Item talk:Q237226
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{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "H-binding of size- and polarity-fractionated soil and lignite humic acids after removal of metal and ash components", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70189960", "url": "https://pubs.usgs.gov/publication/70189960" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70189960 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1007/s11356-013-2302-9", "url": "https://doi.org/10.1007/s11356-013-2302-9" } ], "journal": { "@type": "Periodical", "name": "Environmental Science and Pollution Research", "volumeNumber": "21", "issueNumber": "5" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Environmental Science and Pollution Research" } ], "datePublished": "2014", "dateModified": "2017-07-31", "abstract": "A fractionation technique, combining dialysis removal of metal and ash components with hydrofluoric acid and pH 10 citrate buffer followed by chromatography of dialysis permeate on XAD-8 resin at decreasing pH values, has been applied to lignite humic acid (lignite-HA) and soil humic acid (soil-HA). H-binding data and non ideal competitive adsorption-Donnan model parameters were obtained for the HA fractions by theoretical analysis of H-binding data which reveal a significant increase of the carboxyl and the phenolic charge for the lignite-HA fractions vs. the parental lignite humic acid (LParentalHA). The fractionated lignite-HA material consisted mainly of permeate fractions, some of which were fulvic acid-like. The fractionated soil-HA material consisted mainly of large macromolecular structures that did not permeate the dialysis membrane during deashing. Chargeable groups had comparable concentrations in soil-HA fractions and parental soil humic acid (SParentalHA), indicating minimal interference of ash components with carboxyl and phenolic (and/or enolic) groups. Fractionation of HA, combined with theoretical analysis of H-binding, can distinguish the supramolecular vs. macromolecular nature of fractions within the same parental HA.", "description": "9 p.", "publisher": { "@type": "Organization", "name": "Springer" }, "author": [ { "@type": "Person", "name": "Avgeropoulos, Apostolos", "givenName": "Apostolos", "familyName": "Avgeropoulos" }, { "@type": "Person", "name": "Leenheer, Jerry A.", "givenName": "Jerry A.", "familyName": "Leenheer" }, { "@type": "Person", "name": "Drosos, Marios", "givenName": "Marios", "familyName": "Drosos" }, { "@type": "Person", "name": "Deligiannakis, Yiannis", "givenName": "Yiannis", "familyName": "Deligiannakis" } ], "funder": [ { "@type": "Organization", "name": "National Research Program - Central Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" } ] }, "OpenAlex": { "abstract_inverted_index": null, "apc_list": { "value": 2890, "currency": "EUR", "value_usd": 3690, "provenance": "doaj" }, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5090384824", "display_name": "\u039c\u03ac\u03c1\u03b9\u03bf\u03c2 \u0394\u03c1\u03cc\u03c3\u03bf\u03c2", "orcid": "https://orcid.org/0000-0003-0403-7014" }, "institutions": [ { "id": "https://openalex.org/I174878644", "display_name": "University of Patras", "ror": "https://ror.org/017wvtq80", "country_code": "GR", "type": "education", "lineage": [ "https://openalex.org/I174878644" ] } ], "countries": [ "GR" ], "is_corresponding": false, "raw_author_name": "Marios Drosos", "raw_affiliation_strings": [ "University of Patras;" ], "affiliations": [ { "raw_affiliation_string": "University of Patras;", "institution_ids": [ "https://openalex.org/I174878644" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5090880179", "display_name": "Jerry A. 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