Item talk:Q70904: Difference between revisions

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= Mantle and Crustal Sources of Carbon, Nitrogen, and Noble gases in Cascade-Range and Aleutian-Arc Volcanic gases =
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Here we report anhydrous chemical (CO2, H2S, N2, H2, CH4, O2, Ar, He, Ne) and isotopic (3He/4He, 40Ar/36Ar, δ13C of CO2, δ13C of CH4, δ15N) compositions of virtually airfree gas samples collected between 1994 and 1998 from 12 quiescent but potentially restless volcanoes in the Cascade Range and Aleutian Arc (CRAA). Sample sites include ≤173°C fumaroles and springs at Mount Shasta, Mount Hood, Mount St. Helens, Mount Rainier, Mount Baker, Augustine Volcano, Mount Griggs, Trident, Mount Mageik, Aniakchak Crater, Akutan, and Makushin. The chemical and isotopic data generally point to magmatic (CO2, Ar, He), shallow crustal sedimentary (hereafter, SCS) (CO2, N2, CH4), crustal (He), and meteoric (N2, Ar) sources of volatiles. CH4 clearly comes from SCS rocks in the subvolcanic systems because CH4 cannot survive the higher temperatures of deeper potential sources. Further evidence for a SCS source for CH4 as well as for non-mantle CO2 and non-meteoric N2 comes from isotopic data that show wide variations between volcanoes that are spatially very close and similar isotopic signatures from volcanoes from very disparate areas. Our results are in direct opposition to many recent studies on other volcanic arcs (Kita and others, 1993; Sano and Marty, 1995; Fischer and others, 1998), in that they point to a dearth of subducted components of CO2 and N2 in the CRAA discharges. Either the CRAA volcanoes are fundamentally different from volcanoes in other arcs or we need to reevaluate the significance of subducted C and N recycling in convergent-plate volcanoes.
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      "abstract": "Here we report anhydrous chemical (CO2, H2S, N2, H2, CH4, O2, Ar, He, Ne) and isotopic (3He/4He, 40Ar/36Ar, \u03b413C of CO2, \u03b413C of CH4, \u03b415N) compositions of virtually airfree gas samples collected between 1994 and 1998 from 12 quiescent but potentially restless volcanoes in the Cascade Range and Aleutian Arc (CRAA). Sample sites include \u2264173\u00b0C fumaroles and springs at Mount Shasta, Mount Hood, Mount St. Helens, Mount Rainier, Mount Baker, Augustine Volcano, Mount Griggs, Trident, Mount Mageik, Aniakchak Crater, Akutan, and Makushin. The chemical and isotopic data generally point to magmatic (CO2, Ar, He), shallow crustal sedimentary (hereafter, SCS) (CO2, N2, CH4), crustal (He), and meteoric (N2, Ar) sources of volatiles. CH4 clearly comes from SCS rocks in the subvolcanic systems because CH4 cannot survive the higher temperatures of deeper potential sources. Further evidence for a SCS source for CH4 as well as for non-mantle CO2 and non-meteoric N2 comes from isotopic data that show wide variations between volcanoes that are spatially very close and similar isotopic signatures from volcanoes from very disparate areas. Our results are in direct opposition to many recent studies on other volcanic arcs (Kita and others, 1993; Sano and Marty, 1995; Fischer and others, 1998), in that they point to a dearth of subducted components of CO2 and N2 in the CRAA discharges. Either the CRAA volcanoes are fundamentally different from volcanoes in other arcs or we need to reevaluate the significance of subducted C and N recycling in convergent-plate volcanoes.",
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Latest revision as of 03:49, 15 August 2024

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