name": "Aqueous solution", "level": 2, "score": 0.13390699 }, { "id": "https://openalex.org/C147789679", "wikidata": "https://www.wikidata.org/wiki/Q11372", "display_name": "Physical chemistry", "level": 1, "score": 0.13380083 }, { "id": "https://openalex.org/C121332964", "wikidata": "https://www.wikidata.org/wiki/Q413", "display_name": "Physics", "level": 0, "score": 0.0 }, { "id": "https://openalex.org/C510490043", "wikidata": "https://www.wikidata.org/wiki/Q104085", "display_name": "Asbestos", "level": 2, "score": 0.0 } ], "corresponding_author_ids": [], "corresponding_institution_ids": [], "countries_distinct_count": 1, "counts_by_year": [ { "year": 2023, "cited_by_count": 2 }, { "year": 2020, "cited_by_count": 1 }, { "year": 2014, "cited_by_count": 2 }, { "year": 2013, "cited_by_count": 1 }, { "year": 2012, "cited_by_count": 1 } ], "created_date": "2016-06-24", "datasets": [], "display_name": "Studies in the system MgO-SiO2-CO2-H2O(I): The activity-product constant of chrysotile", "doi": "https://doi.org/10.1016/0016-7037(68)90041-0", "fulltext_origin": "ngrams", "fwci": 1.689, "grants": [], "has_fulltext": true, "id": "https://openalex.org/W1988575076", "ids": { "openalex": "https://openalex.org/W1988575076", "doi": "https://doi.org/10.1016/0016-7037(68)90041-0", "mag": "1988575076" }, "indexed_in": [ "crossref" ], "institutions_distinct_count": 1, "is_paratext": false, "is_retracted": false, "keywords": [ { "id": "https://openalex.org/keywords/chrysotile", "display_name": "Chrysotile", "score": 0.8955387 }, { "id": "https://openalex.org/keywords/molality", "display_name": "Molality", "score": 0.57166034 }, { "id": "https://openalex.org/keywords/solubility-equilibrium", "display_name": "Solubility equilibrium", "score": 0.48353934 }, { "id": "https://openalex.org/keywords/hydration-mechanisms", "display_name": "Hydration Mechanisms", "score": 0.430783 } ], "language": "en", "locations": [ { "is_oa": false, "landing_page_url": "https://doi.org/10.1016/0016-7037(68)90041-0", "pdf_url": null, "source": { "id": "https://openalex.org/S7538555", "display_name": "Geochimica et Cosmochimica Acta", "issn_l": "0016-7037", "issn": [ "0016-7037", "1872-9533" ], "is_oa": false, "is_in_doaj": false, "is_core": true, "host_organization": "https://openalex.org/P4310320990", "host_organization_name": "Elsevier BV", "host_organization_lineage": [ "https://openalex.org/P4310320990" ], "host_organization_lineage_names": [ "Elsevier BV" ], "type": "journal" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false } ], "locations_count": 1, "mesh": [], "ngrams_url": "https://api.openalex.org/works/W1988575076/ngrams", "open_access": { "is_oa": false, "oa_status": "closed", "oa_url": null, "any_repository_has_fulltext": false }, "primary_location": { "is_oa": false, "landing_page_url": "https://doi.org/10.1016/0016-7037(68)90041-0", "pdf_url": null, "source": { "id": "https://openalex.org/S7538555", "display_name": "Geochimica et Cosmochimica Acta", "issn_l": "0016-7037", "issn": [ "0016-7037", "1872-9533" ], "is_oa": false, "is_in_doaj": false, "is_core": true, "host_organization": "https://openalex.org/P4310320990", "host_organization_name": "Elsevier BV", "host_organization_lineage": [ "https://openalex.org/P4310320990" ], "host_organization_lineage_names": [ "Elsevier BV" ], "type": "journal" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false }, "primary_topic": { "id": "https://openalex.org/T11852", "display_name": "Applications of Clay Nanotubes in Various Fields", "score": 0.998, "subfield": { "id": "https://openalex.org/subfields/2502", "display_name": "Biomaterials" }, "field": { "id": "https://openalex.org/fields/25", "display_name": "Materials Science" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, "publication_date": "1968-05-01", "publication_year": 1968, "referenced_works": [ "https://openalex.org/W1488282249", "https://openalex.org/W1521171930", "https://openalex.org/W1969812288", "https://openalex.org/W2031917118", "https://openalex.org/W2044024128", "https://openalex.org/W2060027402", "https://openalex.org/W2101787749", "https://openalex.org/W2133177055", "https://openalex.org/W2160835451", "https://openalex.org/W2325627351", "https://openalex.org/W2466651870", "https://openalex.org/W249213272", "https://openalex.org/W2736501108", "https://openalex.org/W2736639999", "https://openalex.org/W2913501227", "https://openalex.org/W2922106556", "https://openalex.org/W2945504800", "https://openalex.org/W3121893776", "https://openalex.org/W3152497836", "https://openalex.org/W49710852", "https://openalex.org/W88726933" ], "referenced_works_count": 21, "related_works": [ "https://openalex.org/W4361288141", "https://openalex.org/W4239447182", "https://openalex.org/W2526655853", "https://openalex.org/W2482500574", "https://openalex.org/W2149665507", "https://openalex.org/W2112052324", "https://openalex.org/W2094787759", "https://openalex.org/W2035609666", "https://openalex.org/W2034334873", "https://openalex.org/W1976022586" ], "sustainable_development_goals": [ { "score": 0.76, "display_name": "Clean water and sanitation", "id": "https://metadata.un.org/sdg/6" } ], "title": "Studies in the system MgO-SiO2-CO2-H2O(I): The activity-product constant of chrysotile", "topics": [ { "id": "https://openalex.org/T11852", "display_name": "Applications of Clay Nanotubes in Various Fields", "score": 0.998, "subfield": { "id": "https://openalex.org/subfields/2502", "display_name": "Biomaterials" }, "field": { "id": "https://openalex.org/fields/25", "display_name": "Materials Science" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T12524", "display_name": "Novel Methods for Cesium Removal from Wastewater", "score": 0.9942, "subfield": { "id": "https://openalex.org/subfields/2311", "display_name": "Industrial and Manufacturing Engineering" }, "field": { "id": "https://openalex.org/fields/23", "display_name": "Environmental Science" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T10033", "display_name": "Geopolymer and Alternative Cementitious Materials", "score": 0.9935, "subfield": { "id": "https://openalex.org/subfields/2205", "display_name": "Civil and Structural Engineering" }, "field": { "id": "https://openalex.org/fields/22", "display_name": "Engineering" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } } ], "type": "article", "type_crossref": "journal-article", "updated_date": "2024-08-14T01:54:19.966784", "versions": [] }
}