{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Copper speciation in variably toxic sediments at the Ely Copper Mine, Vermont, United States", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70168662", "url": "https://pubs.usgs.gov/publication/70168662" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70168662 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1021/acs.est.5b04081", "url": "https://doi.org/10.1021/acs.est.5b04081" } ], "journal": { "@type": "Periodical", "name": "Environmental Science & Technology", "volumeNumber": "50", "issueNumber": "3" }, "bookEdition": "1126", "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Environmental Science & Technology" } ], "datePublished": "2016", "dateModified": "2018-10-29", "abstract": "At the Ely Copper Mine Superfund site, Cu concentrations exceed background values in both streamwater (160\u20131200 times) and sediments (15\u201379 times). Previously, these sediment samples were incubated with laboratory test organisms, and they exhibited variable toxicity for different stream sites. In this study we combined bulk- and microscale techniques to determine Cu speciation and distribution in these contaminated sediments on the basis of evidence from previous work that Cu was the most important stressor in this environment and that variable observed toxicity could have resulted from differences in Cu speciation. Copper speciation results were similar at microscopic and bulk scales. The major Cu species in the more toxic samples were sorbed or coprecipitated with secondary Mn (birnessite) and Fe minerals (jarosite and goethite), which together accounted for nearly 80% of the total Cu. The major Cu species in the less toxic samples were Cu sulfides (chalcopyrite and a covellite-like phase), making up about 80\u201395% of the total Cu, with minor amounts of Cu associated with jarosite or goethite. These Cu speciation results are consistent with the toxicity results, considering that Cu sorbed or coprecipitated with secondary phases at near-neutral pH is relatively less stable than Cu bound to sulfide at lower pH. The more toxic stream sediment sites were those that contained fewer detrital sulfides and were upstream of the major mine waste pile, suggesting that removal and consolidation of sulfide-bearing waste piles on site may not eliminate all sources of bioaccessible Cu.", "description": "11 p.", "publisher": { "@type": "Organization", "name": "American Chemical Society" }, "author": [ { "@type": "Person", "name": "Foster, Andrea L. afoster@usgs.gov", "givenName": "Andrea L.", "familyName": "Foster", "email": "afoster@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-1362-0068", "url": "https://orcid.org/0000-0003-1362-0068" }, "affiliation": [ { "@type": "Organization", "name": "Geology, Minerals, Energy, and Geophysics Science Center", "url": "https://www.usgs.gov/centers/gmeg" }, { "@type": "Organization", "name": "Western Mineral and Environmental Resources Science Center", "url": "https://www.usgs.gov/centers/gmeg" } ] }, { "@type": "Person", "name": "Kimball, Bryn E. bekimball@usgs.gov", "givenName": "Bryn E.", "familyName": "Kimball", "email": "bekimball@usgs.gov" }, { "@type": "Person", "name": "Seal, Robert R. II rseal@usgs.gov", "givenName": "Robert R. ", "familyName": "Seal", "email": "rseal@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-0901-2529", "url": "https://orcid.org/0000-0003-0901-2529" }, "affiliation": [ { "@type": "Organization", "name": "Eastern Mineral and Environmental Resources Science Center", "url": "https://www.usgs.gov/centers/geology-energy-and-minerals-science-center" } ] }, { "@type": "Person", "name": "Piatak, Nadine M. npiatak@usgs.gov", "givenName": "Nadine M.", "familyName": "Piatak", "email": "npiatak@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-1973-8537", "url": "https://orcid.org/0000-0002-1973-8537" }, "affiliation": [ { "@type": "Organization", "name": "Eastern Mineral and Environmental Resources Science Center", "url": "https://www.usgs.gov/centers/geology-energy-and-minerals-science-center" } ] }, { "@type": "Person", "name": "Webb, Samuel M.", "givenName": "Samuel M.", "familyName": "Webb" }, { "@type": "Person", "name": "Hammarstrom, Jane M. jhammars@usgs.gov", "givenName": "Jane M.", "familyName": "Hammarstrom", "email": "jhammars@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-2742-3460", "url": "https://orcid.org/0000-0003-2742-3460" }, "affiliation": [ { "@type": "Organization", "name": "Mineral Resources Program", "url": "https://www.usgs.gov/programs/mineral-resources-program" }, { "@type": "Organization", "name": "Eastern Mineral and Environmental Resources Science Center", "url": "https://www.usgs.gov/centers/geology-energy-and-minerals-science-center" } ] } ], "funder": [ { "@type": "Organization", "name": "Eastern Mineral and Environmental Resources Science Center", "url": "https://www.usgs.gov/centers/geology-energy-and-minerals-science-center" }, { "@type": "Organization", "name": "Geology, Minerals, Energy, and Geophysics Science Center", "url": "https://www.usgs.gov/centers/gmeg" } ], "archivedAt": "http://dx.doi.org/10.1021/acs.est.5b04081", "spatialCoverage": [ { "@type": "Place", "additionalType": "country", "name": "United States", "url": "https://geonames.org/4074035" }, { "@type": "Place", "additionalType": "state", "name": "Vermont" }, { "@type": "Place", "additionalType": "unknown", "name": "Ely Copper Mine" }, { "@type": "Place", "geo": [ { "@type": "GeoShape", "additionalProperty": { "@type": "PropertyValue", "name": "GeoJSON", "value": { "type": "FeatureCollection", "features": [ { "type": "Feature", "properties": {}, "geometry": { "type": "Polygon", "coordinates": [ [ [ -72.3, 44 ], [ -72.3, 43.9 ], [ -72.1, 43.9 ], [ -72.1, 44 ], [ -72.3, 44 ] ] ] } } ] } } }, { "@type": "GeoCoordinates", "latitude": 43.949999999999996, "longitude": -72.2 } ] } ] }, "OpenAlex": { "abstract_inverted_index": { "At": [ 0 ], "the": [ 1, 60, 70, 105, 130, 138, 155, 175, 219 ], "Ely": [ 2 ], "Copper": [ 3, 90 ], "Mine": [ 4 ], "Superfund": [ 5 ], "site,": [ 6 ], "Cu": [ 7, 51, 68, 88, 102, 135, 143, 162, 169, 180, 195 ], "concentrations": [ 8 ], "exceed": [ 9 ], "background": [ 10 ], "values": [ 11 ], "in": [ 12, 55, 74, 87, 104, 137 ], "both": [ 13 ], "streamwater": [ 14 ], "(160-1200": [ 15 ], "times)": [ 16 ], "and": [ 17, 31, 46, 53, 77, 97, 117, 121, 146, 215, 227 ], "sediments": [ 18, 58 ], "(15-79": [ 19 ], "times).": [ 20 ], "Previously,": [ 21 ], "these": [ 22, 56 ], "sediment": [ 23, 206 ], "samples": [ 24, 108, 141 ], "were": [ 25, 93, 109, 142, 208, 216 ], "incubated": [ 26 ], "with": [ 27, 113, 158, 164, 174, 184 ], "laboratory": [ 28 ], "test": [ 29 ], "organisms,": [ 30 ], "they": [ 32 ], "exhibited": [ 33 ], "variable": [ 34, 79 ], "toxicity": [ 35, 81, 176 ], "for": [ 36, 126 ], "different": [ 37 ], "stream": [ 38, 205 ], "sites.": [ 39 ], "In": [ 40 ], "this": [ 41, 75 ], "study": [ 42 ], "we": [ 43 ], "combined": [ 44 ], "bulk-": [ 45 ], "microscale": [ 47 ], "techniques": [ 48 ], "to": [ 49, 197 ], "determine": [ 50 ], "speciation": [ 52, 91, 170 ], "distribution": [ 54 ], "contaminated": [ 57 ], "on": [ 59, 233 ], "basis": [ 61 ], "of": [ 62, 129, 154, 161, 218, 229, 240 ], "evidence": [ 63 ], "from": [ 64, 85 ], "previous": [ 65 ], "work": [ 66 ], "that": [ 67, 78, 179, 210, 225 ], "was": [ 69 ], "most": [ 71 ], "important": [ 72 ], "stressor": [ 73 ], "environment": [ 76 ], "observed": [ 80 ], "could": [ 82 ], "have": [ 83 ], "resulted": [ 84 ], "differences": [ 86 ], "speciation.": [ 89 ], "results": [ 92, 171 ], "similar": [ 94 ], "at": [ 95, 187, 199 ], "microscopic": [ 96 ], "bulk": [ 98 ], "scales.": [ 99 ], "The": [ 100, 133, 202 ], "major": [ 101, 134, 220 ], "species": [ 103, 136 ], "more": [ 106, 203 ], "toxic": [ 107, 140, 204 ], "sorbed": [ 110, 181 ], "or": [ 111, 166, 182 ], "coprecipitated": [ 112, 183 ], "secondary": [ 114, 185 ], "Mn": [ 115 ], "(birnessite)": [ 116 ], "Fe": [ 118 ], "minerals": [ 119 ], "(jarosite": [ 120 ], "goethite),": [ 122 ], "which": [ 123 ], "together": [ 124 ], "accounted": [ 125 ], "nearly": [ 127 ], "80%": [ 128 ], "total": [ 131, 156 ], "Cu.": [ 132, 242 ], "less": [ 139, 192 ], "sulfides": [ 144, 214 ], "(chalcopyrite": [ 145 ], "a": [ 147 ], "covellite-like": [ 148 ], "phase),": [ 149 ], "making": [ 150 ], "up": [ 151 ], "about": [ 152 ], "80-95%": [ 153 ], "Cu,": [ 157 ], "minor": [ 159 ], "amounts": [ 160 ], "associated": [ 163 ], "jarosite": [ 165 ], "goethite.": [ 167 ], "These": [ 168 ], "are": [ 172 ], "consistent": [ 173 ], "results,": [ 177 ], "considering": [ 178 ], "phases": [ 186 ], "near-neutral": [ 188 ], "pH": [ 189 ], "is": [ 190 ], "relatively": [ 191 ], "stable": [ 193 ], "than": [ 194 ], "bound": [ 196 ], "sulfide": [ 198 ], "lower": [ 200 ], "pH.": [ 201 ], "sites": [ 207 ], "those": [ 209 ], "contained": [ 211 ], "fewer": [ 212 ], "detrital": [ 213 ], "upstream": [ 217 ], "mine": [ 221 ], "waste": [ 222, 231 ], "pile,": [ 223 ], "suggesting": [ 224 ], "removal": [ 226 ], "consolidation": [ 228 ], "sulfide-bearing": [ 230 ], "piles": [ 232 ], "site": [ 234 ], "may": [ 235 ], "not": [ 236 ], "eliminate": [ 237 ], "all": [ 238 ], "sources": [ 239 ], "bioaccessible": [ 241 ] }, "apc_list": null, "apc_paid": null, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5008171687", "display_name": "Briant A. Kimball", "orcid": null }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Bryn E. Kimball", "raw_affiliation_strings": [ "U.S. Geological Survey, Reston, Virginia, 20192 United States" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Reston, Virginia, 20192 United States", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5027406123", "display_name": "Andrea L. Foster", "orcid": "https://orcid.org/0000-0003-1362-0068" }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Andrea L. Foster", "raw_affiliation_strings": [ "U.S. Geological Survey, Menlo Park, California, 94025 United States" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Menlo Park, California, 94025 United States", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5086220081", "display_name": "Robert R. Seal", "orcid": "https://orcid.org/0000-0003-0901-2529" }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Robert R. Seal", "raw_affiliation_strings": [ "U.S. Geological Survey, Reston, Virginia, 20192 United States" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Reston, Virginia, 20192 United States", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5064229887", "display_name": "Nadine M. Piatak", "orcid": "https://orcid.org/0000-0002-1973-8537" }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Nadine M. Piatak", "raw_affiliation_strings": [ "U.S. Geological Survey, Reston, Virginia, 20192 United States" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Reston, Virginia, 20192 United States", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5060067287", "display_name": "Samuel M. Webb", "orcid": "https://orcid.org/0000-0003-1188-0464" }, "institutions": [ { "id": "https://openalex.org/I4210120900", "display_name": "Stanford Synchrotron Radiation Lightsource", "ror": "https://ror.org/02vzbm991", "country_code": "US", "type": "facility", "lineage": [ "https://openalex.org/I1330989302", "https://openalex.org/I2801935854", "https://openalex.org/I39565521", "https://openalex.org/I4210120900", "https://openalex.org/I97018004" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Samuel M. Webb", "raw_affiliation_strings": [ "Stanford Synchrotron Radiation Lightsource, Menlo Park, California, 94025 United States" ], "affiliations": [ { "raw_affiliation_string": "Stanford Synchrotron Radiation Lightsource, Menlo Park, California, 94025 United States", "institution_ids": [ "https://openalex.org/I4210120900" ] } ] }, { "author_position": "last", "author": { "id": "https://openalex.org/A5011144281", "display_name": "Jane M. Hammarstrom", "orcid": "https://orcid.org/0000-0003-2742-3460" }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Jane M. Hammarstrom", "raw_affiliation_strings": [ "U.S. Geological Survey, Reston, Virginia, 20192 United States" ], "affiliations": [ { "raw_affiliation_string": "U.S. Geological Survey, Reston, Virginia, 20192 United States", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] } ], "best_oa_location": null, "biblio": { "volume": "50", "issue": "3", "first_page": "1126", "last_page": "1136" }, "citation_normalized_percentile": { "value": 0.683869, "is_in_top_1_percent": false, "is_in_top_10_percent": false }, "cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2256241948", "cited_by_count": 8, "cited_by_percentile_year": { "min": 85, "max": 86 }, "concepts": [ { "id": "https://openalex.org/C2777787761", "wikidata": "https://www.wikidata.org/wiki/Q189703", "display_name": "Goethite", "level": 3, "score": 0.80254817 }, { "id": "https://openalex.org/C107872376", "wikidata": "https://www.wikidata.org/wiki/Q321355", "display_name": "Environmental chemistry", "level": 1, "score": 0.79706025 }, { "id": "https://openalex.org/C2775929177", "wikidata": "https://www.wikidata.org/wiki/Q411168", "display_name": "Jarosite", "level": 2, "score": 0.7791087 }, { "id": "https://openalex.org/C2776838516", "wikidata": "https://www.wikidata.org/wiki/Q187787", "display_name": "Genetic algorithm", "level": 2, "score": 0.68096334 }, { "id": "https://openalex.org/C544778455", "wikidata": "https://www.wikidata.org/wiki/Q753", "display_name": "Copper", "level": 2, "score": 0.62185264 }, { "id": "https://openalex.org/C185592680", "wikidata": "https://www.wikidata.org/wiki/Q2329", "display_name": "Chemistry", "level": 0, "score": 0.59679186 }, { "id": "https://openalex.org/C2780596425", "wikidata": "https://www.wikidata.org/wiki/Q221205", "display_name": "Sulfide", "level": 2, "score": 0.57881534 }, { "id": "https://openalex.org/C2779889824", "wikidata": "https://www.wikidata.org/wiki/Q341381", "display_name": "Acid mine drainage", "level": 2, "score": 0.49000183 }, { "id": "https://openalex.org/C2816523", "wikidata": "https://www.wikidata.org/wiki/Q180184", "display_name": "Sediment", "level": 2, "score": 0.4893019 }, { "id": "https://openalex.org/C145761182", "wikidata": "https://www.wikidata.org/wiki/Q11196343", "display_name": "Hypogene", "level": 4, "score": 0.4782159 }, { "id": "https://openalex.org/C2776268066", "wikidata": "https://www.wikidata.org/wiki/Q105006", "display_name": "Sphalerite", "level": 3, "score": 0.46512103 }, { "id": "https://openalex.org/C2780191927", "wikidata": "https://www.wikidata.org/wiki/Q2250996", "display_name": "Ferrihydrite", "level": 3, "score": 0.43460262 }, { "id": "https://openalex.org/C2777840720", "wikidata": "https://www.wikidata.org/wiki/Q325345", "display_name": "Covellite", "level": 4, "score": 0.4184235 }, { "id": "https://openalex.org/C199289684", "wikidata": "https://www.wikidata.org/wiki/Q83353", "display_name": "Mineralogy", "level": 1, "score": 0.31956726 }, { "id": "https://openalex.org/C127313418", "wikidata": "https://www.wikidata.org/wiki/Q1069", "display_name": "Geology", "level": 0, "score": 0.2888838 }, { "id": "https://openalex.org/C2778188036", "wikidata": "https://www.wikidata.org/wiki/Q111044", "display_name": "Chalcopyrite", "level": 3, "score": 0.20199487 }, { "id": "https://openalex.org/C2776062231", "wikidata": "https://www.wikidata.org/wiki/Q50769", "display_name": "Pyrite", "level": 2, "score": 0.13624269 }, { "id": "https://openalex.org/C150394285", "wikidata": "https://www.wikidata.org/wiki/Q180254", "display_name": "Adsorption", "level": 2, "score": 0.12761927 }, { "id": "https://openalex.org/C18903297", "wikidata": "https://www.wikidata.org/wiki/Q7150", "display_name": "Ecology", "level": 1, "score": 0.122692674 }, { "id": "https://openalex.org/C151730666", "wikidata": "https://www.wikidata.org/wiki/Q7205", "display_name": "Paleontology", "level": 1, "score": 0.0 }, { "id": "https://openalex.org/C178790620", "wikidata": "https://www.wikidata.org/wiki/Q11351", "display_name": "Organic chemistry", "level": 1, "score": 0.0 }, { "id": "https://openalex.org/C86803240", "wikidata": "https://www.wikidata.org/wiki/Q420", "display_name": "Biology", "level": 0, "score": 0.0 } ], "corresponding_author_ids": [], "corresponding_institution_ids": [], "countries_distinct_count": 1, "counts_by_year": [ { "year": 2021, "cited_by_count": 2 }, { "year": 2020, "cited_by_count": 2 }, { "year": 2018, "cited_by_count": 1 }, { "year": 2017, "cited_by_count": 1 }, { "year": 2016, "cited_by_count": 2 } ], "created_date": "2016-06-24", "datasets": [], "display_name": "Copper Speciation in Variably Toxic Sediments at the Ely Copper Mine, Vermont, United States", "doi": "https://doi.org/10.1021/acs.est.5b04081", "fulltext_origin": "ngrams", "fwci": 0.765, "grants": [ { "funder": "https://openalex.org/F4320306107", "funder_display_name": "U.S. Environmental Protection Agency", "award_id": null }, { "funder": "https://openalex.org/F4320332183", "funder_display_name": "U.S. Geological Survey", "award_id": null }, { "funder": "https://openalex.org/F4320337480", "funder_display_name": "Basic Energy Sciences", "award_id": "DE-AC02-76SF00515" } ], "has_fulltext": true, "id": "https://openalex.org/W2256241948", "ids": { "openalex": "https://openalex.org/W2256241948", "doi": "https://doi.org/10.1021/acs.est.5b04081", "mag": "2256241948", "pmid": "https://pubmed.ncbi.nlm.nih.gov/26734712" }, "indexed_in": [ "crossref", "pubmed" ], "institutions_distinct_count": 2, "is_paratext": false, "is_retracted": false, "keywords": [ { "id": "https://openalex.org/keywords/jarosite", "display_name": "Jarosite", "score": 0.7791087 }, { "id": "https://openalex.org/keywords/genetic-algorithm", "display_name": "Genetic algorithm", "score": 0.68096334 }, { "id": "https://openalex.org/keywords/acid-mine-drainage", "display_name": "Acid mine drainage", "score": 0.49000183 }, { "id": "https://openalex.org/keywords/hypogene", "display_name": "Hypogene", "score": 0.4782159 }, { "id": "https://openalex.org/keywords/sulfide-precipitation", "display_name": "Sulfide Precipitation", "score": 0.476971 }, { "id": "https://openalex.org/keywords/ferrihydrite", "display_name": "Ferrihydrite", "score": 0.43460262 }, { "id": "https://openalex.org/keywords/covellite", "display_name": "Covellite", "score": 0.4184235 } ], "language": "en", "locations": [ { "is_oa": false, "landing_page_url": "https://doi.org/10.1021/acs.est.5b04081", "pdf_url": null, "source": { "id": "https://openalex.org/S13479253", "display_name": "Environmental Science & Technology", "issn_l": "0013-936X", "issn": [ "0013-936X", "1520-5851" ], "is_oa": false, "is_in_doaj": false, "is_core": true, "host_organization": "https://openalex.org/P4310320006", "host_organization_name": "American Chemical Society", "host_organization_lineage": [ "https://openalex.org/P4310320006" ], "host_organization_lineage_names": [ "American Chemical Society" ], "type": "journal" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false }, { "is_oa": false, "landing_page_url": "https://pubmed.ncbi.nlm.nih.gov/26734712", "pdf_url": null, "source": { "id": "https://openalex.org/S4306525036", "display_name": "PubMed", "issn_l": null, "issn": null, "is_oa": false, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1299303238", "host_organization_name": "National Institutes of Health", "host_organization_lineage": [ "https://openalex.org/I1299303238" ], "host_organization_lineage_names": [ "National Institutes of Health" ], "type": "repository" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false } ], "locations_count": 2, "mesh": [ { "descriptor_ui": "D003300", "descriptor_name": "Copper", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": true }, { "descriptor_ui": "D003300", "descriptor_name": "Copper", "qualifier_ui": "Q000032", "qualifier_name": "analysis", "is_major_topic": true }, { "descriptor_ui": "D019015", "descriptor_name": "Geologic Sediments", "qualifier_ui": "Q000032", "qualifier_name": "analysis", "is_major_topic": true }, { "descriptor_ui": "D008906", "descriptor_name": "Mining", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": true }, { "descriptor_ui": "D014874", "descriptor_name": "Water Pollutants, Chemical", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": true }, { "descriptor_ui": "D003300", "descriptor_name": "Copper", "qualifier_ui": "Q000633", "qualifier_name": "toxicity", "is_major_topic": false }, { "descriptor_ui": "D003300", "descriptor_name": "Copper", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D005290", "descriptor_name": "Ferric Compounds", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": false }, { "descriptor_ui": "D005290", "descriptor_name": "Ferric Compounds", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D019015", "descriptor_name": "Geologic Sediments", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": false }, { "descriptor_ui": "D019015", "descriptor_name": "Geologic Sediments", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D058085", "descriptor_name": "Iron Compounds", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": false }, { "descriptor_ui": "D058085", "descriptor_name": "Iron Compounds", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D008855", "descriptor_name": "Microscopy, Electron, Scanning", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D008903", "descriptor_name": "Minerals", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": false }, { "descriptor_ui": "D008903", "descriptor_name": "Minerals", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D010087", "descriptor_name": "Oxides", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": false }, { "descriptor_ui": "D010087", "descriptor_name": "Oxides", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D013052", "descriptor_name": "Spectrometry, X-Ray Emission", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D013431", "descriptor_name": "Sulfates", "qualifier_ui": "Q000737", "qualifier_name": "chemistry", "is_major_topic": false }, { "descriptor_ui": "D013431", "descriptor_name": "Sulfates", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D014707", "descriptor_name": "Vermont", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D014874", "descriptor_name": "Water Pollutants, Chemical", "qualifier_ui": "Q000633", "qualifier_name": "toxicity", "is_major_topic": false }, { "descriptor_ui": "D014874", "descriptor_name": "Water Pollutants, Chemical", "qualifier_ui": "Q000032", "qualifier_name": "analysis", "is_major_topic": false }, { "descriptor_ui": "D014874", "descriptor_name": "Water Pollutants, Chemical", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D056928", "descriptor_name": "X-Ray Absorption Spectroscopy", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false }, { "descriptor_ui": "D014961", "descriptor_name": "X-Ray Diffraction", "qualifier_ui": "", "qualifier_name": null, "is_major_topic": false } ], "ngrams_url": "https://api.openalex.org/works/W2256241948/ngrams", "open_access": { "is_oa": false, "oa_status": "closed", "oa_url": null, "any_repository_has_fulltext": false }, "primary_location": { "is_oa": false, "landing_page_url": "https://doi.org/10.1021/acs.est.5b04081", "pdf_url": null, "source": { "id": "https://openalex.org/S13479253", "display_name": "Environmental Science & Technology", "issn_l": "0013-936X", "issn": [ "0013-936X", "1520-5851" ], "is_oa": false, "is_in_doaj": false, "is_core": true, "host_organization": "https://openalex.org/P4310320006", "host_organization_name": "American Chemical Society", "host_organization_lineage": [ "https://openalex.org/P4310320006" ], "host_organization_lineage_names": [ "American Chemical Society" ], "type": "journal" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false }, "primary_topic": { "id": "https://openalex.org/T11923", "display_name": "Acid Mine Drainage Remediation and Biogeochemistry", "score": 0.9999, "subfield": { "id": "https://openalex.org/subfields/2304", "display_name": "Environmental Chemistry" }, "field": { "id": "https://openalex.org/fields/23", "display_name": "Environmental Science" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, "publication_date": "2016-01-15", "publication_year": 2016, "referenced_works": [ "https://openalex.org/W1480969938", "https://openalex.org/W1490914127", "https://openalex.org/W156374387", "https://openalex.org/W1604035276", "https://openalex.org/W1623559396", "https://openalex.org/W1974769041", "https://openalex.org/W1978450379", "https://openalex.org/W1979031550", "https://openalex.org/W1987430723", "https://openalex.org/W1993596116", "https://openalex.org/W2004496943", "https://openalex.org/W2008688844", "https://openalex.org/W2010118935", "https://openalex.org/W2012041123", "https://openalex.org/W2016087688", "https://openalex.org/W2016400838", "https://openalex.org/W2017714628", "https://openalex.org/W2025503868", "https://openalex.org/W2028886386", "https://openalex.org/W2029845349", "https://openalex.org/W2037741769", "https://openalex.org/W2043502723", "https://openalex.org/W2046928966", "https://openalex.org/W2052401730", "https://openalex.org/W2055453091", "https://openalex.org/W2056444470", "https://openalex.org/W2062192005", "https://openalex.org/W2065079252", "https://openalex.org/W2067505240", "https://openalex.org/W2068496413", "https://openalex.org/W2070113273", "https://openalex.org/W2072064998", "https://openalex.org/W2073706527", "https://openalex.org/W2075766915", "https://openalex.org/W2079843838", "https://openalex.org/W2084022693", "https://openalex.org/W2087563629", "https://openalex.org/W2090967395", "https://openalex.org/W2092061424", "https://openalex.org/W2094137019", "https://openalex.org/W2119925220", "https://openalex.org/W2120772354", "https://openalex.org/W2129210135", "https://openalex.org/W2137250569", "https://openalex.org/W2153400439", "https://openalex.org/W2162729926", "https://openalex.org/W2167675178", "https://openalex.org/W2331500940", "https://openalex.org/W2345606912", "https://openalex.org/W2467465937", "https://openalex.org/W26764329", "https://openalex.org/W2795884722", "https://openalex.org/W2913802060", "https://openalex.org/W4235259112" ], "referenced_works_count": 54, "related_works": [ "https://openalex.org/W885063479", "https://openalex.org/W4233017221", "https://openalex.org/W3141442165", "https://openalex.org/W2766712111", "https://openalex.org/W2091237466", "https://openalex.org/W2075451244", "https://openalex.org/W2073670401", "https://openalex.org/W2038314068", "https://openalex.org/W2020448214", "https://openalex.org/W2009535976" ], "sustainable_development_goals": [ { "display_name": "Life below water", "score": 0.42, "id": "https://metadata.un.org/sdg/14" } ], "title": "Copper Speciation in Variably Toxic Sediments at the Ely Copper Mine, Vermont, United States", "topics": [ { "id": "https://openalex.org/T11923", "display_name": "Acid Mine Drainage Remediation and Biogeochemistry", "score": 0.9999, "subfield": { "id": "https://openalex.org/subfields/2304", "display_name": "Environmental Chemistry" }, "field": { "id": "https://openalex.org/fields/23", "display_name": "Environmental Science" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T10139", "display_name": "Environmental Impact of Heavy Metal Contamination", "score": 0.9971, "subfield": { "id": "https://openalex.org/subfields/2310", "display_name": "Pollution" }, "field": { "id": "https://openalex.org/fields/23", "display_name": "Environmental Science" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T11740", "display_name": "Geochemistry of Manganese Oxides in Sedimentary Environments", "score": 0.991, "subfield": { "id": "https://openalex.org/subfields/1906", "display_name": "Geochemistry and Petrology" }, "field": { "id": "https://openalex.org/fields/19", "display_name": "Earth and Planetary Sciences" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } } ], "type": "article", "type_crossref": "journal-article", "updated_date": "2024-08-15T13:55:40.125428", "versions": [] }
}