{
"USGS Publications Warehouse": {
"@context": "https://schema.org",
"@type": "Article",
"additionalType": "Journal Article",
"name": "The viability of a nonenzymatic reductive citric acid cycle - Kinetics and thermochemistry",
"identifier": [
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse IndexID",
"value": "70032990",
"url": "https://pubs.usgs.gov/publication/70032990"
},
{
"@type": "PropertyValue",
"propertyID": "USGS Publications Warehouse Internal ID",
"value": 70032990
},
{
"@type": "PropertyValue",
"propertyID": "DOI",
"value": "10.1007/s11084-006-9017-6",
"url": "https://doi.org/10.1007/s11084-006-9017-6"
},
{
"@type": "PropertyValue",
"propertyID": "ISSN",
"value": "01696149"
}
],
"journal": {
"@type": "Periodical",
"name": "Origins of Life and Evolution of the Biosphere",
"volumeNumber": "37",
"issueNumber": "1"
},
"inLanguage": "en",
"isPartOf": [
{
"@type": "CreativeWorkSeries",
"name": "Origins of Life and Evolution of the Biosphere"
}
],
"datePublished": "2007",
"dateModified": "2023-10-06",
"abstract": "The likelihood of a functioning nonenzymatic reductive citric acid cycle, recently proposed as the precursor to biosynthesis on early Earth, is examined on the basis of the kinetics and thermochemistry of the acetate \u2192 pyruvate \u2192 oxaloacetate \u2192 malate sequence. Using data derived from studies of the Pd-catalyzed phosphinate reduction of carbonyl functions it is shown that the rate of conversion of pyruvate to malate with that system would have been much too slow to have played a role in the early chemistry of life, while naturally occurring reduction systems such as the fayalite\u2013magnetite\u2013quartz and pyrrhotite\u2013pyrite\u2013magnetite mineral assemblages would have provided even slower conversions. It is also shown that the production of pyruvate from acetate is too highly endoergic to be driven by a naturally occurring energy source such as pyrophosphate. It is thus highly doubtful that the cycle can operate at suitable rates without enzymes, and most unlikely that it could have participated in the chemistry leading to life.",
"description": "5 p.",
"publisher": {
"@type": "Organization",
"name": "Springer"
},
"author": [
{
"@type": "Person",
"name": "Ross, D.S.",
"givenName": "D.S.",
"familyName": "Ross"
}
]
},
"OpenAlex": {
"abstract_inverted_index": null,
"apc_list": {
"value": 2590,
"currency": "EUR",
"value_usd": 3290,
"provenance": "doaj"
},
"apc_paid": null,
"authorships": [
{
"author_position": "first",
"author": {
"id": "https://openalex.org/A5102962153",
"display_name": "David S. Ross",
"orcid": "https://orcid.org/0000-0002-4090-7139"
},
"institutions": [
{
"id": "https://openalex.org/I1286329397",
"display_name": "United States Geological Survey",
"ror": "https://ror.org/035a68863",
"country_code": "US",
"type": "government",
"lineage": [
"https://openalex.org/I1286329397",
"https://openalex.org/I1335927249"
]
}
],
"countries": [
"US"
],
"is_corresponding": true,
"raw_author_name": "David S Ross",
"raw_affiliation_strings": [
"U.S. Geological Survey, Menlo Park, CA 94025, USA. dsross3@yahoo.com"
],
"affiliations": [
{
"raw_affiliation_string": "U.S. Geological Survey, Menlo Park, CA 94025, USA. dsross3@yahoo.com",
"institution_ids": [
"https://openalex.org/I1286329397"
]
}
]
}
],
"best_oa_location": null,
"biblio": {
"volume": "37",
"issue": "1",
"first_page": "61",
"last_page": "65"
},
"citation_normalized_percentile": {
"value": 0.806199,
"is_in_top_1_percent": false,
"is_in_top_10_percent": false
},
"cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2068690806",
"cited_by_count": 19,
"cited_by_percentile_year": {
"min": 87,
"max": 88
},
"concepts": [
{
"id": "https://openalex.org/C29563950",
"wikidata": "https://www.wikidata.org/wiki/Q183410",
"display_name": "Thermochemistry",
"level": 2,
"score": 0.8119383
},
{
"id": "https://openalex.org/C185592680",
"wikidata": "https://www.wikidata.org/wiki/Q2329",
"display_name": "Chemistry",
"level": 0,
"score": 0.7821554
},
{
"id": "https://openalex.org/C179104552",
"wikidata": "https://www.wikidata.org/wiki/Q11165",
"display_name": "Inorganic chemistry",
"level": 1,
"score": 0.50896454
},
{
"id": "https://openalex.org/C165135838",
"wikidata": "https://www.wikidata.org/wiki/Q133895",
"display_name": "Citric acid cycle",
"level": 3,
"score": 0.46696547
},
{
"id": "https://openalex.org/C2776062231",
"wikidata": "https://www.wikidata.org/wiki/Q50769",
"display_name": "Pyrite",
"level": 2,
"score": 0.44959912
},
{
"id": "https://openalex.org/C148898269",
"wikidata": "https://www.wikidata.org/wiki/Q1108792",
"display_name": "Kinetics",
"level": 2,
"score": 0.44050077
},
{
"id": "https://openalex.org/C2776043855",
"wikidata": "https://www.wikidata.org/wiki/Q55506489",
"display_name": "Pyrophosphate",
"level": 3,
"score": 0.43374464
},
{
"id": "https://openalex.org/C2779032678",
"wikidata": "https://www.wikidata.org/wiki/Q159683",
"display_name": "Citric acid",
"level": 2,
"score": 0.42149764
},
{
"id": "https://openalex.org/C2777781897",
"wikidata": "https://www.wikidata.org/wiki/Q181395",
"display_name": "Magnetite",
"level": 2,
"score": 0.41255188
},
{
"id": "https://openalex.org/C178790620",
"wikidata": "https://www.wikidata.org/wiki/Q11351",
"display_name": "Organic chemistry",
"level": 1,
"score": 0.23092437
},
{
"id": "https://openalex.org/C199289684",
"wikidata": "https://www.wikidata.org/wiki/Q83353",
"display_name": "Mineralogy",
"level": 1,
"score": 0.19984105
},
{
"id": "https://openalex.org/C181199279",
"wikidata": "https://www.wikidata.org/wiki/Q8047",
"display_name": "Enzyme",
"level": 2,
"score": 0.12200484
},
{
"id": "https://openalex.org/C127313418",
"wikidata": "https://www.wikidata.org/wiki/Q1069",
"display_name": "Geology",
"level": 0,
"score": 0.07126814
},
{
"id": "https://openalex.org/C121332964",
"wikidata": "https://www.wikidata.org/wiki/Q413",
"display_name": "Physics",
"level": 0,
"score": 0.0
},
{
"id": "https://openalex.org/C62520636",
"wikidata": "https://www.wikidata.org/wiki/Q944",
"display_name": "Quantum mechanics",
"level": 1,
"score": 0.0
},
{
"id": "https://openalex.org/C151730666",
"wikidata": "https://www.wikidata.org/wiki/Q7205",
"display_name": "Paleontology",
"level": 1,
"score": 0.0
}
],
"corresponding_author_ids": [
"https://openalex.org/A5102962153"
],
"corresponding_institution_ids": [
"https://openalex.org/I1286329397"
],
"countries_distinct_count": 1,
"counts_by_year": [
{
"year": 2022,
"cited_by_count": 1
},
{
"year": 2021,
"cited_by_count": 1
},
{
"year": 2020,
"cited_by_count": 4
},
{
"year": 2018,
"cited_by_count": 1
},
{
"year": 2017,
"cited_by_count": 1
},
{
"year": 2015,
"cited_by_count": 2
},
{
"year": 2012,
"cited_by_count": 1
}
],
"created_date": "2016-06-24",
"datasets": [],
"display_name": "The Viability of a Nonenzymatic Reductive Citric Acid Cycle \u2013 Kinetics and Thermochemistry",
"doi": "https://doi.org/10.1007/s11084-006-9017-6",
"fulltext_origin": "ngrams",
"fwci": 0.9,
"grants": [],
"has_fulltext": true,
"id": "https://openalex.org/W2068690806",
"ids": {
"openalex": "https://openalex.org/W2068690806",
"doi": "https://doi.org/10.1007/s11084-006-9017-6",
"mag": "2068690806",
"pmid": "https://pubmed.ncbi.nlm.nih.gov/17136437"
},
"indexed_in": [
"crossref",
"pubmed"
],
"institutions_distinct_count": 1,
"is_paratext": false,
"is_retracted": false,
"keywords": [
{
"id": "https://openalex.org/keywords/thermochemistry",
"display_name": "Thermochemistry",
"score": 0.8119383
},
{
"id": "https://openalex.org/keywords/photosynthetic-acclimation",
"display_name": "Photosynthetic Acclimation",
"score": 0.475093
}
],
"language": "en",
"locations": [
{
"is_oa": false,
"landing_page_url": "https://doi.org/10.1007/s11084-006-9017-6",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S126192178",
"display_name": "Origins of Life and Evolution of Biospheres",
"issn_l": "0169-6149",
"issn": [
"0169-6149",
"1573-0875"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310319900",
"host_organization_name": "Springer Science+Business Media",
"host_organization_lineage": [
"https://openalex.org/P4310319965",
"https://openalex.org/P4310319900"
],
"host_organization_lineage_names": [
"Springer Nature",
"Springer Science+Business Media"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
},
{
"is_oa": false,
"landing_page_url": "https://pubmed.ncbi.nlm.nih.gov/17136437",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S4306525036",
"display_name": "PubMed",
"issn_l": null,
"issn": null,
"is_oa": false,
"is_in_doaj": false,
"is_core": false,
"host_organization": "https://openalex.org/I1299303238",
"host_organization_name": "National Institutes of Health",
"host_organization_lineage": [
"https://openalex.org/I1299303238"
],
"host_organization_lineage_names": [
"National Institutes of Health"
],
"type": "repository"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
}
],
"locations_count": 2,
"mesh": [
{
"descriptor_ui": "D002952",
"descriptor_name": "Citric Acid Cycle",
"qualifier_ui": "",
"qualifier_name": null,
"is_major_topic": false
},
{
"descriptor_ui": "D007700",
"descriptor_name": "Kinetics",
"qualifier_ui": "",
"qualifier_name": null,
"is_major_topic": false
},
{
"descriptor_ui": "D010084",
"descriptor_name": "Oxidation-Reduction",
"qualifier_ui": "",
"qualifier_name": null,
"is_major_topic": false
}
],
"ngrams_url": "https://api.openalex.org/works/W2068690806/ngrams",
"open_access": {
"is_oa": false,
"oa_status": "closed",
"oa_url": null,
"any_repository_has_fulltext": false
},
"primary_location": {
"is_oa": false,
"landing_page_url": "https://doi.org/10.1007/s11084-006-9017-6",
"pdf_url": null,
"source": {
"id": "https://openalex.org/S126192178",
"display_name": "Origins of Life and Evolution of Biospheres",
"issn_l": "0169-6149",
"issn": [
"0169-6149",
"1573-0875"
],
"is_oa": false,
"is_in_doaj": false,
"is_core": true,
"host_organization": "https://openalex.org/P4310319900",
"host_organization_name": "Springer Science+Business Media",
"host_organization_lineage": [
"https://openalex.org/P4310319965",
"https://openalex.org/P4310319900"
],
"host_organization_lineage_names": [
"Springer Nature",
"Springer Science+Business Media"
],
"type": "journal"
},
"license": null,
"license_id": null,
"version": null,
"is_accepted": false,
"is_published": false
},
"primary_topic": {
"id": "https://openalex.org/T11445",
"display_name": "Origin of Life and Prebiotic Chemistry",
"score": 0.9996,
"subfield": {
"id": "https://openalex.org/subfields/3103",
"display_name": "Astronomy and Astrophysics"
},
"field": {
"id": "https://openalex.org/fields/31",
"display_name": "Physics and Astronomy"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
"publication_date": "2006-11-29",
"publication_year": 2006,
"referenced_works": [
"https://openalex.org/W1044340",
"https://openalex.org/W1967700370",
"https://openalex.org/W1987569423",
"https://openalex.org/W1991196512",
"https://openalex.org/W1991992370",
"https://openalex.org/W2016327292",
"https://openalex.org/W2029931639",
"https://openalex.org/W2035295072",
"https://openalex.org/W2047398157",
"https://openalex.org/W2073535751",
"https://openalex.org/W2080748525",
"https://openalex.org/W2092725966",
"https://openalex.org/W2111473359",
"https://openalex.org/W2314117155",
"https://openalex.org/W3147240467",
"https://openalex.org/W43643348",
"https://openalex.org/W617681017"
],
"referenced_works_count": 17,
"related_works": [
"https://openalex.org/W4298292914",
"https://openalex.org/W4245623259",
"https://openalex.org/W4244514184",
"https://openalex.org/W4206057215",
"https://openalex.org/W409089612",
"https://openalex.org/W3092398131",
"https://openalex.org/W2067924393",
"https://openalex.org/W2009541437",
"https://openalex.org/W1574085992",
"https://openalex.org/W1572943104"
],
"sustainable_development_goals": [],
"title": "The Viability of a Nonenzymatic Reductive Citric Acid Cycle \u2013 Kinetics and Thermochemistry",
"topics": [
{
"id": "https://openalex.org/T11445",
"display_name": "Origin of Life and Prebiotic Chemistry",
"score": 0.9996,
"subfield": {
"id": "https://openalex.org/subfields/3103",
"display_name": "Astronomy and Astrophysics"
},
"field": {
"id": "https://openalex.org/fields/31",
"display_name": "Physics and Astronomy"
},
"domain": {
"id": "https://openalex.org/domains/3",
"display_name": "Physical Sciences"
}
},
{
"id": "https://openalex.org/T10303",
"display_name": "Molecular Mechanisms of Photosynthesis and Photoprotection",
"score": 0.9794,
"subfield": {
"id": "https://openalex.org/subfields/1312",
"display_name": "Molecular Biology"
},
"field": {
"id": "https://openalex.org/fields/13",
"display_name": "Biochemistry, Genetics and Molecular Biology"
},
"domain": {
"id": "https://openalex.org/domains/1",
"display_name": "Life Sciences"
}
},
{
"id": "https://openalex.org/T10044",
"display_name": "Protein Structure Prediction and Analysis",
"score": 0.952,
"subfield": {
"id": "https://openalex.org/subfields/1312",
"display_name": "Molecular Biology"
},
"field": {
"id": "https://openalex.org/fields/13",
"display_name": "Biochemistry, Genetics and Molecular Biology"
},
"domain": {
"id": "https://openalex.org/domains/1",
"display_name": "Life Sciences"
}
}
],
"type": "article",
"type_crossref": "journal-article",
"updated_date": "2024-08-13T13:13:53.621086",
"versions": []
}
}