Item talk:Q233678
From geokb
{
"USGS Publications Warehouse": {
"@context": "https://schema.org",
"@type": "Article",
"additionalType": "Journal Article",
"name": "Aqueous chlorination of resorcinol",
"identifier": [
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse IndexID",
"value": "70015085",
"url": "https://pubs.usgs.gov/publication/70015085"
},
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse Internal ID",
"value": 70015085
},
{
"@type": "PropertyValue",
"propertyID": "DOI",
"value": "10.1002/etc.5620081208",
"url": "https://doi.org/10.1002/etc.5620081208"
},
{
"@type": "PropertyValue",
"propertyID": "ISSN",
"value": "07307268"
}
],
"journal": {
"@type": "Periodical",
"name": "Environmental Toxicology and Chemistry",
"volumeNumber": "8",
"issueNumber": "12"
},
"inLanguage": "en",
"isPartOf": [
{
"@type": "CreativeWorkSeries",
"name": "Environmental Toxicology and Chemistry"
}
],
"datePublished": "1989",
"dateModified": "2024-02-13",
"abstract": "An investigation of the aqueous chlorination (NaOCl) of resorcinol is reported. The following intermediates were detected in moderate to high yield at different pH values and varying percentages of chlorination: 2-chloro-, 4-chloro-, 2,4-dichloro-, 4,6-dichloro- and 2,4,6-trichlororesorcinol. Only trace amounts of the intermediates were detected when the chlorination was conducted in the presence of phosphate buffer. This result has significant implications since resorcinol in phosphate buffer has been used as a model compound in several recent studies on the formation of chlorinated hydrocarbons during chlorination of drinking water. Relative rates of chlorination were determined for resorcinol and several of the chlorinated resorcinols. Resorcinol was found to chlorinate only three times faster than 2,4,6-trichlororesorcinol. The structure 2,4,6-trichlororesorcinol was established as a monohydrate even after sublimation. A tetrachloro or pentachloro intermediate was not detected, suggesting that the ring-opening step of such an intermediate must be rapid.",
"description": "5 p.",
"publisher": {
"@type": "Organization",
"name": "Society of Environmental Toxicology and Chemistry"
},
"author": [
{
"@type": "Person",
"name": "Heasley, V.L.",
"givenName": "V.L.",
"familyName": "Heasley"
},
{
"@type": "Person",
"name": "Schroeter, H.",
"givenName": "H.",
"familyName": "Schroeter"
},
{
"@type": "Person",
"name": "Kemalyan, N.A.",
"givenName": "N.A.",
"familyName": "Kemalyan"
},
{
"@type": "Person",
"name": "Mckee, T.C.",
"givenName": "T.C.",
"familyName": "Mckee"
},
{
"@type": "Person",
"name": "Wershaw, R. L.",
"givenName": "R. L.",
"familyName": "Wershaw"
},
{
"@type": "Person",
"name": "Whitney, S.E.",
"givenName": "S.E.",
"familyName": "Whitney"
},
{
"@type": "Person",
"name": "Burns, M.D.",
"givenName": "M.D.",
"familyName": "Burns"
},
{
"@type": "Person",
"name": "Teegarden, B.R.",
"givenName": "B.R.",
"familyName": "Teegarden"
}
]
},
"OpenAlex": {
"abstract_inverted_index": {
"Abstract": [
0
],
"An": [
1
],
"investigation": [
2
],
"of": [
3,
8,
29,
40,
53,
80,
85,
90,
98,
137
],
"the": [
4,
41,
46,
51,
78,
99,
134
],
"aqueous": [
5
],
"chlorination": [
6,
47,
84,
91
],
"(NaOCl)": [
7
],
"resorcinol": [
9,
62,
95
],
"is": [
10
],
"reported.": [
11
],
"The": [
12,
113
],
"following": [
13
],
"intermediates": [
14,
42
],
"were": [
15,
43,
92
],
"detected": [
16,
44
],
"in": [
17,
50,
63,
73
],
"moderate": [
18
],
"to": [
19,
105
],
"high": [
20
],
"yield": [
21
],
"at": [
22
],
"different": [
23
],
"pH": [
24
],
"values": [
25
],
"and": [
26,
35,
96
],
"varying": [
27
],
"percentages": [
28
],
"chlorination:": [
30
],
"2\u2010chloro\u2010,": [
31
],
"4\u2010chloro\u2010,": [
32
],
"2,4\u2010dichloro\u2010,": [
33
],
"4,6\u2010dichloro\u2010": [
34
],
"2,4,6\u2010trichlororesorcinol.": [
36,
112
],
"Only": [
37
],
"trace": [
38
],
"amounts": [
39
],
"when": [
45
],
"was": [
48,
103,
116,
129
],
"conducted": [
49
],
"presence": [
52
],
"phosphate": [
54,
64
],
"buffer.": [
55
],
"This": [
56
],
"result": [
57
],
"has": [
58,
66
],
"significant": [
59
],
"implications": [
60
],
"since": [
61
],
"buffer": [
65
],
"been": [
67
],
"used": [
68
],
"as": [
69,
118
],
"a": [
70,
119
],
"model": [
71
],
"compound": [
72
],
"several": [
74,
97
],
"recent": [
75
],
"studies": [
76
],
"on": [
77
],
"formation": [
79
],
"chlorinated": [
81,
100
],
"hydrocarbons": [
82
],
"during": [
83
],
"drinking": [
86
],
"water.": [
87
],
"Relative": [
88
],
"rates": [
89
],
"determined": [
93
],
"for": [
94
],
"resorcinols.": [
101
],
"Resorcinol": [
102
],
"found": [
104
],
"chlorinate": [
106
],
"only": [
107
],
"three": [
108
],
"times": [
109
],
"faster": [
110
],
"than": [
111
],
"structure": [
114
],
"2,4,6\u2010trichlororesorcinol": [
115
],
"established": [
117
],
"monohydrate": [
120
],
"even": [
121
],
"after": [
122
],
"sublimation.": [
123
],
"A": [
124
],
"tetrachloro": [
125
],
"or": [
126
],
"pentachloro": [
127
],
"intermediate": [
128,
140
],
"not": [
130
],
"detected,": [
131
],
"suggesting": [
132
],
"that": [
133
],
"ring\u2010opening": [
135
],
"step": [
136
],
"such": [
138
],
"an": [
139
],
"must": [
141
],
"be": [
142
],
"rapid.": [
143
]
},
"apc_list": {
"value": 3400,
"currency": "USD",
"value_usd": 3400,
"provenance": "doaj"
},
"apc_paid": null,
"authorships": [
{
"author_position": "first",
"author": {
"id": "https://openalex.org/A5039746631",
"display_name": "Victor L. Heasley",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I98607628",
"display_name": "Point Loma Nazarene University",
"ror": "https://ror.org/02rsjqy82",
"country_code": "US",
"type": "education",
"lineage": [
"https://openalex.org/I98607628"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Victor L. Heasley",
"raw_affiliation_strings": [
"Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106"
],
"affiliations": [
{
"raw_affiliation_string": "Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106",
"institution_ids": [
"https://openalex.org/I98607628"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5004151237",
"display_name": "Michael D. Burns",
"orcid": "https://orcid.org/0000-0002-1381-587X"
},
"institutions": [
{
"id": "https://openalex.org/I98607628",
"display_name": "Point Loma Nazarene University",
"ror": "https://ror.org/02rsjqy82",
"country_code": "US",
"type": "education",
"lineage": [
"https://openalex.org/I98607628"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Michael D. Burns",
"raw_affiliation_strings": [
"Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106"
],
"affiliations": [
{
"raw_affiliation_string": "Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106",
"institution_ids": [
"https://openalex.org/I98607628"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5081528676",
"display_name": "Nathan A. Kemalyan",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I98607628",
"display_name": "Point Loma Nazarene University",
"ror": "https://ror.org/02rsjqy82",
"country_code": "US",
"type": "education",
"lineage": [
"https://openalex.org/I98607628"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Nathan A. Kemalyan",
"raw_affiliation_strings": [
"Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106"
],
"affiliations": [
{
"raw_affiliation_string": "Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106",
"institution_ids": [
"https://openalex.org/I98607628"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5029867843",
"display_name": "Tawnya C. McKee",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I98607628",
"display_name": "Point Loma Nazarene University",
"ror": "https://ror.org/02rsjqy82",
"country_code": "US",
"type": "education",
"lineage": [
"https://openalex.org/I98607628"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Tawnya C. McKee",
"raw_affiliation_strings": [
"Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106"
],
"affiliations": [
{
"raw_affiliation_string": "Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106",
"institution_ids": [
"https://openalex.org/I98607628"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5080492811",
"display_name": "Hinako Schroeter",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I98607628",
"display_name": "Point Loma Nazarene University",
"ror": "https://ror.org/02rsjqy82",
"country_code": "US",
"type": "education",
"lineage": [
"https://openalex.org/I98607628"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Hinako Schroeter",
"raw_affiliation_strings": [
"Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106"
],
"affiliations": [
{
"raw_affiliation_string": "Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106",
"institution_ids": [
"https://openalex.org/I98607628"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5081489999",
"display_name": "Brad R. Teegarden",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I98607628",
"display_name": "Point Loma Nazarene University",
"ror": "https://ror.org/02rsjqy82",
"country_code": "US",
"type": "education",
"lineage": [
"https://openalex.org/I98607628"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Brad R. Teegarden",
"raw_affiliation_strings": [
"Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106"
],
"affiliations": [
{
"raw_affiliation_string": "Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106",
"institution_ids": [
"https://openalex.org/I98607628"
]
}
]
},
{
"author_position": "middle",
"author": {
"id": "https://openalex.org/A5077124321",
"display_name": "Scott Whitney",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I98607628",
"display_name": "Point Loma Nazarene University",
"ror": "https://ror.org/02rsjqy82",
"country_code": "US",
"type": "education",
"lineage": [
"https://openalex.org/I98607628"
]
}
],
"countries": [
"US"
],
"is_corresponding": false,
"raw_author_name": "Scott E. Whitney",
"raw_affiliation_strings": [
"Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106"
],
"affiliations": [
{
"raw_affiliation_string": "Department of Chemistry, Point Loma Nazarene College, San Diego, California 92106",
"institution_ids": [
"https://openalex.org/I98607628"
]
}
]
},
{
"author_position": "last",
"author": {
"id": "https://openalex.org/A5022792336",
"display_name": "Robert L. Wershaw",
"orcid": null
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": true,
"raw_author_name": "Robert L. Wershaw",
"raw_affiliation_strings": [
"U.S. Geological Survey, Arvada, Colorado 80002"
],
"affiliations": [
{
"raw_affiliation_string": "U.S. Geological Survey, Arvada, Colorado 80002",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
}
],
"best_oa_location": null,
"biblio": {
"volume": "8",
"issue": "12",
"first_page": "1159",
"last_page": "1163"
},
"citation_normalized_percentile": {
"value": 0.758309,
"is_in_top_1_percent": false,
"is_in_top_10_percent": false
},
"cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2120401804",
"cited_by_count": 23,
"cited_by_percentile_year": {
"min": 87,
"max": 88
},
"concepts": [
{
"id": "https://openalex.org/C2780016452",
"wikidata": "https://www.wikidata.org/wiki/Q408865",
"display_name": "Resorcinol",
"level": 2,
"score": 0.99316037
},
{
"id": "https://openalex.org/C185592680",
"wikidata": "https://www.wikidata.org/wiki/Q2329",
"display_name": "Chemistry",
"level": 0,
"score": 0.84127426
},
{
"id": "https://openalex.org/C184651966",
"wikidata": "https://www.wikidata.org/wiki/Q906356",
"display_name": "Aqueous solution",
"level": 2,
"score": 0.7130565
},
{
"id": "https://openalex.org/C58437636",
"wikidata": "https://www.wikidata.org/wiki/Q217249",
"display_name": "Sublimation (psychology)",
"level": 2,
"score": 0.5727545
},
{
"id": "https://openalex.org/C2777132085",
"wikidata": "https://www.wikidata.org/wiki/Q46220103",
"display_name": "Phosphate",
"level": 2,
"score": 0.48900688
},
{
"id": "https://openalex.org/C96616956",
"wikidata": "https://www.wikidata.org/wiki/Q285100",
"display_name": "Phosphate buffered saline",
"level": 2,
"score": 0.45954722
},
{
"id": "https://openalex.org/C179104552",
"wikidata": "https://www.wikidata.org/wiki/Q11165",
"display_name": "Inorganic chemistry",
"level": 1,
"score": 0.3714
},
{
"id": "https://openalex.org/C13965031",
"wikidata": "https://www.wikidata.org/wiki/Q243545",
"display_name": "Nuclear chemistry",
"level": 1,
"score": 0.34197664
},
{
"id": "https://openalex.org/C178790620",
"wikidata": "https://www.wikidata.org/wiki/Q11351",
"display_name": "Organic chemistry",
"level": 1,
"score": 0.33873412
},
{
"id": "https://openalex.org/C43617362",
"wikidata": "https://www.wikidata.org/wiki/Q170050",
"display_name": "Chromatography",
"level": 1,
"score": 0.19986147
},
{
"id": "https://openalex.org/C15744967",
"wikidata": "https://www.wikidata.org/wiki/Q9418",
"display_name": "Psychology",
"level": 0,
"score": 0.0
},
{
"id": "https://openalex.org/C542102704",
"wikidata": "https://www.wikidata.org/wiki/Q183257",
"display_name": "Psychotherapist",
"level": 1,
"score": 0.0
}
],
"corresponding_author_ids": [
"https://openalex.org/A5022792336"
],
"corresponding_institution_ids": [
"https://openalex.org/I1286329397"
],
"countries_distinct_count": 1,
"counts_by_year": [
{
"year": 2023,
"cited_by_count": 2
},
{
"year": 2020,
"cited_by_count": 2
},
{
"year": 2019,
"cited_by_count": 1
},
{
"year": 2015,
"cited_by_count": 2
},
{
"year": 2014,
"cited_by_count": 1
},
{
"year": 2013,
"cited_by_count": 1
},
{
"year": 2012,
"cited_by_count": 1
}
],
"created_date": "2016-06-24",
"datasets": [],
"display_name": "Aqueous chlorination of resorcinol",
"doi": "https://doi.org/10.1002/etc.5620081208",
"fulltext_origin": "ngrams",
"fwci": 0.0,
"grants": [],
"has_fulltext": true,
"id": "https://openalex.org/W2120401804",
"ids": {
"openalex": "https://openalex.org/W2120401804",
"doi": "https://doi.org/10.1002/etc.5620081208",
"mag": "2120401804"
},
"indexed_in": [
"crossref"
],
"institutions_distinct_count": 2,
"is_paratext": false,
"is_retracted": false,
"keywords": [
{
"id": "https://openalex.org/keywords/resorcinol",
"display_name": "Resorcinol",
"score": 0.99316037
},
{
"id": "https://openalex.org/keywords/sublimation",
"display_name": "Sublimation (psychology)",
"score": 0.5727545
},
{
"id": "https://openalex.org/keywords/chlorination",
"display_name": "Chlorination",
"score": 0.54097
},
{
"id": "https://openalex.org/keywords/phosphate-buffered-saline",
"display_name": "Phosphate buffered saline",
"score": 0.45954722
}
],
"language": "en",
"locations": [
{
"is_oa": false,
"landing_page_url": "https://doi.org/10.1002/etc.5620081208",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S136710263",
"display_name": "Environmental Toxicology and Chemistry",
"issn_l": "0730-7268",
"issn": [
"0730-7268",
"1552-8618"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320595",
"host_organization_name": "Wiley",
"host_organization_lineage": [
"https://openalex.org/P4310320595"
],
"host_organization_lineage_names": [
"Wiley"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
}
],
"locations_count": 1,
"mesh": [],
"ngrams_url": "https://api.openalex.org/works/W2120401804/ngrams",
"open_access": {
"is_oa": false,
"oa_status": "closed",
"oa_url": null,
"any_repository_has_fulltext": false
},
"primary_location": {
"is_oa": false,
"landing_page_url": "https://doi.org/10.1002/etc.5620081208",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S136710263",
"display_name": "Environmental Toxicology and Chemistry",
"issn_l": "0730-7268",
"issn": [
"0730-7268",
"1552-8618"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310320595",
"host_organization_name": "Wiley",
"host_organization_lineage": [
"https://openalex.org/P4310320595"
],
"host_organization_lineage_names": [
"Wiley"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
},
"primary_topic": {
"id": "https://openalex.org/T11493",
"display_name": "Occurrence and Health Effects of Drinking Water Disinfection By-Products",
"score": 0.9925,
"subfield": {
"id": "https://openalex.org/subfields/2307",
"display_name": "Health, Toxicology and Mutagenesis"
},
"field": {
"id": "https://openalex.org/fields/23",
"display_name": "Environmental Science"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
"publication_date": "1989-12-01",
"publication_year": 1989,
"referenced_works": [
"https://openalex.org/W2005835112",
"https://openalex.org/W2034788507",
"https://openalex.org/W2065534085",
"https://openalex.org/W2068014920",
"https://openalex.org/W2284542694",
"https://openalex.org/W2314380469"
],
"referenced_works_count": 6,
"related_works": [
"https://openalex.org/W636275296",
"https://openalex.org/W3921243",
"https://openalex.org/W3136634579",
"https://openalex.org/W2763257503",
"https://openalex.org/W2390293339",
"https://openalex.org/W2375790370",
"https://openalex.org/W2369534154",
"https://openalex.org/W2365747617",
"https://openalex.org/W2060754049",
"https://openalex.org/W2058844695"
],
"sustainable_development_goals": [
{
"display_name": "Clean water and sanitation",
"id": "https://metadata.un.org/sdg/6",
"score": 0.86
}
],
"title": "Aqueous chlorination of resorcinol",
"topics": [
{
"id": "https://openalex.org/T11493",
"display_name": "Occurrence and Health Effects of Drinking Water Disinfection By-Products",
"score": 0.9925,
"subfield": {
"id": "https://openalex.org/subfields/2307",
"display_name": "Health, Toxicology and Mutagenesis"
},
"field": {
"id": "https://openalex.org/fields/23",
"display_name": "Environmental Science"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T10180",
"display_name": "Analytical Chemistry Techniques",
"score": 0.9713,
"subfield": {
"id": "https://openalex.org/subfields/1602",
"display_name": "Analytical Chemistry"
},
"field": {
"id": "https://openalex.org/fields/16",
"display_name": "Chemistry"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T13092",
"display_name": "Fate and Effects of Surfactants in the Environment",
"score": 0.9651,
"subfield": {
"id": "https://openalex.org/subfields/2304",
"display_name": "Environmental Chemistry"
},
"field": {
"id": "https://openalex.org/fields/23",
"display_name": "Environmental Science"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
}
],
"type": "article",
"type_crossref": "journal-article",
"updated_date": "2024-08-13T21:40:56.761083",
"versions": []
}
}
