Item talk:Q267525
From geokb
{
"USGS Publications Warehouse": {
"@context": "https://schema.org",
"@type": "Article",
"additionalType": "Journal Article",
"name": "Phase relations in the system NaCl-KCl-H2O. Part I: Differential thermal analysis of the NaCl-KCl liquidas at 1 atmosphere and 500, 1000, 1500, and 2000 bars",
"identifier": [
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse IndexID",
"value": "70011517",
"url": "https://pubs.usgs.gov/publication/70011517"
},
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse Internal ID",
"value": 70011517
},
{
"@type": "PropertyValue",
"propertyID": "DOI",
"value": "10.1016/0016-7037(82)90133-8",
"url": "https://doi.org/10.1016/0016-7037(82)90133-8"
},
{
"@type": "PropertyValue",
"propertyID": "ISSN",
"value": "00167037"
}
],
"journal": {
"@type": "Periodical",
"name": "Geochimica et Cosmochimica Acta",
"volumeNumber": "46",
"issueNumber": "10"
},
"inLanguage": "en",
"isPartOf": [
{
"@type": "CreativeWorkSeries",
"name": "Geochimica et Cosmochimica Acta"
}
],
"datePublished": "1982",
"dateModified": "2024-03-18",
"abstract": "A simple differential thermal analysis (DTA) technique has been developed to study phase relations of various chemical systems at elevated pressures and temperatures. The DTA system has been calibrated against known melting temperatures in the system NaCl-KCl. Isobaric sections of the liquidus in the system NaCl-KCl have been determined at pressures of 1 atmosphere and 500, 1000, 1500, and 2000 bars. Using the least-squares method, the following equation was used to fit the experimental data: T(\u00b0C)=\u2211i=06aiXiKClwhere\u00a0T\u00a0is the liquidus temperature,\u00a0XKCl\u00a0is mole fraction of KCl, and\u00a0ai\u00a0(listed below) are the derived empirical constants.P (bars)aoa1a2a3a4a5a61 atm.800.1\u2212334.2781.6\u22126490.317553.1\u221217638.46098.3500813.5\u2212354.9743.3\u22126011.716406.4\u221216516.35702.81000824.5\u2212406.71446.8\u22128818.421253.5\u221220343.76839.41500838.6\u2212418.71434.7\u22128819.021557.9\u221220908.47123.12000848.5\u2212381.51246.9\u22128605.021785.8\u221221449.17375.8The liquidus temperatures estimated from these equations are within \u00b13\u00b0C of experimental values. The measured liquidus temperatures at 1 atmosphere agree with the best available data to within 5\u00b0C. The melting temperatures for pure end members at higher pressures agree with the values calculated from the Simon equation (Clark, 1959) to within 3\u00b0C. No previous melting data are available for the intermediate compositions at elevated pressures. Using the data in both heating and cooling scans, the minimum melting temperature at 1 atmosphere in the system was located at 658\u00b0 \u00b1 3\u00b0C\u00a0where the sample has an equimolar composition.",
"description": "6 p.",
"publisher": {
"@type": "Organization",
"name": "Elsevier"
},
"author": [
{
"@type": "Person",
"name": "Chou, I.-Ming",
"givenName": "I.-Ming",
"familyName": "Chou",
"identifier": {
"@type": "PropertyValue",
"propertyID": "ORCID",
"value": "0000-0001-5233-6479",
"url": "https://orcid.org/0000-0001-5233-6479"
},
"affiliation": [
{
"@type": "Organization",
"name": "Eastern Mineral and Environmental Resources Science Center",
"url": "https://www.usgs.gov/centers/geology-energy-and-minerals-science-center"
}
]
}
]
},
"OpenAlex": {
"_id": "https://openalex.org/w2154596208",
"abstract_inverted_index": {
"A": [
0
],
"simple": [
1
],
"differential": [
2
],
"thermal": [
3
],
"analysis": [
4
],
"(DTA)": [
5
],
"technique": [
6
],
"has": [
7,
26,
194
],
"been": [
8,
27,
47
],
"developed": [
9
],
"to": [
10,
70,
126,
150
],
"study": [
11
],
"phase": [
12
],
"relations": [
13
],
"of": [
14,
39,
51,
86,
110
],
"various": [
15
],
"chemical": [
16
],
"systems": [
17
],
"at": [
18,
49,
117,
136,
163,
179,
187
],
"elevated": [
19,
164
],
"pressures": [
20,
50,
138
],
"and": [
21,
54,
58,
88,
172
],
"temperatures.": [
22
],
"The": [
23,
100,
113,
129
],
"DTA": [
24
],
"system": [
25,
35,
44,
184
],
"calibrated": [
28
],
"against": [
29
],
"known": [
30
],
"melting": [
31,
130,
155,
177
],
"temperatures": [
32,
102,
116,
131
],
"in": [
33,
42,
169,
182
],
"the": [
34,
40,
43,
62,
65,
72,
79,
93,
122,
141,
145,
160,
167,
175,
183,
192
],
"NaCl-KCl.": [
36
],
"Isobaric": [
37
],
"sections": [
38
],
"liquidus": [
41,
80,
101,
115
],
"NaCl-KCl": [
45
],
"have": [
46
],
"determined": [
48
],
"1": [
52,
118,
180
],
"atmosphere": [
53,
119,
181
],
"500,": [
55
],
"1000,": [
56
],
"1500,": [
57
],
"2000": [
59
],
"bars.": [
60
],
"Using": [
61,
166
],
"least-squares": [
63
],
"method,": [
64
],
"following": [
66
],
"equation": [
67,
147
],
"was": [
68,
185
],
"used": [
69
],
"fit": [
71
],
"experimental": [
73,
111
],
"data:": [
74
],
"T(\u00b0C)=\u2211i=06aiXiKCl": [
75
],
"where": [
76,
191
],
"T": [
77
],
"is": [
78,
83
],
"temperature,": [
81
],
"XKCl": [
82
],
"mole": [
84
],
"fraction": [
85
],
"KCl,": [
87
],
"ai": [
89
],
"(listed": [
90
],
"below)": [
91
],
"are": [
92,
107,
157
],
"derived": [
94
],
"empirical": [
95
],
"constants.": [
96
],
"P": [
97
],
"(bars)aoa1a2a3a4a5a61": [
98
],
"atm.800.1\u2212334.2781.6\u22126490.317553.1\u221217638.46098.3500813.5\u2212354.9743.3\u22126011.716406.4\u221216516.35702.81000824.5\u2212406.71446.8\u22128818.421253.5\u221220343.76839.41500838.6\u2212418.71434.7\u22128819.021557.9\u221220908.47123.12000848.5\u2212381.51246.9\u22128605.021785.8\u221221449.17375.8": [
99
],
"estimated": [
103
],
"from": [
104,
144
],
"these": [
105
],
"equations": [
106
],
"within": [
108,
127,
151
],
"\u00b13\u00b0C": [
109
],
"values.": [
112
],
"measured": [
114
],
"agree": [
120,
139
],
"with": [
121,
140
],
"best": [
123
],
"available": [
124,
158
],
"data": [
125,
156,
168
],
"5\u00b0C.": [
128
],
"for": [
132,
159
],
"pure": [
133
],
"end": [
134
],
"members": [
135
],
"higher": [
137
],
"values": [
142
],
"calculated": [
143
],
"Simon": [
146
],
"(Clark,": [
148
],
"1959)": [
149
],
"3\u00b0C.": [
152
],
"No": [
153
],
"previous": [
154
],
"intermediate": [
161
],
"compositions": [
162
],
"pressures.": [
165
],
"both": [
170
],
"heating": [
171
],
"cooling": [
173
],
"scans,": [
174
],
"minimum": [
176
],
"temperature": [
178
],
"located": [
186
],
"658\u00b0": [
188
],
"\u00b1": [
189
],
"3\u00b0C": [
190
],
"sample": [
193
],
"an": [
195
],
"equimolar": [
196
],
"composition.": [
197
]
},
"apc_list": {
"value": 3690,
"currency": "USD",
"value_usd": 3690,
"provenance": "doaj"
},
"apc_paid": null,
"authorships": [
{
"author_position": "first",
"author": {
"id": "https://openalex.org/A5074729117",
"display_name": "I\u2010Ming Chou",
"orcid": "https://orcid.org/0000-0001-5233-6479"
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": true,
"raw_author_name": "I-Ming Chou",
"raw_affiliation_strings": [
"U. S. Geological Survey, 959 National Center, Reston, VA 22092, U.S.A."
],
"affiliations": [
{
"raw_affiliation_string": "U. S. Geological Survey, 959 National Center, Reston, VA 22092, U.S.A.",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
}
],
"best_oa_location": null,
"biblio": {
"volume": "46",
"issue": "10",
"first_page": "1957",
"last_page": "1962"
},
"citation_normalized_percentile": {
"value": 0.856077,
"is_in_top_1_percent": false,
"is_in_top_10_percent": false
},
"cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2154596208",
"cited_by_count": 21,
"cited_by_percentile_year": {
"min": 88,
"max": 89
},
"concepts": [
{
"id": "https://openalex.org/C145653223",
"wikidata": "https://www.wikidata.org/wiki/Q899386",
"display_name": "Liquidus",
"level": 3,
"score": 0.9842684
},
{
"id": "https://openalex.org/C146211579",
"wikidata": "https://www.wikidata.org/wiki/Q137649",
"display_name": "Isobaric process",
"level": 2,
"score": 0.7013389
},
{
"id": "https://openalex.org/C65440619",
"wikidata": "https://www.wikidata.org/wiki/Q177974",
"display_name": "Atmosphere (unit)",
"level": 2,
"score": 0.6458453
},
{
"id": "https://openalex.org/C97355855",
"wikidata": "https://www.wikidata.org/wiki/Q11473",
"display_name": "Thermodynamics",
"level": 1,
"score": 0.626409
},
{
"id": "https://openalex.org/C76804077",
"wikidata": "https://www.wikidata.org/wiki/Q905301",
"display_name": "Differential thermal analysis",
"level": 3,
"score": 0.59889925
},
{
"id": "https://openalex.org/C185592680",
"wikidata": "https://www.wikidata.org/wiki/Q2329",
"display_name": "Chemistry",
"level": 0,
"score": 0.5356787
},
{
"id": "https://openalex.org/C113196181",
"wikidata": "https://www.wikidata.org/wiki/Q485223",
"display_name": "Analytical Chemistry (journal)",
"level": 2,
"score": 0.5260135
},
{
"id": "https://openalex.org/C44280652",
"wikidata": "https://www.wikidata.org/wiki/Q104837",
"display_name": "Phase (matter)",
"level": 2,
"score": 0.496224
},
{
"id": "https://openalex.org/C37641323",
"wikidata": "https://www.wikidata.org/wiki/Q4230455",
"display_name": "Congruent melting",
"level": 4,
"score": 0.44023848
},
{
"id": "https://openalex.org/C90086362",
"wikidata": "https://www.wikidata.org/wiki/Q1084485",
"display_name": "Cooling curve",
"level": 2,
"score": 0.4269461
},
{
"id": "https://openalex.org/C85906118",
"wikidata": "https://www.wikidata.org/wiki/Q186693",
"display_name": "Phase diagram",
"level": 3,
"score": 0.398414
},
{
"id": "https://openalex.org/C121332964",
"wikidata": "https://www.wikidata.org/wiki/Q413",
"display_name": "Physics",
"level": 0,
"score": 0.06884587
},
{
"id": "https://openalex.org/C178790620",
"wikidata": "https://www.wikidata.org/wiki/Q11351",
"display_name": "Organic chemistry",
"level": 1,
"score": 0.0
},
{
"id": "https://openalex.org/C43617362",
"wikidata": "https://www.wikidata.org/wiki/Q170050",
"display_name": "Chromatography",
"level": 1,
"score": 0.0
},
{
"id": "https://openalex.org/C207114421",
"wikidata": "https://www.wikidata.org/wiki/Q133900",
"display_name": "Diffraction",
"level": 2,
"score": 0.0
},
{
"id": "https://openalex.org/C120665830",
"wikidata": "https://www.wikidata.org/wiki/Q14620",
"display_name": "Optics",
"level": 1,
"score": 0.0
}
],
"corresponding_author_ids": [
"https://openalex.org/A5074729117"
],
"corresponding_institution_ids": [
"https://openalex.org/I1286329397"
],
"countries_distinct_count": 1,
"counts_by_year": [
{
"year": 2022,
"cited_by_count": 2
},
{
"year": 2016,
"cited_by_count": 1
},
{
"year": 2012,
"cited_by_count": 1
}
],
"created_date": "2016-06-24",
"datasets": [],
"display_name": "Phase relations in the system NaCl-KCl-H2O. Part I: Differential thermal analysis of the NaCl-KCl liquidas at 1 atmosphere and 500, 1000, 1500, and 2000 bars",
"doi": "https://doi.org/10.1016/0016-7037(82)90133-8",
"fulltext_origin": "ngrams",
"fwci": 1.494,
"grants": [],
"has_fulltext": true,
"id": "https://openalex.org/W2154596208",
"ids": {
"openalex": "https://openalex.org/W2154596208",
"doi": "https://doi.org/10.1016/0016-7037(82)90133-8",
"mag": "2154596208"
},
"indexed_in": [
"crossref"
],
"institutions_distinct_count": 1,
"is_paratext": false,
"is_retracted": false,
"keywords": [
{
"id": "https://openalex.org/keywords/liquidus",
"display_name": "Liquidus",
"score": 0.9842684
},
{
"id": "https://openalex.org/keywords/isobaric-process",
"display_name": "Isobaric process",
"score": 0.7013389
},
{
"id": "https://openalex.org/keywords/differential-thermal-analysis",
"display_name": "Differential thermal analysis",
"score": 0.59889925
},
{
"id": "https://openalex.org/keywords/thermoanalytical-data",
"display_name": "Thermoanalytical Data",
"score": 0.548488
},
{
"id": "https://openalex.org/keywords/aqueous-two-phase-systems",
"display_name": "Aqueous Two-Phase Systems",
"score": 0.522952
},
{
"id": "https://openalex.org/keywords/high-temperature-solar-chemistry",
"display_name": "High-Temperature Solar Chemistry",
"score": 0.520894
},
{
"id": "https://openalex.org/keywords/congruent-melting",
"display_name": "Congruent melting",
"score": 0.44023848
},
{
"id": "https://openalex.org/keywords/cooling-curve",
"display_name": "Cooling curve",
"score": 0.4269461
}
],
"language": "en",
"locations": [
{
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/0016-7037(82)90133-8",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
}
],
"locations_count": 1,
"mesh": [],
"ngrams_url": "https://api.openalex.org/works/W2154596208/ngrams",
"open_access": {
"is_oa": false,
"oa_status": "closed",
"oa_url": null,
"any_repository_has_fulltext": false
},
"primary_location": {
"is_oa": false,
"landing_page_url": "https://doi.org/10.1016/0016-7037(82)90133-8",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S7538555",
"display_name": "Geochimica et Cosmochimica Acta",
"issn_l": "0016-7037",
"issn": [
"0016-7037",
"1872-9533"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320990",
"host_organization_name": "Elsevier BV",
"host_organization_lineage": [
"https://openalex.org/P4310320990"
],
"host_organization_lineage_names": [
"Elsevier BV"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
},
"primary_topic": {
"id": "https://openalex.org/T12358",
"display_name": "Kinetic Analysis of Thermal Processes in Materials",
"score": 0.9994,
"subfield": {
"id": "https://openalex.org/subfields/2505",
"display_name": "Materials Chemistry"
},
"field": {
"id": "https://openalex.org/fields/25",
"display_name": "Materials Science"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
"publication_date": "1982-10-01",
"publication_year": 1982,
"referenced_works": [
"https://openalex.org/W1512105224",
"https://openalex.org/W1974386414",
"https://openalex.org/W1981363657",
"https://openalex.org/W1989834014",
"https://openalex.org/W1992079615",
"https://openalex.org/W1993654914",
"https://openalex.org/W1998453624",
"https://openalex.org/W2027547745",
"https://openalex.org/W2068331306",
"https://openalex.org/W2073747346",
"https://openalex.org/W2081647456",
"https://openalex.org/W2101034903",
"https://openalex.org/W2128062455",
"https://openalex.org/W2131133936",
"https://openalex.org/W2144236132",
"https://openalex.org/W2156632395",
"https://openalex.org/W2317323342",
"https://openalex.org/W2325351172",
"https://openalex.org/W2483033476",
"https://openalex.org/W435494043",
"https://openalex.org/W567277538"
],
"referenced_works_count": 21,
"related_works": [
"https://openalex.org/W3215993000",
"https://openalex.org/W2905069680",
"https://openalex.org/W2806343894",
"https://openalex.org/W2138298076",
"https://openalex.org/W2055777860",
"https://openalex.org/W1994804620",
"https://openalex.org/W1890300672",
"https://openalex.org/W1600774571",
"https://openalex.org/W1449839846",
"https://openalex.org/W1235564400"
],
"sustainable_development_goals": [],
"title": "Phase relations in the system NaCl-KCl-H2O. Part I: Differential thermal analysis of the NaCl-KCl liquidas at 1 atmosphere and 500, 1000, 1500, and 2000 bars",
"topics": [
{
"id": "https://openalex.org/T12358",
"display_name": "Kinetic Analysis of Thermal Processes in Materials",
"score": 0.9994,
"subfield": {
"id": "https://openalex.org/subfields/2505",
"display_name": "Materials Chemistry"
},
"field": {
"id": "https://openalex.org/fields/25",
"display_name": "Materials Science"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T11936",
"display_name": "Aqueous Two-Phase Systems in Separation Science",
"score": 0.9867,
"subfield": {
"id": "https://openalex.org/subfields/1506",
"display_name": "Filtration and Separation"
},
"field": {
"id": "https://openalex.org/fields/15",
"display_name": "Chemical Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T11802",
"display_name": "Chemical-Looping Technologies",
"score": 0.98,
"subfield": {
"id": "https://openalex.org/subfields/2204",
"display_name": "Biomedical Engineering"
},
"field": {
"id": "https://openalex.org/fields/22",
"display_name": "Engineering"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
}
],
"type": "article",
"type_crossref": "journal-article",
"updated_date": "2024-08-08T18:58:51.269593",
"versions": []
}
}
