Item talk:Q237169
From geokb
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"name": "Iron oxide minerals in dust of the Red Dawn event in eastern Australia, September 2009",
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"abstract": "Iron oxide minerals typically compose only a few weight percent of bulk atmospheric dust but are important for potential roles in forcing climate, affecting cloud properties, influencing rates of snow and ice melt, and fertilizing marine phytoplankton. Dust samples collected from locations across eastern Australia (Lake Cowal, Orange, Hornsby, and Sydney) following the spectacular \u201cRed Dawn\u201d dust storm on 23 September 2009 enabled study of the dust iron oxide assemblage using a combination of magnetic measurements, M\u00f6ssbauer spectroscopy, reflectance spectroscopy, and scanning electron microscopy. Red Dawn was the worst dust storm to have hit the city of Sydney in more than 60\u00a0years, and it also deposited dust into the Tasman Sea and onto snow cover in New Zealand. Magnetization measurements from 20 to 400\u00a0K reveal that hematite, goethite, and trace amounts of magnetite are present in all samples. Magnetite concentrations (as much as 0.29\u00a0wt%) were much higher in eastern, urban sites than in western, agricultural sites in central New South Wales (0.01\u00a0wt%), strongly suggesting addition of magnetite from local urban sources. Variable temperature M\u00f6ssbauer spectroscopy (300 and 4.2\u00a0K) indicates that goethite and hematite compose approximately 25\u201345% of the Fe-bearing phases in samples from the inland sites of Orange and Lake Cowal. Hematite was observed at both temperatures but goethite only at 4.2\u00a0K, thereby revealing the presence of nanogoethite (less than about 20\u00a0nm). Similarly, hematite particulate matter is very small (some of it d\u00a0<\u00a0100\u00a0nm) on the basis of magnetic results and M\u00f6ssbauer spectra. The degree to which ferric oxide in these samples might absorb solar radiation is estimated by comparing reflectance values with a magnetic parameter (hard isothermal remanent magnetization, HIRM) for ferric oxide abundance. Average visible reflectance and HIRM are correlated as a group (r2\u00a0=\u00a00.24), indicating that Red Dawn ferric oxides have capacity to absorb solar radiation. Much of this ferric oxide occurs as nanohematite and nanogoethite particles on surfaces of other particulate matter, thereby providing high surface area to enhance absorption of solar radiation. Leaching of the sample from Orange in simulated human-lung fluid revealed low bioaccessibility for most metals.",
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