{
"USGS Publications Warehouse": { "@context": "https://schema.org", "@type": "Article", "additionalType": "Journal Article", "name": "Most Earth-surface calcites precipitate out of isotopic equilibrium", "identifier": [ { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse IndexID", "value": "70202191", "url": "https://pubs.usgs.gov/publication/70202191" }, { "@type": "PropertyValue", "propertyID": "USGS Publications Warehouse Internal ID", "value": 70202191 }, { "@type": "PropertyValue", "propertyID": "DOI", "value": "10.1038/s41467-019-08336-5", "url": "https://doi.org/10.1038/s41467-019-08336-5" } ], "journal": { "@type": "Periodical", "name": "Nature Communications", "volumeNumber": "10", "issueNumber": "1" }, "inLanguage": "en", "isPartOf": [ { "@type": "CreativeWorkSeries", "name": "Nature Communications" } ], "datePublished": "2019", "dateModified": "2019-02-14", "abstract": "Oxygen-isotope thermometry played a critical role in the rise of modern geochemistry and remains extensively used in (bio-)geoscience. Its theoretical foundations rest on the assumption that\u00a018O/16O partitioning among water and carbonate minerals primarily reflects thermodynamic equilibrium. However, after decades of research, there is no consensus on the true equilibrium\u00a018O/16O fractionation between calcite and water (18\u03b1cc/w). Here, we constrain the equilibrium relations linking temperature,\u00a018\u03b1cc/w, and clumped isotopes (\u039447) based on the composition of extremely slow-growing calcites from Devils Hole and Laghetto Basso (Corchia Cave). Equilibrium\u00a018\u03b1cc/w\u00a0values are systematically ~1.5\u2030 greater than those in biogenic and synthetic calcite traditionally considered to approach oxygen-isotope equilibrium. We further demonstrate that subtle disequilibria also affect\u00a0\u039447\u00a0in biogenic calcite. These observations provide evidence that most Earth-surface calcites fail to achieve isotopic equilibrium, highlighting the need to improve our quantitative understanding of non-equilibrium isotope fractionation effects instead of relying on phenomenological calibrations.", "description": "Article number: 429; 7 p.", "publisher": { "@type": "Organization", "name": "Nature" }, "author": [ { "@type": "Person", "name": "Da\u00ebron, Mathieu", "givenName": "Mathieu", "familyName": "Da\u00ebron", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-1210-9786", "url": "https://orcid.org/0000-0003-1210-9786" }, "affiliation": [ { "@type": "Organization", "name": "Universit\u00e9 Paris-Saclay, France" } ] }, { "@type": "Person", "name": "Peral, Marion", "givenName": "Marion", "familyName": "Peral", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-6027-5482", "url": "https://orcid.org/0000-0002-6027-5482" }, "affiliation": [ { "@type": "Organization", "name": "Universit\u00e9 Paris-Saclay, France" } ] }, { "@type": "Person", "name": "Huyghe, Damien", "givenName": "Damien", "familyName": "Huyghe", "affiliation": [ { "@type": "Organization", "name": "Sorbonne Universit\u00e9, F-66650 Banyuls-sur-mer, France" } ] }, { "@type": "Person", "name": "Drysdale, Russell N", "givenName": "Russell N", "familyName": "Drysdale", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0001-7867-031X", "url": "https://orcid.org/0000-0001-7867-031X" }, "affiliation": [ { "@type": "Organization", "name": "University of Melbourne, Australia" } ] }, { "@type": "Person", "name": "Blamart, Dominique", "givenName": "Dominique", "familyName": "Blamart", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-1422-362X", "url": "https://orcid.org/0000-0003-1422-362X" }, "affiliation": [ { "@type": "Organization", "name": "Universit\u00e9 Paris-Saclay, France" } ] }, { "@type": "Person", "name": "Coplen, Tyler B. tbcoplen@usgs.gov", "givenName": "Tyler B.", "familyName": "Coplen", "email": "tbcoplen@usgs.gov", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0003-4884-6008", "url": "https://orcid.org/0000-0003-4884-6008" }, "affiliation": [ { "@type": "Organization", "name": "National Water Quality Program", "url": "https://www.usgs.gov/programs/national-water-quality-program" }, { "@type": "Organization", "name": "WMA - Earth System Processes Division", "url": "https://www.usgs.gov/mission-areas/water-resources" }, { "@type": "Organization", "name": "National Research Program - Eastern Branch", "url": "https://www.usgs.gov/centers/arizona-water-science-center" }, { "@type": "Organization", "name": "WMA - Laboratory & Analytical Services Division", "url": "https://www.usgs.gov/mission-areas/water-resources" } ] }, { "@type": "Person", "name": "Lartaud, Franck", "givenName": "Franck", "familyName": "Lartaud", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0001-7130-2944", "url": "https://orcid.org/0000-0001-7130-2944" }, "affiliation": [ { "@type": "Organization", "name": "Sorbonne Universit\u00e9, F-66650 Banyuls-sur-mer, France" } ] }, { "@type": "Person", "name": "Zanchetta, Giovanni", "givenName": "Giovanni", "familyName": "Zanchetta", "identifier": { "@type": "PropertyValue", "propertyID": "ORCID", "value": "0000-0002-7080-9599", "url": "https://orcid.org/0000-0002-7080-9599" }, "affiliation": [ { "@type": "Organization", "name": "University of Pisa, Italy" } ] } ], "funder": [ { "@type": "Organization", "name": "WMA - Earth System Processes Division", "url": "https://www.usgs.gov/mission-areas/water-resources" } ] }, "OpenAlex": { "_id": "https://openalex.org/W2911893008", "abstract_inverted_index": { "Abstract": [ 0 ], "Oxygen-isotope": [ 1 ], "thermometry": [ 2 ], "played": [ 3 ], "a": [ 4 ], "critical": [ 5 ], "role": [ 6 ], "in": [ 7, 17, 114, 135 ], "the": [ 8, 24, 51, 71, 89, 152 ], "rise": [ 9 ], "of": [ 10, 44, 91, 159, 165 ], "modern": [ 11 ], "geochemistry": [ 12 ], "and": [ 13, 34, 61, 80, 98, 116 ], "remains": [ 14 ], "extensively": [ 15 ], "used": [ 16 ], "(bio-)geoscience.": [ 18 ], "Its": [ 19 ], "theoretical": [ 20 ], "foundations": [ 21 ], "rest": [ 22 ], "on": [ 23, 50, 88, 167 ], "assumption": [ 25 ], "that": [ 26, 128, 142 ], "18": [ 27, 54, 64, 76, 104 ], "O/": [ 28, 55 ], "16": [ 29, 56 ], "O": [ 30, 57 ], "partitioning": [ 31 ], "among": [ 32 ], "water": [ 33, 62 ], "carbonate": [ 35 ], "minerals": [ 36 ], "primarily": [ 37 ], "reflects": [ 38 ], "thermodynamic": [ 39 ], "equilibrium.": [ 40, 124 ], "However,": [ 41 ], "after": [ 42 ], "decades": [ 43 ], "research,": [ 45 ], "there": [ 46 ], "is": [ 47 ], "no": [ 48 ], "consensus": [ 49 ], "true": [ 52 ], "equilibrium": [ 53, 72 ], "fractionation": [ 58, 162 ], "between": [ 59 ], "calcite": [ 60, 118 ], "(": [ 63, 83 ], "\u03b1": [ 65, 77, 105 ], "cc/w": [ 66, 78, 106 ], ").": [ 67 ], "Here,": [ 68 ], "we": [ 69 ], "constrain": [ 70 ], "relations": [ 73 ], "linking": [ 74 ], "temperature,": [ 75 ], ",": [ 79 ], "clumped": [ 81 ], "isotopes": [ 82 ], "\u0394": [ 84, 133 ], "47": [ 85, 134 ], ")": [ 86 ], "based": [ 87 ], "composition": [ 90 ], "extremely": [ 92 ], "slow-growing": [ 93 ], "calcites": [ 94, 145 ], "from": [ 95 ], "Devils": [ 96 ], "Hole": [ 97 ], "Laghetto": [ 99 ], "Basso": [ 100 ], "(Corchia": [ 101 ], "Cave).": [ 102 ], "Equilibrium": [ 103 ], "values": [ 107 ], "are": [ 108 ], "systematically": [ 109 ], "~1.5\u2030": [ 110 ], "greater": [ 111 ], "than": [ 112 ], "those": [ 113 ], "biogenic": [ 115, 136 ], "synthetic": [ 117 ], "traditionally": [ 119 ], "considered": [ 120 ], "to": [ 121, 147, 154 ], "approach": [ 122 ], "oxygen-isotope": [ 123 ], "We": [ 125 ], "further": [ 126 ], "demonstrate": [ 127 ], "subtle": [ 129 ], "disequilibria": [ 130 ], "also": [ 131 ], "affect": [ 132 ], "calcite.": [ 137 ], "These": [ 138 ], "observations": [ 139 ], "provide": [ 140 ], "evidence": [ 141 ], "most": [ 143 ], "Earth-surface": [ 144 ], "fail": [ 146 ], "achieve": [ 148 ], "isotopic": [ 149 ], "equilibrium,": [ 150 ], "highlighting": [ 151 ], "need": [ 153 ], "improve": [ 155 ], "our": [ 156 ], "quantitative": [ 157 ], "understanding": [ 158 ], "non-equilibrium": [ 160 ], "isotope": [ 161 ], "effects": [ 163 ], "instead": [ 164 ], "relying": [ 166 ], "phenomenological": [ 168 ], "calibrations.": [ 169 ] }, "apc_list": { "value": 3920, "currency": "GBP", "value_usd": 4808, "provenance": "doaj" }, "apc_paid": { "value": 3850, "currency": "EUR", "value_usd": 4152, "provenance": "openapc" }, "authorships": [ { "author_position": "first", "author": { "id": "https://openalex.org/A5043059416", "display_name": "Mathieu Da\u00ebron", "orcid": "https://orcid.org/0000-0003-1210-9786" }, "institutions": [ { "id": "https://openalex.org/I4210124937", "display_name": "Laboratoire des Sciences du Climat et de l'Environnement", "ror": "https://ror.org/03dsd0g48", "country_code": "FR", "type": "facility", "lineage": [ "https://openalex.org/I1294671590", "https://openalex.org/I195731000", "https://openalex.org/I2738703131", "https://openalex.org/I4210113668", "https://openalex.org/I4210124937", "https://openalex.org/I4210148025" ] } ], "countries": [ "FR" ], "is_corresponding": false, "raw_author_name": "Mathieu Da\u00ebron", "raw_affiliation_strings": [ "Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette]", "Pal\u00e9oc\u00e9anographie" ], "affiliations": [ { "raw_affiliation_string": "Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette]", "institution_ids": [ "https://openalex.org/I4210124937" ] }, { "raw_affiliation_string": "Pal\u00e9oc\u00e9anographie", "institution_ids": [] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5001010378", "display_name": "Russell N. Drysdale", "orcid": "https://orcid.org/0000-0001-7867-031X" }, "institutions": [ { "id": "https://openalex.org/I165779595", "display_name": "University of Melbourne", "ror": "https://ror.org/01ej9dk98", "country_code": "AU", "type": "education", "lineage": [ "https://openalex.org/I165779595" ] } ], "countries": [ "AU" ], "is_corresponding": false, "raw_author_name": "Russell N Drysdale", "raw_affiliation_strings": [ "University of Melbourne" ], "affiliations": [ { "raw_affiliation_string": "University of Melbourne", "institution_ids": [ "https://openalex.org/I165779595" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5031592095", "display_name": "Marion Peral", "orcid": "https://orcid.org/0000-0002-6027-5482" }, "institutions": [ { "id": "https://openalex.org/I4210124937", "display_name": "Laboratoire des Sciences du Climat et de l'Environnement", "ror": "https://ror.org/03dsd0g48", "country_code": "FR", "type": "facility", "lineage": [ "https://openalex.org/I1294671590", "https://openalex.org/I195731000", "https://openalex.org/I2738703131", "https://openalex.org/I4210113668", "https://openalex.org/I4210124937", "https://openalex.org/I4210148025" ] } ], "countries": [ "FR" ], "is_corresponding": false, "raw_author_name": "Marion Peral", "raw_affiliation_strings": [ "Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette]" ], "affiliations": [ { "raw_affiliation_string": "Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette]", "institution_ids": [ "https://openalex.org/I4210124937" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5071809757", "display_name": "Damien Huyghe", "orcid": "https://orcid.org/0000-0003-0244-4345" }, "institutions": [ { "id": "https://openalex.org/I4210148040", "display_name": "Centre de G\u00e9osciences", "ror": "https://ror.org/03kc13263", "country_code": "FR", "type": "facility", "lineage": [ "https://openalex.org/I190752583", "https://openalex.org/I4210091621", "https://openalex.org/I4210148040", "https://openalex.org/I70768539" ] }, { "id": "https://openalex.org/I4210158675", "display_name": "Laboratoire d'Ecog\u00e9ochimie des Environnements Benthiques", "ror": "https://ror.org/049xh5y45", "country_code": "FR", "type": "facility", "lineage": [ "https://openalex.org/I1294671590", "https://openalex.org/I39804081", "https://openalex.org/I4210107625", "https://openalex.org/I4210144707", "https://openalex.org/I4210158675" ] }, { "id": "https://openalex.org/I4210164289", "display_name": "G\u00e9osciences Environnement Toulouse", "ror": "https://ror.org/05k0qmv73", "country_code": "FR", "type": "facility", "lineage": [ "https://openalex.org/I1294671590", "https://openalex.org/I134560555", "https://openalex.org/I2799535048", "https://openalex.org/I2802818602", "https://openalex.org/I4210090127", "https://openalex.org/I4210131494", "https://openalex.org/I4210148025", "https://openalex.org/I4210164289", "https://openalex.org/I4210166444" ] } ], "countries": [ "FR" ], "is_corresponding": false, "raw_author_name": "Damien Huyghe", "raw_affiliation_strings": [ "Centre de G\u00e9osciences", "G\u00e9osciences Environnement Toulouse", "Laboratoire d'Ecog\u00e9ochimie des environnements benthiques" ], "affiliations": [ { "raw_affiliation_string": "Centre de G\u00e9osciences", "institution_ids": [ "https://openalex.org/I4210148040" ] }, { "raw_affiliation_string": "Laboratoire d'Ecog\u00e9ochimie des environnements benthiques", "institution_ids": [ "https://openalex.org/I4210158675" ] }, { "raw_affiliation_string": "G\u00e9osciences Environnement Toulouse", "institution_ids": [ "https://openalex.org/I4210164289" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5078998894", "display_name": "D. Blamart", "orcid": "https://orcid.org/0000-0003-1422-362X" }, "institutions": [ { "id": "https://openalex.org/I4210124937", "display_name": "Laboratoire des Sciences du Climat et de l'Environnement", "ror": "https://ror.org/03dsd0g48", "country_code": "FR", "type": "facility", "lineage": [ "https://openalex.org/I1294671590", "https://openalex.org/I195731000", "https://openalex.org/I2738703131", "https://openalex.org/I4210113668", "https://openalex.org/I4210124937", "https://openalex.org/I4210148025" ] } ], "countries": [ "FR" ], "is_corresponding": false, "raw_author_name": "Dominique Blamart", "raw_affiliation_strings": [ "Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette]", "Pal\u00e9oc\u00e9anographie" ], "affiliations": [ { "raw_affiliation_string": "Laboratoire des Sciences du Climat et de l'Environnement [Gif-sur-Yvette]", "institution_ids": [ "https://openalex.org/I4210124937" ] }, { "raw_affiliation_string": "Pal\u00e9oc\u00e9anographie", "institution_ids": [] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5082667605", "display_name": "Tyler B. Coplen", "orcid": "https://orcid.org/0000-0003-4884-6008" }, "institutions": [ { "id": "https://openalex.org/I1286329397", "display_name": "United States Geological Survey", "ror": "https://ror.org/035a68863", "country_code": "US", "type": "government", "lineage": [ "https://openalex.org/I1286329397", "https://openalex.org/I1335927249" ] } ], "countries": [ "US" ], "is_corresponding": false, "raw_author_name": "Tyler B. Coplen", "raw_affiliation_strings": [ "United States Geological Survey [Reston]" ], "affiliations": [ { "raw_affiliation_string": "United States Geological Survey [Reston]", "institution_ids": [ "https://openalex.org/I1286329397" ] } ] }, { "author_position": "middle", "author": { "id": "https://openalex.org/A5042287954", "display_name": "Franck Lartaud", "orcid": "https://orcid.org/0000-0001-7130-2944" }, "institutions": [ { "id": "https://openalex.org/I4210158675", "display_name": "Laboratoire d'Ecog\u00e9ochimie des Environnements Benthiques", "ror": "https://ror.org/049xh5y45", "country_code": "FR", "type": "facility", "lineage": [ "https://openalex.org/I1294671590", "https://openalex.org/I39804081", "https://openalex.org/I4210107625", "https://openalex.org/I4210144707", "https://openalex.org/I4210158675" ] } ], "countries": [ "FR" ], "is_corresponding": false, "raw_author_name": "Franck Lartaud", "raw_affiliation_strings": [ "Laboratoire d'Ecog\u00e9ochimie des environnements benthiques" ], "affiliations": [ { "raw_affiliation_string": "Laboratoire d'Ecog\u00e9ochimie des environnements benthiques", "institution_ids": [ "https://openalex.org/I4210158675" ] } ] }, { "author_position": "last", "author": { "id": "https://openalex.org/A5053851938", "display_name": "Giovanni Zanchetta", "orcid": "https://orcid.org/0000-0002-7080-9599" }, "institutions": [ { "id": "https://openalex.org/I108290504", "display_name": "University of Pisa", "ror": "https://ror.org/03ad39j10", "country_code": "IT", "type": "education", "lineage": [ "https://openalex.org/I108290504" ] } ], "countries": [ "IT" ], "is_corresponding": false, "raw_author_name": "Giovanni Zanchetta", "raw_affiliation_strings": [ "University of Pisa - Universit\u00e0 di Pisa" ], "affiliations": [ { "raw_affiliation_string": "University of Pisa - Universit\u00e0 di Pisa", "institution_ids": [ "https://openalex.org/I108290504" ] } ] } ], "best_oa_location": { "is_oa": true, "landing_page_url": "https://doi.org/10.1038/s41467-019-08336-5", "pdf_url": "https://www.nature.com/articles/s41467-019-08336-5.pdf", "source": { "id": "https://openalex.org/S64187185", "display_name": "Nature Communications", "issn_l": "2041-1723", "issn": [ "2041-1723" ], "is_oa": true, "is_in_doaj": true, "is_core": true, "host_organization": "https://openalex.org/P4310319908", "host_organization_name": "Nature Portfolio", "host_organization_lineage": [ "https://openalex.org/P4310319908", "https://openalex.org/P4310319965" ], "host_organization_lineage_names": [ "Nature Portfolio", "Springer Nature" ], "type": "journal" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, "biblio": { "volume": "10", "issue": "1", "first_page": null, "last_page": null }, "cited_by_api_url": "https://api.openalex.org/works?filter=cites:W2911893008", "cited_by_count": 167, "cited_by_percentile_year": { "min": 99, "max": 100 }, "concepts": [ { "id": "https://openalex.org/c2780191791", "wikidata": "https://www.wikidata.org/wiki/Q171917", "display_name": "Calcite", "level": 2, "score": 0.897004, "qid": "Q162281" }, { "id": "https://openalex.org/c195511166", "wikidata": "https://www.wikidata.org/wiki/Q5384484", "display_name": "Equilibrium fractionation", "level": 4, "score": 0.8808012, "qid": null }, { "id": "https://openalex.org/c71468253", "wikidata": "https://www.wikidata.org/wiki/Q785643", "display_name": "Isotopes of oxygen", "level": 2, "score": 0.62799287, "qid": null }, { "id": "https://openalex.org/c97428945", "wikidata": "https://www.wikidata.org/wiki/Q15305109", "display_name": "Fractionation", "level": 2, "score": 0.5644495, "qid": null }, { "id": "https://openalex.org/c2779334269", "wikidata": "https://www.wikidata.org/wiki/Q3080293", "display_name": "Isotope fractionation", "level": 3, "score": 0.55240977, "qid": null }, { "id": "https://openalex.org/c2780659211", "wikidata": "https://www.wikidata.org/wiki/Q181699", "display_name": "Carbonate", "level": 2, "score": 0.52499354, "qid": null }, { "id": "https://openalex.org/c164304813", "wikidata": "https://www.wikidata.org/wiki/Q25276", "display_name": "Isotope", "level": 2, "score": 0.5193409, "qid": null }, { "id": "https://openalex.org/c165349299", "wikidata": "https://www.wikidata.org/wiki/Q1674549", "display_name": "Isotope geochemistry", "level": 3, "score": 0.5146666, "qid": null }, { "id": "https://openalex.org/c22117777", "wikidata": "https://www.wikidata.org/wiki/Q17148629", "display_name": "Stable isotope ratio", "level": 2, "score": 0.49740675, "qid": null }, { "id": "https://openalex.org/c127313418", "wikidata": "https://www.wikidata.org/wiki/Q1069", "display_name": "Geology", "level": 0, "score": 0.48907453, "qid": "Q158984" }, { "id": "https://openalex.org/c111663737", "wikidata": "https://www.wikidata.org/wiki/Q10860570", "display_name": "Equilibrium thermodynamics", "level": 3, "score": 0.46918204, "qid": null }, { "id": "https://openalex.org/c76462348", "wikidata": "https://www.wikidata.org/wiki/Q1820977", "display_name": "Oxygen isotope ratio cycle", "level": 3, "score": 0.46800083, "qid": null }, { "id": "https://openalex.org/c131157278", "wikidata": "https://www.wikidata.org/wiki/Q51363", "display_name": "Thermodynamic equilibrium", "level": 2, "score": 0.42015043, "qid": null }, { "id": "https://openalex.org/c199289684", "wikidata": "https://www.wikidata.org/wiki/Q83353", "display_name": "Mineralogy", "level": 1, "score": 0.41696033, "qid": "Q159009" }, { "id": "https://openalex.org/c17409809", "wikidata": "https://www.wikidata.org/wiki/Q161764", "display_name": "Geochemistry", "level": 1, "score": 0.325347, "qid": "Q158980" }, { "id": "https://openalex.org/c185592680", "wikidata": "https://www.wikidata.org/wiki/Q2329", "display_name": "Chemistry", "level": 0, "score": 0.32085437, "qid": "Q166089" }, { "id": "https://openalex.org/c97355855", "wikidata": "https://www.wikidata.org/wiki/Q11473", "display_name": "Thermodynamics", "level": 1, "score": 0.20016271, "qid": "Q226322" }, { "id": "https://openalex.org/c121332964", "wikidata": "https://www.wikidata.org/wiki/Q413", "display_name": "Physics", "level": 0, "score": 0.0, "qid": "Q166093" }, { "id": "https://openalex.org/c178790620", "wikidata": "https://www.wikidata.org/wiki/Q11351", "display_name": "Organic chemistry", "level": 1, "score": 0.0, "qid": "Q166197" }, { "id": "https://openalex.org/c62520636", "wikidata": "https://www.wikidata.org/wiki/Q944", "display_name": "Quantum mechanics", "level": 1, "score": 0.0, "qid": "Q226309" } ], "corresponding_author_ids": [], "corresponding_institution_ids": [], "countries_distinct_count": 4, "counts_by_year": [ { "year": 2024, "cited_by_count": 23 }, { "year": 2023, "cited_by_count": 27 }, { "year": 2022, "cited_by_count": 37 }, { "year": 2021, "cited_by_count": 40 }, { "year": 2020, "cited_by_count": 28 }, { "year": 2019, "cited_by_count": 12 } ], "created_date": "2019-02-21", "datasets": [], "display_name": "Most Earth-surface calcites precipitate out of isotopic equilibrium", "doi": "https://doi.org/10.1038/s41467-019-08336-5", "fulltext_origin": "pdf", "fwci": 16.81, "grants": [], "has_fulltext": true, "id": "https://openalex.org/W2911893008", "ids": { "openalex": "https://openalex.org/W2911893008", "doi": "https://doi.org/10.1038/s41467-019-08336-5", "mag": "2911893008", "pmid": "https://pubmed.ncbi.nlm.nih.gov/30683869", "pmcid": "https://www.ncbi.nlm.nih.gov/pmc/articles/6347637" }, "indexed_in": [ "crossref", "doaj", "pubmed" ], "institutions_distinct_count": 7, "is_paratext": false, "is_retracted": false, "keywords": [ { "id": "https://openalex.org/keywords/equilibrium-fractionation", "display_name": "Equilibrium fractionation", "score": 0.8808012 }, { "id": "https://openalex.org/keywords/temperature", "display_name": "Temperature", "score": 0.516453 }, { "id": "https://openalex.org/keywords/isotope-geochemistry", "display_name": "Isotope geochemistry", "score": 0.5146666 }, { "id": "https://openalex.org/keywords/equilibrium-thermodynamics", "display_name": "Equilibrium thermodynamics", "score": 0.46918204 } ], "language": "en", "locations": [ { "is_oa": true, "landing_page_url": "https://doi.org/10.1038/s41467-019-08336-5", "pdf_url": "https://www.nature.com/articles/s41467-019-08336-5.pdf", "source": { "id": "https://openalex.org/S64187185", "display_name": "Nature Communications", "issn_l": "2041-1723", "issn": [ "2041-1723" ], "is_oa": true, "is_in_doaj": true, "is_core": true, "host_organization": "https://openalex.org/P4310319908", "host_organization_name": "Nature Portfolio", "host_organization_lineage": [ "https://openalex.org/P4310319908", "https://openalex.org/P4310319965" ], "host_organization_lineage_names": [ "Nature Portfolio", "Springer Nature" ], "type": "journal" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": false, "landing_page_url": "https://hal.archives-ouvertes.fr/hal-02011797", "pdf_url": null, "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false }, { "is_oa": true, "landing_page_url": "https://hal.archives-ouvertes.fr/hal-02396547", "pdf_url": "https://hal.science/hal-02396547/document", "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": false, "landing_page_url": "https://hal.science/hal-02396547", "pdf_url": null, "source": null, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false }, { "is_oa": false, "landing_page_url": "https://doaj.org/article/7f71bb6639164d8895d5625b539d49ba", "pdf_url": null, "source": { "id": "https://openalex.org/S4306401280", "display_name": "DOAJ (DOAJ: Directory of Open Access Journals)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": null, "host_organization_name": null, "host_organization_lineage": [], "host_organization_lineage_names": [], "type": "repository" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false }, { "is_oa": true, "landing_page_url": "https://europepmc.org/articles/pmc6347637", "pdf_url": "https://europepmc.org/articles/pmc6347637?pdf=render", "source": { "id": "https://openalex.org/S4306400806", "display_name": "Europe PMC (PubMed Central)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1303153112", "host_organization_name": "European Bioinformatics Institute", "host_organization_lineage": [ "https://openalex.org/I1303153112" ], "host_organization_lineage_names": [ "European Bioinformatics Institute" ], "type": "repository" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "https://hal.science/hal-03136285/document", "pdf_url": "https://hal.science/hal-03136285/document", "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "https://hal.science/hal-03136285/file/s41467-019-08336-5.pdf", "pdf_url": "https://hal.science/hal-03136285/file/s41467-019-08336-5.pdf", "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "https://hal.archives-ouvertes.fr/hal-03136285/file/s41467-019-08336-5.pdf", "pdf_url": "https://hal.archives-ouvertes.fr/hal-03136285/file/s41467-019-08336-5.pdf", "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "https://hal.archives-ouvertes.fr/hal-03136285/document", "pdf_url": "https://hal.archives-ouvertes.fr/hal-03136285/document", "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "http://hdl.handle.net/11343/240771", "pdf_url": "http://minerva-access.unimelb.edu.au/bitstreams/56aa5aac-5959-5b9e-b595-ac0b50890a16/download", "source": { "id": "https://openalex.org/S4306402500", "display_name": "Minerva Access (University of Melbourne)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I165779595", "host_organization_name": "University of Melbourne", "host_organization_lineage": [ "https://openalex.org/I165779595" ], "host_organization_lineage_names": [ "University of Melbourne" ], "type": "repository" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "http://hdl.handle.net/11568/962952", "pdf_url": "https://arpi.unipi.it/bitstream/11568/962952/1/Dearonetal2019NC.pdf", "source": { "id": "https://openalex.org/S4377196265", "display_name": "CINECA IRIS Institutial research information system (University of Pisa)", "issn_l": null, "issn": null, "is_oa": false, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I108290504", "host_organization_name": "University of Pisa", "host_organization_lineage": [ "https://openalex.org/I108290504" ], "host_organization_lineage_names": [ "University of Pisa" ], "type": "repository" }, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "https://hal.archives-ouvertes.fr/hal-02396547/file/s41467-019-08336-5.pdf", "pdf_url": "https://hal.archives-ouvertes.fr/hal-02396547/file/s41467-019-08336-5.pdf", "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "https://hal.science/hal-02396547/file/s41467-019-08336-5.pdf", "pdf_url": "https://hal.science/hal-02396547/file/s41467-019-08336-5.pdf", "source": { "id": "https://openalex.org/S4306402512", "display_name": "HAL (Le Centre pour la Communication Scientifique Directe)", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1294671590", "host_organization_name": "Centre National de la Recherche Scientifique", "host_organization_lineage": [ "https://openalex.org/I1294671590" ], "host_organization_lineage_names": [ "Centre National de la Recherche Scientifique" ], "type": "repository" }, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": true, "landing_page_url": "https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6347637", "pdf_url": null, "source": { "id": "https://openalex.org/S2764455111", "display_name": "PubMed Central", "issn_l": null, "issn": null, "is_oa": true, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1299303238", "host_organization_name": "National Institutes of Health", "host_organization_lineage": [ "https://openalex.org/I1299303238" ], "host_organization_lineage_names": [ "National Institutes of Health" ], "type": "repository" }, "license": null, "license_id": null, "version": "publishedVersion", "is_accepted": true, "is_published": true }, { "is_oa": false, "landing_page_url": "https://pubmed.ncbi.nlm.nih.gov/30683869", "pdf_url": null, "source": { "id": "https://openalex.org/S4306525036", "display_name": "PubMed", "issn_l": null, "issn": null, "is_oa": false, "is_in_doaj": false, "is_core": false, "host_organization": "https://openalex.org/I1299303238", "host_organization_name": "National Institutes of Health", "host_organization_lineage": [ "https://openalex.org/I1299303238" ], "host_organization_lineage_names": [ "National Institutes of Health" ], "type": "repository" }, "license": null, "license_id": null, "version": null, "is_accepted": false, "is_published": false } ], "locations_count": 16, "mesh": [], "ngrams_url": "https://api.openalex.org/works/W2911893008/ngrams", "open_access": { "is_oa": true, "oa_status": "gold", "oa_url": "https://www.nature.com/articles/s41467-019-08336-5.pdf", "any_repository_has_fulltext": true }, "primary_location": { "is_oa": true, "landing_page_url": "https://doi.org/10.1038/s41467-019-08336-5", "pdf_url": "https://www.nature.com/articles/s41467-019-08336-5.pdf", "source": { "id": "https://openalex.org/S64187185", "display_name": "Nature Communications", "issn_l": "2041-1723", "issn": [ "2041-1723" ], "is_oa": true, "is_in_doaj": true, "is_core": true, "host_organization": "https://openalex.org/P4310319908", "host_organization_name": "Nature Portfolio", "host_organization_lineage": [ "https://openalex.org/P4310319908", "https://openalex.org/P4310319965" ], "host_organization_lineage_names": [ "Nature Portfolio", "Springer Nature" ], "type": "journal" }, "license": "cc-by", "license_id": "https://openalex.org/licenses/cc-by", "version": "publishedVersion", "is_accepted": true, "is_published": true }, "primary_topic": { "id": "https://openalex.org/T10109", "display_name": "Paleoredox and Paleoproductivity Proxies", "score": 0.9996, "subfield": { "id": "https://openalex.org/subfields/1911", "display_name": "Paleontology" }, "field": { "id": "https://openalex.org/fields/19", "display_name": "Earth and Planetary Sciences" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, "publication_date": "2019-01-25", "publication_year": 2019, "referenced_works": [ "https://openalex.org/W121857346", "https://openalex.org/W1516493227", "https://openalex.org/W1577963485", "https://openalex.org/W1592067263", "https://openalex.org/W1597819980", "https://openalex.org/W1625995244", "https://openalex.org/W1823013860", "https://openalex.org/W1913208140", "https://openalex.org/W1970658925", "https://openalex.org/W1975758195", "https://openalex.org/W1976172506", "https://openalex.org/W1981825598", "https://openalex.org/W1982501612", "https://openalex.org/W1983017748", "https://openalex.org/W1986580664", "https://openalex.org/W1993875196", "https://openalex.org/W1999458700", "https://openalex.org/W2006657131", "https://openalex.org/W2008281306", "https://openalex.org/W2017913935", "https://openalex.org/W2018302626", "https://openalex.org/W2026298114", "https://openalex.org/W2028382268", "https://openalex.org/W2036887905", "https://openalex.org/W2045019212", "https://openalex.org/W2045888443", "https://openalex.org/W2051173832", "https://openalex.org/W2051973454", "https://openalex.org/W2054602287", "https://openalex.org/W2061870789", "https://openalex.org/W2063009391", "https://openalex.org/W2082422470", "https://openalex.org/W2086782132", "https://openalex.org/W2090887314", "https://openalex.org/W2090942757", "https://openalex.org/W2093887815", "https://openalex.org/W2106839072", "https://openalex.org/W2113025387", "https://openalex.org/W2129805855", "https://openalex.org/W2133324096", "https://openalex.org/W2140488683", "https://openalex.org/W2140524010", "https://openalex.org/W2146543851", "https://openalex.org/W2150862234", "https://openalex.org/W2151103985", "https://openalex.org/W2153669645", "https://openalex.org/W2156694865", "https://openalex.org/W2161874332", "https://openalex.org/W2172500198", "https://openalex.org/W2198740925", "https://openalex.org/W2518194862", "https://openalex.org/W2532673986", "https://openalex.org/W2553285585", "https://openalex.org/W2724461345", "https://openalex.org/W2788511281", "https://openalex.org/W2791823349", "https://openalex.org/W2792390955", "https://openalex.org/W2800140460", "https://openalex.org/W2884215589", "https://openalex.org/W2885555794", "https://openalex.org/W2907771304" ], "referenced_works_count": 61, "related_works": [ "https://openalex.org/W3002066736", "https://openalex.org/W2906492078", "https://openalex.org/W2901834674", "https://openalex.org/W2724461345", "https://openalex.org/W2360877805", "https://openalex.org/W2033480865", "https://openalex.org/W1994214244", "https://openalex.org/W1987388908", "https://openalex.org/W1980798762", "https://openalex.org/W1976853293" ], "sustainable_development_goals": [], "title": "Most Earth-surface calcites precipitate out of isotopic equilibrium", "topics": [ { "id": "https://openalex.org/T10109", "display_name": "Paleoredox and Paleoproductivity Proxies", "score": 0.9996, "subfield": { "id": "https://openalex.org/subfields/1911", "display_name": "Paleontology" }, "field": { "id": "https://openalex.org/fields/19", "display_name": "Earth and Planetary Sciences" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T10017", "display_name": "Climate Change and Paleoclimatology", "score": 0.9991, "subfield": { "id": "https://openalex.org/subfields/1902", "display_name": "Atmospheric Science" }, "field": { "id": "https://openalex.org/fields/19", "display_name": "Earth and Planetary Sciences" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } }, { "id": "https://openalex.org/T11056", "display_name": "Metabolic Theory of Ecology and Climate Change Impacts", "score": 0.9968, "subfield": { "id": "https://openalex.org/subfields/2303", "display_name": "Ecology" }, "field": { "id": "https://openalex.org/fields/23", "display_name": "Environmental Science" }, "domain": { "id": "https://openalex.org/domains/3", "display_name": "Physical Sciences" } } ], "type": "article", "type_crossref": "journal-article", "updated_date": "2024-08-08T13:07:23.088869", "versions": [], "qid": null }
}